Citation: Haoyu Fang, Kai Yong, Boya Wang, Kaipeng Wu, Yun Zhang, Hao Wu. V-substituted pyrochlore-type polyantimonic acid for highly enhanced lithium-ion storage[J]. Chinese Chemical Letters, ;2023, 34(5): 107545. doi: 10.1016/j.cclet.2022.05.059 shu

V-substituted pyrochlore-type polyantimonic acid for highly enhanced lithium-ion storage

College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China

wukaipeng@scu.edu.cn

hao.wu@scu.edu.cn

Received Date: 26 April 2022
Revised Date: 10 May 2022
Accepted Date: 18 May 2022
Available Online: 23 May 2022

Figures(6)

Pyrochlore-structured polyantimonic acid (PAA) is a potential high-capacity electrode material, but its innately poor electroconductivity (~10⁻¹⁰ S/cm) seriously impairs its electrochemical reversibility for lithium-ion storage. Herein, we report design and synthesis of a novel V-substituted PAA (PAA-V), where V⁵⁺ are introduced to partially replace Sb⁵⁺. Owing to identical valence and close ionic radius relative to Sb⁵⁺, the V⁵⁺ cation can constitute the covalent VO₆ octahedra framework without changing the pyrochlore crystal structure of PAA. As a result, the V⁵⁺-substitution is capable to modulate the electronic structure of PAA with significantly improved electrical conductivity (~10⁻⁶ S/cm for PAA-V) and meanwhile decreases the size of crystals with reduced diffusion length for Li⁺-ions. With varying the ratio of V⁵⁺-substitution, the PAA-V with optimized substitution molar ratio (18%) exhibits the best lithium-ion storage performance, delivering a long cycling life with high reversible capacity (731 mAh/g after 1200 cycles at 1 A/g) and outstanding rate capability (279 mAh/g at 15 A/g). More importantly, by pairing the PAA-V as anode and commercial LiFePO₄ as cathode, the full cell with a limited negative/positive capacity ratio of 1.2 exhibits decent cycling stability at 1 C after 150 cycles with 85.5% capacity retention.
- Lithium-ion batteries,
- Anode materials,
- Polyantimonic acid,
- Element substitution,
- Electrochemical reaction mechanism
1. [1]
  N. Nitta, F.X. Wu, J.T. Lee, G. Yushin, Mater. Today 18 (2015) 252-264. doi: 10.1016/j.mattod.2014.10.040
2. [2]
  G. Harper, R. Sommerville, E. Kendrick, et al., Nature 575 (2019) 75-86. doi: 10.1038/s41586-019-1682-5
3. [3]
  M. Winter, B. Barnett, K. Xu, Chem. Rev. 118 (2018) 11433-11456. doi: 10.1021/acs.chemrev.8b00422
4. [4]
  M. Li, J. Lu, Z.W. Chen, K. Amine, Adv. Mater. 30 (2018) 1800561. doi: 10.1002/adma.201800561
5. [5]
  Z.M. Liu, T. Song, U. Paik, J. Mater. Chem. A 6 (2018) 8159-8193. doi: 10.1039/c8ta01782d
6. [6]
  J. He, Y.Q. Wei, T.Y. Zhai, H.Q. Li, Mat. Chem. Front. 2 (2018) 437-455. doi: 10.1039/c7qm00480j
7. [7]
  L.Y. Kovalenko, V.A. Burmistrov, A.A. Biryukova, Russ. J. Electrochem. 52 (2016) 694-698. doi: 10.1134/S1023193516070107
8. [8]
  L.H. Baetsle, D. Huys, J. Inorg. Nucl. Chem. 30 (1968) 639-649. doi: 10.1016/0022-1902(68)80489-0
9. [9]
  T.N. Yu, H.B. Zhang, H.Z. Cao, G.Q. Zheng, Chem. Eng. J. 360 (2019) 313-324. doi: 10.1016/j.cej.2018.11.209
10. [10]
  F. Girardi, E. Sabbioni, J. Radioanal. Chem. 1 (1968) 169-178. doi: 10.1007/BF02530237
11. [11]
  Y.M. Tan, L.J. Chen, H. Chen, Q.L. Hou, X.H. Chen., Mater. Lett. 212 (2018) 103-106. doi: 10.1016/j.matlet.2017.10.080
