Citation: Yuchen Wang, Yaoyu Liu, Ahsan Ejaz, Kai Yan. Temperature-controlled fabrication of hydrophilic manganese oxide microspheres as high-performance electrode materials for supercapacitors[J]. Chinese Chemical Letters, ;2023, 34(5): 107538. doi: 10.1016/j.cclet.2022.05.052 shu

Temperature-controlled fabrication of hydrophilic manganese oxide microspheres as high-performance electrode materials for supercapacitors

Yuchen Wang ^a ,
Yaoyu Liu ^a ,
Ahsan Ejaz ^b ,
Kai Yan ^{a, *,}

a.
Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
b.
Department of Civil Engineering, Mirpur University of Science and Technology, AJK, Mirpur 10250, Pakistan

yank9@mail.sysu.edu.cn

Received Date: 9 May 2022
Accepted Date: 17 May 2022
Available Online: 20 May 2022

Figures(4)

The supercapacitive properties of manganese oxides (MnO_x) are strongly affected by their crystal structure. Nevertheless, the relationship between the crystal structure and supercapacitive performance of MnO_x is elusive. Herein, a temperature-controlled fabrication method was developed to achieve MnO₂, Mn₃O₄, MnO and Mn₂O₃ microspheres with various crystal structure as electrode materials tunable for supercapacitors. The detailed material and electrochemical characterizations revealed the structure-activity relationship of MnO_x microspheres by systematically investigating the effect of valence state, specific surface area, conductivity and morphology on supercapacitive performance. Among these MnO_x materials, nanoneedle-like MnO₂ delivered a relatively high specific capacitance of 274.1 F/g at 1 A/g due to a high Mn valence state of +4, a large specific surface area of 113.4 m²/g and a desirable electronic conductivity of 1.73 × 10^–5 S/cm. Furthermore, MnO₂ presented a remarkable cycle stability with 115% capacitance retention after 10,000 cycles owing to the enhancement of wettability. This work not only provides a facile strategy to modulate MnO_x crystal structure, but also offers a deep understanding of structure-dependent supercapacitive performance of MnO_x.
- Temperature-controlled,
- Manganese oxide,
- Microsphere,
- Supercapacitors,
- Hydrophilic
1. [1]
  L. Lin, J. Chen, D. Liu, et al., Adv. Energy Mater. 10 (2020) 2002621. doi: 10.1002/aenm.202002621
2. [2]
  V. Dusastre, L. Martiradonna, Nat. Mater. 16 (2017) 15. doi: 10.1038/nmat4838
3. [3]
  J. Feng, X. Zhang, Y. Xu, et al., Energy Storage Mater. 46 (2022) 278-288. doi: 10.1016/j.ensm.2022.01.024
4. [4]
  C. Liu, Q. Li, K. Wang, Renew. Sustain. Energy Rev. 150 (2021) 111408. doi: 10.1016/j.rser.2021.111408
5. [5]
  Y. Zhou, H. Qi, J. Yang, et al., Energy Environ. Sci. 14 (2021) 1854-1896. doi: 10.1039/d0ee03167d
6. [6]
  K. Li, X. Liu, T. Zheng, et al., Chem. Eng. J. 370 (2019) 136-147. doi: 10.1016/j.cej.2019.03.190
7. [7]
  A. Zhang, R. Gao, L. Hu, et al., Chem. Eng. J. 417 (2021) 129186. doi: 10.1016/j.cej.2021.129186
8. [8]
  L. Shi, Y. Wang, P. Zou, et al., Chin. Chem. Lett. 29 (2018) 592-595. doi: 10.1016/j.cclet.2018.01.024
9. [9]
  J. Kang, A. Hirata, L. Kang, et al., Angew. Chem. Int. Ed. 52 (2013) 1664-1667. doi: 10.1002/anie.201208993
10. [10]
  P. Guillemet, T. Brousse, O. Crosnier, et al., Electrochim. Acta 67 (2012) 41-49. doi: 10.1016/j.electacta.2012.01.110
11. [11]
  Y. Wu, C. Cao, Sci. China Mater. 61 (2018) 1517-1526. doi: 10.1007/s40843-018-9290-y
12. [12]
  Y. Hu, Y. Wu, J. Wang, Adv. Mater. 30 (2018) 1802569. doi: 10.1002/adma.201802569
13. [13]
  Y. Liu, X. Wu, Chin. Chem. Lett. 33 (2022) 1236-1244. doi: 10.1016/j.cclet.2021.08.081
14. [14]
  L. Wei, Z. Wang, Y. Liu, et al., J. Hazard. Mater. 416 (2021) 126117. doi: 10.1016/j.jhazmat.2021.126117
15. [15]
  S. Devaraj, N. Munichandraiah, J. Phys. Chem. C 112 (2008) 4406-4417. doi: 10.1021/jp7108785
16. [16]
  Y. Hu, Y. Zhang, D. Yuan, et al., Nanoscale Horiz. 2 (2017) 326-332. doi: 10.1039/C7NH00078B
