Citation: Meilin Wang, Yinjuan Guo, Guiyan Zhao, Baokuan Chen, Yanfeng Bi. Ni₄-thiacalix[4]arene sandwiched Mo₈ polyoxometalate bimetallic nanoclusters for electrocatalytic glucose oxidation[J]. Chinese Chemical Letters, ;2023, 34(3): 107365. doi: 10.1016/j.cclet.2022.03.088 shu

Ni₄-thiacalix[4]arene sandwiched Mo₈ polyoxometalate bimetallic nanoclusters for electrocatalytic glucose oxidation

School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China

biyanfeng@lnpu.edu.cn

Received Date: 9 March 2022
Revised Date: 20 March 2022
Accepted Date: 21 March 2022
Available Online: 24 March 2022

Figures(5)

Available online two new Ni₈Mo₈ bimetallic coordination clusters, [Ni₄(TC4A)]₂[(Mo₅^ⅤMo₃^ⅥO₂₄)(PO₄)] (+Solvent) (Ni₈PMo₈, H₄TC4A= p-tert-butylthiacalix[4]arene) and [Ni₄(TC4A)]₂[(Mo₅^ⅤMo₃^ⅥO₂₄)(OH)(CO₃)] (+Solvent) (Ni₈Mo₈), were synthesized by solvothermal method and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy, and TGA experiments, respectively. The usage of H₃PMo₁₂O₄₀ as source for Ni₈PMo₈ resulted a sandwich like structure built from two Ni₄-thiacalix[4]arene units and a Mo₈ polyoxometalate with inner spaces of PO₄³⁻. Ni₈Mo₈ with the similar structure to that of Ni₈PMo₈ is from H₂MoO₄ starting reagent with OH⁻ and CO₃²⁻ anions encapsulated in the center. The two clusters can be directly loaded on carbon paper and utilized as working electrodes which showed distinguishable performances for glucose detection and oxidation. This work provides a better understanding of the structure–property relationships in using substituted polyoxometalates for electrochemical applications and is helpful for building calixarene-based or polyoxometalate-based functional materials.
- Thiacalix[4]arene,
- Substituted polyoxometalates,
- Bimetallic nanocluster,
- Crystal structure,
- Glucose oxidation
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Ni4-thiacalix[4]arene sandwiched Mo8 polyoxometalate bimetallic nanoclusters for electrocatalytic glucose oxidation

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通讯作者: 陈斌, bchen63@163.com

Ni₄-thiacalix[4]arene sandwiched Mo₈ polyoxometalate bimetallic nanoclusters for electrocatalytic glucose oxidation