Citation: Wei Wang, Liqin Li, Jie Ouyang, Jialin Gong, Jie Tian, Liang Chen, Junlin Huang, Binhong He, Zhaohui Hou. CoS₂/N, S co-doped mesoporous carbon with 3D micro-nano crosslinked structure as efficient bifunctional oxygen electrocatalysts for zinc-air batteries[J]. Chinese Chemical Letters, ;2023, 34(5): 107597. doi: 10.1016/j.cclet.2022.06.020 shu

CoS₂/N, S co-doped mesoporous carbon with 3D micro-nano crosslinked structure as efficient bifunctional oxygen electrocatalysts for zinc-air batteries

Wei Wang ^{a, b, c} ,
Liqin Li ^a ,
Jie Ouyang ^{a, d} ,
Jialin Gong ^a ,
Jie Tian ^a ,
Liang Chen ^a ,
Junlin Huang ^a ,
Binhong He ^a ,
Zhaohui Hou ^{a, *,}

a.
Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials, School of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China
b.
Guangxi Key Laboratory of Low Energy Material, Guangxi Normal University, Guilin 541004, China
c.
Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University, Huangshi 435002, China
d.
Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, Material Science and Engineering School, Central South University of Forestry and Technology, Changsha 410004, China

zhaohuihou@126.com

Received Date: 27 April 2022
Revised Date: 28 May 2022
Accepted Date: 8 June 2022
Available Online: 13 June 2022

Figures(4)

This work describes a bifunctional oxygen catalyst made of cobalt disulfide encapsulated in N, S co-doped mesoporous carbon with a novel three-dimensional micro-nano crosslinking structure. The proposed composite materials exhibit promising oxygen electrocatalytic activity and stability. The composite assembled rechargeable zinc-air battery can achieve a high power density of 208.9 mW/cm², and can be stably cycled for more than 160 h. Additionally, the all-solid zinc-air battery assembled with the electrocatalyst also performs admirably. The micro-nano crosslinking and high porosity structure, as well as the large number of active sites generated by the synergy of N, S doping and the close interface between carbon matrix and CoS₂, contribute to the composite's exceptional electrochemical performance. This study's rational strategy lays the path for the development of other high-performance bifunctional electrocatalysts.
- Micro-nano crosslinked,
- CoS₂,
- ORR,
- OER,
- Zn-air battery
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CoS2/N, S co-doped mesoporous carbon with 3D micro-nano crosslinked structure as efficient bifunctional oxygen electrocatalysts for zinc-air batteries

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通讯作者: 陈斌, bchen63@163.com

CoS₂/N, S co-doped mesoporous carbon with 3D micro-nano crosslinked structure as efficient bifunctional oxygen electrocatalysts for zinc-air batteries