Citation: Qiwen Wang, Wenwen Bu, Zonghang Li, Yu Qi, Xiaohong Wang. PIC catalysis based on polyoxometalates promoting 5-HMF oxidation in H₂O/MIBK biphase[J]. Chinese Chemical Letters, ;2023, 34(5): 107548. doi: 10.1016/j.cclet.2022.05.062 shu

PIC catalysis based on polyoxometalates promoting 5-HMF oxidation in H₂O/MIBK biphase

Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

wangxh665@nenu.edu.cn

Received Date: 6 February 2022
Revised Date: 6 March 2022
Accepted Date: 18 May 2022
Available Online: 21 May 2022

Figures(5)

Novel polyoxometalate (POM) Pickering interfacial catalyst (PIC) was fabricated through loading (NH₄)₅H₆PMo₄V₈O₄₀ (PMo₄V₈) on both alkyl and alkyl-amino groups functionalized silica nanoparticles. PMo₄V₈/SiO₂(C₈/C₈NH₂ with molar ratio as 1:1) PIC system provided a new catalytic model for aerobic conversion of 5-hydroxymethylfurfural (5-HMF), as well as its recovery and product separation in H₂O/methyl isobutyl ketone (MIBK) biphase reaction. Balancing the ratio of PMo₄V₈, C₈ and C₈NH₂ gave rise to variety in hydrophilicity and hydrophobicity for PMo₄V₈/SiO₂(C₈/C₈NH₂), which enhanced the transformation of 5-HMF to 2, 5-diformylfuran (DFF) in H₂O/MIBK with 73.7% yield at 81.8% conversion than in H₂O or MIBK single phase.
- Polyoxometalate,
- Pickering interfacial catalyst,
- 5-Hydroxymethylfurfural,
- 2, 5-Diformylfuran,
- Atmospheric O₂
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沈阳化工大学材料科学与工程学院沈阳 110142

PIC catalysis based on polyoxometalates promoting 5-HMF oxidation in H2O/MIBK biphase

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PIC catalysis based on polyoxometalates promoting 5-HMF oxidation in H₂O/MIBK biphase