Citation: Ruding Zhang, Huixin Chen, Hongjun Yue. Room-temperature synthesis of layered open framework cathode for sodium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(5): 107580. doi: 10.1016/j.cclet.2022.06.003 shu

Room-temperature synthesis of layered open framework cathode for sodium-ion batteries

Ruding Zhang ^{a, b} ,
Huixin Chen ^{a, b} ,
Hongjun Yue ^{a, b, *,}

a.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China

hjyue@fjirsm.ac.cn

Received Date: 5 May 2022
Revised Date: 21 May 2022
Accepted Date: 1 June 2022
Available Online: 3 June 2022

Figures(4)

The synthesis of active electrode materials at room temperature is one of the effective strategies to reduce the fabrication cost of sodium ion batteries (SIBs). Herein, a layered material (Na₂[(VO)₂(HPO4)₂C₂O₄]·2H₂O, abbreviated as NVPC followingly) with open-framework structures has been successfully prepared at room temperature under ambient conditions and is evaluated as a cathode for SIBs. It is revealed that NVPC cathode can deliver a maximum reversible capacity of ca. 70 mAh/g at 10 mA/g, and exhibit superior rate capability and cycling performance: at 50 mA/g, maximum reversible capacity ca. 50 mAh/g with capacity retention of 88.4% over 250 cycles corresponds to only 0.046% capacity decay per cycle; at 100 mA/g, a maximum reversible capacity of 35 mAh/g with capacity retention of 60.9% over 500 cycles. This study demonstrates a practical example of a low-cost synthesis of the cathode materials for SIBs. At the same time, the systematic electrochemical research results also show promising prospects for long lifespan low-cost SIBs.
- Room temperature solution synthesis,
- Open framework structure,
- Cathode materials,
- Sodium-ion batteries,
- Full cell
1. [1]
  N. Yabuuchi, K. Kubota, M. Dahbi, S. Komaba, Chem. Rev. 114 (2014) 11636–11682. doi: 10.1021/cr500192f
2. [2]
  D. Kundu, E. Talaie, V. Duffort, L.F. Nazar, Angew. Chem. Int. Ed. 54 (2015) 3431–3448. doi: 10.1002/anie.201410376
3. [3]
  R.C. Massé, E. Uchaker, G. Cao, Sci. Chin. Mater. 58 (2015) 715–766.
4. [4]
  B. Liu, D.N. Lei, J. Wang, et al., Nano Res. 13 (2020) 2136–2142. doi: 10.1007/s12274-020-2820-y
5. [5]
  S.Y. Li, W. He, B. Liu, et al., Energy Storage Mater. 25 (2020) 636–643. doi: 10.1016/j.ensm.2019.09.021
6. [6]
  J. Kim, H. Kim, K. Kang, Adv. Energy Mater. 8 (2018) 1702646. doi: 10.1002/aenm.201702646
7. [7]
  B. Senthilkumar, C. Murugesan, L. Sharma, S. Lochab, P. Barpanda, Small Methods 3 (2018) 1800253.
8. [8]
  Y. Sun, S. Guo, H. Zhou, Adv. Energy Mater. 9 (2018) 1800212.
9. [9]
  J. Feng, S. Luo, K. Cai, et al., Chin. Chem. Lett. 33 (2022) 2316–2326. doi: 10.1016/j.cclet.2021.09.077
10. [10]
  A.S. Hameed, M. Ohara, K. Kubota, S. Komaba, J. Mater. Chem. A 9 (2021) 5045–5052. doi: 10.1039/D0TA10517A
11. [11]
  N.T. Aristote, K. Zou, A. Di, et al., Chin. Chem. Lett. 33 (2022) 730–742. doi: 10.1016/j.cclet.2021.08.049
12. [12]
  N.O. Vitoriano, N.E. Drewett, E. Gonzalo, T. Rojo, Energy Environ. Sci. 10 (2017) 1051–1074. doi: 10.1039/C7EE00566K
13. [13]
  C. Vaalma, D. Buchholz, M. Weil, S. Passerini, Nat. Rev. Mater. 3 (2018) 18013. doi: 10.1038/natrevmats.2018.13
14. [14]
  D. Larcher, J.M. Tarascon, Nat. Chem. 7 (2015) 19–29. doi: 10.1038/nchem.2085
15. [15]
  R. Schmuch, R. Wagner, G. Hope, T. Placke, M. Winter, Nat. Energy 3 (2018) 267–278. doi: 10.1038/s41560-018-0107-2
16. [16]
  C. Zhao, F. Ding, Y. Lu, L. Chen, Y.S. Hu, Angew. Chem. Int. Ed. 59 (2020) 264–269. doi: 10.1002/anie.201912171
17. [17]
  C. Yang, S. Xin, L. Mai, Y. You, Adv. Energy Mater. 11 (2020) 2000974.
18. [18]
  Y. Dai, Q. Chen, C. Hu, et al., Chin. Chem. Lett. 33 (2022) 1435–1438. doi: 10.1016/j.cclet.2021.08.050
19. [19]
  R. Zhang, J. Bao, Y. Wang, C.F. Sun, Chem. Sci. 9 (2018) 6193–6198. doi: 10.1039/C8SC01848K
20. [20]
  R.D. Zhang, J.J. Huang, W.Z. Deng, et al., Angew. Chem. Int. Ed. 58 (2019) 16474–16479. doi: 10.1002/anie.201909202
21. [21]
  C. Ho, I. Raistrick, R. Huggins, J. Electrochem. Soc. 127 (1980) 343. doi: 10.1149/1.2129668
22. [22]
  W. Weppner, R.A. Huggins, J. Electrochem. Soc. 12 (1977) 1569–1578.
23. [23]
  D.Y.W. Yu, C. Fietzek, W. Weydanz, et al., J. Electrochem. Soc. 154 (2007) A253–A257. doi: 10.1149/1.2434687
24. [24]
  X. Han, W.J. Zhou, M.F. Chen, et al., Nano Res. 15 (2022) 6156–6167. doi: 10.1007/s12274-022-4242-5
25. [25]
