Citation: Hui Zhang, Jianchen Lu, Yong Zhang, Lei Gao, Xin-Jing Zhao, Yuan-Zhi Tan, Jinming Cai. Magnetism engineering of nanographene: An enrichment strategy by co-depositing diverse precursors on Au(111)[J]. Chinese Chemical Letters, ;2023, 34(1): 107450. doi: 10.1016/j.cclet.2022.04.048 shu

Magnetism engineering of nanographene: An enrichment strategy by co-depositing diverse precursors on Au(111)

Hui Zhang ^{a, 1} ,
Jianchen Lu ^{a, 1} ,
Yong Zhang ^a ,
Lei Gao ^b ,
Xin-Jing Zhao ^{c, *,} ,
Yuan-Zhi Tan ^c ,
Jinming Cai ^{a, *,}

a.
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
Faculty of Science, Kunming University of Science and Technology, Kunming 650500, China
c.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

zhaoxinjing@xmu.edu.cn

j.cai@kust.edu.cn

Received Date: 9 February 2022
Revised Date: 11 April 2022
Accepted Date: 18 April 2022
Available Online: 22 April 2022

Figures(4)

The magnetism of nanographene is dominated by the structure of its carbon skeleton. However, the magnetism engineering of nanographene is hindered due to finite precursors. Here, we demonstrate an ingenious synthetic strategy to engineer the magnetism of nanographene through hetero-coupling two precursors on Au(111) surface. Bond-resolved scanning tunneling microscopy and spectroscopy results show that two homo-coupled products host a closed-shell structure, while the products with five membered ring defects perform as an open-shell one with the total spin number of 1/2, confirmed by spin-polarized density functional theory calculations. While two hetero precursors on Au(111) substrate, the hetero-coupled products both perform as the magnetic structure with total spin quantum numbers of 1/2 and 1, resulting from carbon skeleton transformations. Our work provides an effective way to engineer the magnetism of nanographene by enriching the magnetic products simultaneous, which could be extended into other controllable magnetic nanographene instruction.
- Nanographene,
- Magnetism enrichment,
- Co-deposition,
- Scanning tunneling microscope
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