Citation: Xiaofei Xie, Lei Wang, Quan Zhou, Yongmin Ma, Zhi-Ming Wang, Pinhua Li. Visible-light-induced novel cyclization of 2-(2-(arylethynyl)benzylidene)-malononitrile derivatives with 2,6-di(tert-butyl)-4-methylphenol to bridged spirocyclic compounds[J]. Chinese Chemical Letters, ;2022, 33(12): 5069-5073. doi: 10.1016/j.cclet.2022.03.084 shu

Visible-light-induced novel cyclization of 2-(2-(arylethynyl)benzylidene)-malononitrile derivatives with 2,6-di(tert-butyl)-4-methylphenol to bridged spirocyclic compounds

Xiaofei Xie ^a ,
Lei Wang ^{a, c, *,} ,
Quan Zhou ^a ,
Yongmin Ma ^a ,
Zhi-Ming Wang ^a ,
Pinhua Li ^{b, c, *,}

a.
Advanced Research Institute and Department of Chemistry, Taizhou University, Taizhou 318000, China
b.
Department of Chemistry, Anhui Polytechnic University, Wuhu 241000, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, China

leiwang@chnu.edu.cn

pphuali@126.com

Received Date: 14 December 2021
Revised Date: 18 March 2022
Accepted Date: 20 March 2022
Available Online: 23 March 2022

Figures(5)

A green and highly efficient strategy for the preparation of bridged spirocyclic compounds via visible-light-induced cyclization of 2-(2-(arylethynyl)benzylidene)malononitrile derivatives with 2,6-di(tert-butyl)-4-methylphenol (BHT) at room temperature was developed. The photoinduced radical reactions generated the corresponding products in good yields under simple and mild reaction conditions.
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