  H.Y. Wang, H.X. Chen, C. Chen, et al., Chin. Chem. Lett. 34 (2023) 107465. doi: 10.1016/j.cclet.2022.04.063
26. [26]
  M.T. Cai, H.H. Zhang, Y.G. Zhang, et al., Sci. Bull. 67 (2022) 933–945. doi: 10.1016/j.scib.2022.02.007
27. [27]
  Q. Zhang, Y.P. Zeng, C.S. Ling, et al., Small 18 (2022) 2107514. doi: 10.1002/smll.202107514
28. [28]
  H.S. Kim, J.B. Cook, H. Lin, et al., Nat. Mater. 16 (2017) 454. doi: 10.1038/nmat4810
29. [29]
  J. Wang, J. Polleux, J. Lim, B. Dunn, J. Phys. Chem. C 111 (2007) 14925. doi: 10.1021/jp074464w
1. [1]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
2. [2]
  Zheng Li , Fangkun Li , Xijun Xu , Jun Zeng , Hangyu Zhang , Lei Xi , Yiwen Wu , Linwei Zhao , Jiahe Chen , Jun Liu , Yanping Huo , Shaomin Ji . A scalable approach to Na₄Fe₃(PO₄)₂P₂O₇@carbon/expanded graphite as cathode for ultralong-lifespan and low-temperature sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110390-. doi: 10.1016/j.cclet.2024.110390
3. [3]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
4. [4]
  Xuan Wang , Peng Sun , Siteng Yuan , Lu Yue , Yufeng Zhao . P2-type low-cost and moisture-stable cathode for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(5): 110015-. doi: 10.1016/j.cclet.2024.110015
5. [5]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
6. [6]
  Liangju Zhao , Shiyu Qin , Fei Wu , Limin Zhu , Qing Han , Lingling Xie , Xuejing Qiu , Hongliang Wei , Lanhua Yi , Xiaoyu Cao . Polycarbonyl conjugated porous polyimide as anode materials for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110246-. doi: 10.1016/j.cclet.2024.110246
7. [7]
  Fanjun Kong , Jing Zhang , Yuting Tang , Chencheng Sun , Chunfu Lin , Tao Zhang , Wangsheng Chu , Li Song , Liang Zhang , Shi Tao . Introducing high-valence element into P2-type layered cathode material for high-rate sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110993-. doi: 10.1016/j.cclet.2025.110993
8. [8]
  Wenya Li , Yuanqi Yang , Yuqing Yang , Min Liang , Huizi Li , Xi Ke , Liying Liu , Yan Sun , Chunsheng Li , Zhicong Shi , Su Ma . Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110388-. doi: 10.1016/j.cclet.2024.110388
9. [9]
  Tong Peng , Yupeng Xing , Lan Mu , Chenggang Wang , Ning Zhao , Wenbo Liao , Jianlei Li , Gang Zhao . Recent research on aqueous zinc-ion batteries and progress in optimizing full-cell performance. Chinese Chemical Letters, 2025, 36(6): 110039-. doi: 10.1016/j.cclet.2024.110039
10. [10]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
11. [11]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
12. [12]
  Chunru Zhao , Yi Liu , Shilong Li , Xiang Wu , Jinghai Liu . PVP decorated H_3.78V₆O₁₃ microspheres assembled by nanosheets for aqueous zinc ion batteries at variable work temperature. Chinese Chemical Letters, 2025, 36(6): 110185-. doi: 10.1016/j.cclet.2024.110185
13. [13]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
14. [14]
  Guang Zeng , Yue Zeng , Huamin Hu , Yaqing Bai , Fangjie Nie , Junfei Duan , Zhaoyong Chen , Qi-Long Zhu . Regulating pore structure and pseudo-graphitic phase of hard carbon anode towards enhanced sodium storage performance. Chinese Chemical Letters, 2025, 36(7): 110122-. doi: 10.1016/j.cclet.2024.110122
15. [15]
  Nan Zhang , Qian Yan , Xiaorui Dong , Jingyang Wang , Fan Jin , Jiaxuan Liu , Dianlong Wang , Huakun Liu , Bo Wang , Shixue Dou . Overcoming electron/ion transport barriers in NASICON-type cathode through mixed-conducting interphase. Chinese Chemical Letters, 2025, 36(9): 110328-. doi: 10.1016/j.cclet.2024.110328
16. [16]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
17. [17]
  Yao Wang , Jun Ouyang , Huadong Yuan , Jianmin Luo , Shihui Zou , Jianwei Nai , Xinyong Tao , Yujing Liu . Impact of local amorphous environment on the diffusion of sodium ions at the solid electrolyte interface in sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110412-. doi: 10.1016/j.cclet.2024.110412
18. [18]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
19. [19]
  Yanxue Wu , Xijun Xu , Shanshan Shi , Fangkun Li , Shaomin Ji , Jingwei Zhao , Jun Liu , Yanping Huo . Facile construction of Cu_2-xSe@C nanobelts as anode for superior sodium-ion storage. Chinese Chemical Letters, 2025, 36(6): 110062-. doi: 10.1016/j.cclet.2024.110062
20. [20]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1561)
HTML views(82)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142