Citation: Jie Lv, Yingling Nong, Kai Chen, Qingyun Wang, Jiamiao Jin, Tingting Li, Zhichao Jin, Yonggui Robin Chi. N-Heterocyclic carbene catalyzed C-acylation reaction for access to linear aminoenones[J]. Chinese Chemical Letters, ;2023, 34(1): 107570. doi: 10.1016/j.cclet.2022.05.084 shu

N-Heterocyclic carbene catalyzed C-acylation reaction for access to linear aminoenones

State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education, Guizhou University, Guiyang 550025, China

zcjin@gzu.edu.cn

robinchi@ntu.edu.sg

Received Date: 22 December 2021
Revised Date: 23 May 2022
Accepted Date: 26 May 2022
Available Online: 29 May 2022

Figures(6)

An N-heterocyclic carbene (NHC)-catalyzed carbonyl nucleophilic substitution reaction between 1-cyclopropylcarbaldehydes and N-sulfonyl imines is developed for access to linear β-aminoenone products. The β-aminoenones containing cyclopropyl fragments can be afforded in moderate to excellent yields under mild conditions. The reaction features excellent trans-diastereoselectivities and the desired aminoenone products are all afforded as Z-isomers.
- N-Heterocyclic carbene,
- Organocatalysis,
- C-Acylation reaction,
- Animoenone synthesis
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