12. [12]
  X.Z. Zhou, Z.F. Zhang, X.H. Xu, et al., ACS Appl. Mater. Interfaces 8 (2016) 35398-35406. doi: 10.1021/acsami.6b13548
13. [13]
  C.Z. Ke, F. Liu, Z.M. Zheng, et al., Rare Met. 40 (2021) 1347-1356. doi: 10.1007/s12598-021-01716-1
14. [14]
  X.Y. Feng, H.H. Wu, B. Gao, et al., Nano Res. 15 (2022) 352-360. doi: 10.1007/s12274-021-3482-0
15. [15]
  M. Cai, H. Zhang, Y. Zhang, et al., Sci. Bull. 67 (2022) 933-945. doi: 10.1016/j.scib.2022.02.007
16. [16]
  F. Ni, Y. Ma, J. Chen, W. Luo, J. Yang, Chin. Chem. Lett. 32 (2021) 2073-2078. doi: 10.1016/j.cclet.2021.03.042
17. [17]
  B.Y. Wang, Z.W. Deng, Y.T. Xia, et al., Adv. Energy Mater. 10 (2020) 1903119. doi: 10.1002/aenm.201903119
18. [18]
  B.Y. Wang, Y.H. Wei, H.Y. Fang, et al., Adv. Sci. 8 (2021) 2002866. doi: 10.1002/advs.202002866
19. [19]
  H.D. Zhou, C.R. Wiebe, J.A. Janik, et al., J. Solid State Chem. 183 (2010) 890-894. doi: 10.1016/j.jssc.2010.01.025
20. [20]
  K. Ozawa, M. Hase, H. Fujii, et al., Electrochim. Acta 50 (2005) 3205-3209. doi: 10.1016/j.electacta.2004.11.051
21. [21]
  Y.Q. Jia, J. Solid State Chem. 95 (1991) 184-187. doi: 10.1016/0022-4596(91)90388-X
22. [22]
  J. Morales, L. Sanchez, F. Martin, F. Berry, J. Solid State Chem. 179 (2006) 2554-2561. doi: 10.1016/j.jssc.2006.05.003
23. [23]
  Y.T. Hao, Y. Jiang, L.Z. Zhao, et al., ACS Appl. Mater. Interfaces 13 (2021) 21127-21137. doi: 10.1021/acsami.0c21676
24. [24]
  N.N. Wang, Z.C. Bai, Y.T. Qian, J. Yang, Adv. Mater. 28 (2016) 4126-4133. doi: 10.1002/adma.201505918
25. [25]
  X.M. Kang, G.D. Fu, X.W. Wang, et al., Chin. Chem. Lett. 32 (2021) 938-942. doi: 10.1016/j.cclet.2020.06.013
26. [26]
  W.A. England, M.G. Cross, A. Hamnett, P.J. Wiseman, J.B. Goodenough, Solid State Ion. 1 (1980) 231-249. doi: 10.1016/0167-2738(80)90007-7
27. [27]
  R.C. T. Slade, G.P. Hall, A. Ramanan, E. Prince, Solid State Ion. 92 (1996) 171-181. doi: 10.1016/S0167-2738(96)00497-3
28. [28]
  Z.J. Zhang, H.L. Zhao, Y.Q. Teng, et al., Adv. Energy Mater. 8 (2018) 1700174. doi: 10.1002/aenm.201700174
29. [29]
  Y.T. Yan, X.L. Zhao, H.L. Dou, et al., Chin. Chem. Lett. 32 (2021) 910-913. doi: 10.1016/j.cclet.2020.07.021
30. [30]
  C. Chen, Q. Liang, G. Wang, D. Liu, X. Xiong, Adv. Funct. Mater. 32 (2022) 2107249. doi: 10.1002/adfm.202107249
31. [31]
  Q.K. Zhang, X.Q. Zhang, H. Yuan, J.Q. Huang, Small Sci. 1 (2021) 2100058. doi: 10.1002/smsc.202100058
32. [32]
  C. Chen, Q. Liang, Z. Chen, et al., Angew. Chem. Int. Ed. 133 (2021) 26922-26928. doi: 10.1002/ange.202110441
33. [33]
  D. Larcher, A.S. Prakash, L. Laffont, et al., J. Electrochem. Soc. 153 (2006) A1778-A1787. doi: 10.1149/1.2219711
34. [34]
  C.R. Hao, T.G. Gao, A.B. Yuan, J.Q. Xu, Chin. Chem. Lett. 32 (2021) 113-118. doi: 10.1016/j.cclet.2020.11.038
35. [35]
  G. Zhu, R. Guo, W. Luo, et al., Natl. Sci. Rev. 8 (2021) nwaa152. doi: 10.1093/nsr/nwaa152
36. [36]
  F.Z. Zhang, Y.Y. Ma, M.M. Jiang, W. Luo, J.P. Yang, Rare Met. 41 (2022) 1276-1283. doi: 10.1007/s12598-021-01741-0
37. [37]
  P. Jing, Q. Wang, B.Y. Wang, et al., Ceram. Int. 45 (2019) 216-224. doi: 10.1016/j.ceramint.2018.09.154
38. [38]
  C.P. Wang, J.T. Yan, T.Y. Li, et al., Angew. Chem. Int. Ed. 60 (2021) 25013-25019. doi: 10.1002/anie.202110177
39. [39]
