Citation: Xiaoni Qi, Weichun Li, Bingbing Shi, Youming Zhang, Hong Yao, Qi Lin, Taibao Wei. Fabricating a novel supramolecular light-activated platform based on internal-driven forces induced by the UV-light[J]. Chinese Chemical Letters, ;2022, 33(12): 5065-5068. doi: 10.1016/j.cclet.2022.03.081 shu

Fabricating a novel supramolecular light-activated platform based on internal-driven forces induced by the UV-light

Key Laboratory of Eco-Environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

weitaibao@126.com

Received Date: 15 December 2021
Revised Date: 18 March 2022
Accepted Date: 20 March 2022
Available Online: 24 March 2022

Figures(6)

Recently, exploiting a novel supramolecular fabrication pathway have drawn great attention. To this endeavor, we firstly designed and reported an original light-activated platform based on the internal-driven forces of macrocyclic host by hiring the pillar[5]arene as the host molecule (H) and phenazine derivatives acting as an energetic guest molecule (G). Surprisingly, after adding the H solution into G system, the intensive fluorescence emission of the G molecule rapidly decreased under the irradiation of the UV-light (254 nm) until absolutely quenching. Delightfully, different from the traditional supramolecular host-guest interaction, the fluorescent emission of G molecule could be recovered after irradiating under the nature light. In view of this interesting observations, the interaction mechanism was carefully investigated by a series of characterizations. Those results suggested that the G molecule was easily threaded into the macrocyclic cavity (H) under the internal-driven forces induced by the UV-light irradiation, forming a 1:1 host-guest complex. Moreover, taking advantage of this especial feature, the light-activated platform of host–guest complex was further applied for ink-free light-driven printing materials, exhibiting great potential in the real application.
- Light-activated platform,
- Pillar[5]arene,
- Phenazine derivatives,
- Internal-driven forces,
- UV-light
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