17. [17]
  A. Zhang, R. Zhao, L. Hu, et al., Adv. Energy Mater. 11 (2021) 2101412. doi: 10.1002/aenm.202101412
18. [18]
  A. Wang, H. Wang, H. Deng, et al., Appl. Catal. B Environ. 248 (2019) 298-308. doi: 10.1016/j.apcatb.2019.02.034
19. [19]
  N. Li, X. Zhu, C. Zhang, et al., J. Alloy. Compd. 692 (2017) 26-33. doi: 10.1016/j.jallcom.2016.08.321
20. [20]
  D. Gangwar, C. Rath, Phys. Chem. Chem. Phys. 22 (2020) 14236-14245. doi: 10.1039/d0cp02245d
21. [21]
  T. Falk, S. Anke, H. Hajiyani, et al., Catal. Sci. Technol. 11 (2021) 7552-7562. doi: 10.1039/d1cy00944c
22. [22]
  L. Mo, H. Zheng, J. Alloy. Compd. 788 (2019) 1162-1168. doi: 10.1016/j.jallcom.2019.02.321
23. [23]
  Z. Cui, Q. Liu, C. Xu, et al., J. Mater. Chem. A 5 (2017) 21699-21708. doi: 10.1039/C7TA05986H
24. [24]
  S. Liu, Y. Liang, W. Zhou, et al., J. Mater. Chem. A 6 (2018) 12046-12055. doi: 10.1039/C8TA02838A
25. [25]
  L. Liu, Y. Luo, W. Tan, et al., J. Colloid Interface Sci. 482 (2016) 183-192. doi: 10.1016/j.jcis.2016.07.077
26. [26]
  J.U. Choi, J. Kim, J.Y. Hwang, et al., Nano Energy 61 (2019) 284-294. doi: 10.1016/j.nanoen.2019.04.062
27. [27]
  Q. Zhang, M.D. Levi, Q. Dou, et al., Adv. Energy Mater. 9 (2019) 1802707. doi: 10.1002/aenm.201802707
28. [28]
  Y. Mao, Y. Chen, J. Qin, et al., Nano Energy 58 (2019) 192-201. doi: 10.1016/j.nanoen.2019.01.048
29. [29]
  S.M. Ingole, S.T. Navale, Y.H. Navale, et al., J. Solid State Electrochem. 21 (2017) 1817-1826. doi: 10.1007/s10008-017-3557-8
30. [30]
  G. Zhang, L. Ren, Z. Yan, et al., Chem. Commun. 53 (2017) 2950-2953. doi: 10.1039/C6CC10250F
31. [31]
  Y. Wang, Y. Liu, Z. Chen, et al., Green Chem. Eng. 3 (2022) 55-63. doi: 10.1117/12.2645475
32. [32]
  Y. Zhang, M. Park, H.Y. Kim, S.J. Park, J. Colloid Interface. Sci. 500 (2017) 155-163. doi: 10.1016/j.jcis.2017.04.022
1. [1]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
2. [2]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
3. [3]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
4. [4]
  Zixu Xie , Pengfei Zhang , Ziyao Zhang , Chen Chen , Xing Wang . The choice of antimicrobial polymers: Hydrophilic or hydrophobic?. Chinese Chemical Letters, 2024, 35(9): 109768-. doi: 10.1016/j.cclet.2024.109768
5. [5]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
6. [6]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
7. [7]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
8. [8]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
9. [9]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
10. [10]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
11. [11]
  Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
12. [12]
  Yanqi Wu , Yuhong Guan , Peilin Huang , Hui Chen , Liping Bai , Zhihong Jiang . Preparation of norovirus GII loop mediated isothermal amplification freeze-drying microsphere reagents and its application in an on-site integrated rapid detection platform. Chinese Chemical Letters, 2024, 35(9): 109308-. doi: 10.1016/j.cclet.2023.109308
13. [13]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
14. [14]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
15. [15]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
16. [16]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
17. [17]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
18. [18]
  Yunlong Sun , Wei Ding , Yanhao Wang , Zhening Zhang , Ruyun Wang , Yinghui Guo , Zhiyuan Gao , Haiyan Du , Dong Ma . New insight into manganese-enhanced abiotic degradation of microplastics: Processes and mechanisms. Chinese Chemical Letters, 2025, 36(3): 109941-. doi: 10.1016/j.cclet.2024.109941
19. [19]
  Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
20. [20]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1097)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142