  Y. Liu, H.C. Wang, K.K. Yang, et al., Appl. Sci. 9 (2019) 2677. doi: 10.3390/app9132677
40. [40]
  O.A. Jaramillo-Quintero, M. Benitez-Cruz, J.L. Garcia-Ocampo, A. Cano, M.E. Rincon, J. Alloy. Compd. 807 (2019) 151647. doi: 10.1016/j.jallcom.2019.151647
41. [41]
  M.X. Deng, S.J. Li, W.W. Hong, et al., Mater. Chem. Phys. 223 (2019) 46-52. doi: 10.1016/j.matchemphys.2018.10.043
42. [42]
  Q.G. Han, Y.B. Sun, W.Q. Zhang, et al., Ionics 26 (2020) 1221-1228. doi: 10.1007/s11581-019-03300-1
43. [43]
  Y. Li, Z.J. Song, T.T. Sun, et al., Int. J. Hydrog. Energy 46 (2021) 26308-26317. doi: 10.1016/j.ijhydene.2021.05.110
44. [44]
  C. Xian, W. Liang, M. Feng, et al., Nanoscale Adv. (UK)2 (2020) 5578-5583. doi: 10.1039/D0NA00711K
45. [45]
  J.L. Liu, J. Wang, C.H. Xu, et al., Adv. Sci. 5 (2018) 1700322. doi: 10.1002/advs.201700322
46. [46]
  N.T. Wu, J.K. Shen, L. Sun, et al., Electrochim. Acta 310 (2019) 70-77. doi: 10.1016/j.electacta.2019.04.115
47. [47]
  N.T. Wu, W.D. Tian, J.K. Shen, et al., Inorg. Chem. Front. 6 (2019) 192-198. doi: 10.1039/c8qi01165f
48. [48]
  S.B. Tang, M.O. Lai, L. Lu, Mater. Chem. Phys. 111 (2008) 149-153. doi: 10.1016/j.matchemphys.2008.03.041
49. [49]
  Q. Liu, X. Su, D. Lei, et al., Nat. Energy 3 (2018) 936-943. doi: 10.1038/s41560-018-0180-6
50. [50]
  J. Xie, N. Imanishi, T. Matsumura, et al., Solid State Ion. 179 (2008) 362-370. doi: 10.1016/j.ssi.2008.02.051
51. [51]
  B.Y. Wang, Y. Wang, H. Wu, et al., ChemElectroChem 4 (2017) 1141-1147. doi: 10.1002/celc.201600854
52. [52]
  K. Tang, X.Q. Yu, J.P. Sun, H. Li, X.J. Huang, Electrochim. Acta 56 (2011) 4869-4875. doi: 10.1016/j.electacta.2011.02.119
1. [1]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
2. [2]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
3. [3]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
4. [4]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
5. [5]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
6. [6]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
7. [7]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
8. [8]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
9. [9]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
10. [10]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
13. [13]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
14. [14]
  Jia-hui Li , Jinkai Qiu , Cheng Lian . Lithium-ion rapid transport mechanism and channel design in solid electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100381-100381. doi: 10.1016/j.cjsc.2024.100381
15. [15]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
16. [16]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
17. [17]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
18. [18]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
19. [19]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
20. [20]
  Yun Wei , Lei Zhou , Wenbin Hu , Liming Yang , Guang Yang , Chaoqiang Wang , Hui Shi , Fei Han , Yufa Feng , Xuan Ding , Penghui Shao , Xubiao Luo . Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation. Chinese Chemical Letters, 2024, 35(7): 109172-. doi: 10.1016/j.cclet.2023.109172

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(818)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142