Citation: Meng Li, Xinzhong Wang, Yelin Zhu, Xiuxiu Jia, Shusheng Zhang, Huaisheng Wang, Yongtao Li, Guangzhi Hu. Fe₂O₃-decorated boron/nitrogen-co-doped carbon nanosheets as an electrochemical sensing platform for ultrasensitive determination of paraquat in natural water[J]. Chinese Chemical Letters, ;2023, 34(1): 107299. doi: 10.1016/j.cclet.2022.03.022 shu

Fe₂O₃-decorated boron/nitrogen-co-doped carbon nanosheets as an electrochemical sensing platform for ultrasensitive determination of paraquat in natural water

Meng Li ^{a, b} ,
Xinzhong Wang ^{a, *,} ,
Yelin Zhu ^c ,
Xiuxiu Jia ^c ,
Shusheng Zhang ^{b, *,} ,
Huaisheng Wang ^d ,
Yongtao Li ^e ,
Guangzhi Hu ^{a, c, **,}

a.
School of Electronic Communication Technology, Shenzhen Institute of Information Technology, Shenzhen 518172, China
b.
College of Chemistry, Zhengzhou University, Zhengzhou 450000, China
c.
Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Kunming 650504, China
d.
School of Materials Science and Engineering, Liaocheng University, Liaocheng 252000, China
e.
Joint Institute for Environmental Research and Education, College of resources and environment, South China Agricultural University, Guangzhou 510642, China

^**

wangxz@sziit.com.cn

szz@126.com

guangzhihu@ynu.edu.cn

Received Date: 14 December 2021
Revised Date: 23 January 2022
Accepted Date: 4 March 2022
Available Online: 7 March 2022

Figures(6)

Boron/nitrogen-co-doped carbon (BCN) nanosheets decorated with Fe₂O₃ nanocrystals (Fe₂O₃–BCN) were cast on a glassy carbon electrode (GCE) and applied as an electrochemical sensor to effectively detect paraquat (PQ), a toxic herbicide, in aqueous environments. A linear experiment performed using square wave voltammetry (SWV) under optimized experimental conditions produced a decent linear relationship and a low detection limit (LOD) of 2.74 nmol/L (S/N = 3). Repeatability, reproducibility, stability, and interference experiments confirmed that the Fe₂O₃–BCN/GCE system exhibited decent electrochemical sensing performance for PQ molecules. Notably, the designed sensor showed high selectivity and a decent linear relationship with PQ concentration in natural water samples. To the best of our knowledge, this is the first study on the preparation of Fe₂O₃–BCN nanosheets for PQ detection. The proposed sensor can be employed as an effective alternative tool for distinguishing and processing PQ.
- Paraquat,
- Fe₂O₃–BCN,
- Electrochemical sensor,
- Contaminant detection
1. [1]
  H. Zhang, K.-.T. Huang, L. Ding, et al., Chin. Chem. Lett. 30 (2021) 9–54.
2. [2]
  H.T. Xi, T.T. Yi, X.Q. Sun, Chin. Chem. Lett. 21 (2010) 633–636. doi: 10.1016/j.cclet.2010.01.028
3. [3]
  J. Chen, Y. Su, F. Lin, et al., Ecotoxicol. Environ. Saf. 224 (2021) 112711. doi: 10.1016/j.ecoenv.2021.112711
4. [4]
  Q.Q. Li, Y.P. Du, Y. Xu, et al., Chin. Chem. Lett. 24 (2013) 332–334. doi: 10.1016/j.cclet.2013.02.002
5. [5]
  T.M. Wijerathna, F. Mohamed, I.B. Gawarammana, et al., Ecotoxicol. Environ. Saf. 80 (2020) 103510.
6. [6]
  N. Halim, A. Kuntom, R. Shinde, K. Banerjee, Eur. J. Lipid. Sci. Technol. 121 (2019) 1900092. doi: 10.1002/ejlt.201900092
7. [7]
  H. Lu, J. Yu, L. Wu, et al., J. Chromatogr. B 1027 (2016) 96–102. doi: 10.1016/j.jchromb.2016.05.030
8. [8]
  G.F. Xia, X.Y. Fang, Y.R. Wang, X.Y. Yang, Anal. Lett. 50 (2017) 787–796. doi: 10.1080/00032719.2016.1197233
9. [9]
  M.K. Rai, J.V. Das, V.K. Gupta, Talanta 45 (1997) 343–348. doi: 10.1016/S0039-9140(97)00136-7
10. [10]
  B. Zhao, Q. Yang, J.S. Wang, et al., New J. Chem. 45 (2021) 4401–4407. doi: 10.1039/D0NJ05866A
11. [11]
  A.P. Vu, T.N. Nguyen, T.T. Do, et al., J. Chromatogr. B 1060 (2017) 111–117. doi: 10.1016/j.jchromb.2017.06.010
12. [12]
  S. Ali, M.R. Shah, S. Hussain, et al., J. Clust. Sci. 33 (2021) 413–420. doi: 10.21608/epsj.2021.182516
13. [13]
  H. Karimi-Maleh, M.L. Yola, N. Atar, et al., J. Colloid Interface Sci. 592 (2021) 174–185. doi: 10.1016/j.jcis.2021.02.066
14. [14]
  C. Karaman, O. Karaman, B.B. Yola, et al., New J. Chem. 45 (2021) 11222–11233. doi: 10.1039/D1NJ02293H
15. [15]
  J. Su, S. Zhang, Q. Liu, G. Hu, L. Zhang, J. Mater. Chem. A 9 (2021) 5276–5295. doi: 10.1039/D0TA12447H
16. [16]
  X. Zhao, X. Li, Z. Bi, et al., J. Energy Chem. 66 (2022) 514–524. doi: 10.1016/j.jechem.2021.08.067
17. [17]
  P. Ding, J. Niu, F. Chang, et al., Chin. Chem. Lett. 32 (2021) 2495–2498. doi: 10.1016/j.cclet.2020.12.063
18. [18]
  F.Y. Kong, R.F. Li, L. Yao, et al., Nanotechnology 30 (2019) 285502. doi: 10.1088/1361-6528/ab10ac
19. [19]
  X. Shan, J. de Dieu Habimana, J. Ji, et al., J. Solid State Electr. 23 (2019) 1211–1220. doi: 10.1007/s10008-018-04192-3
20. [20]
  S. Thomas, M. Asle Zaeem, Phys. Chem. Chem. Phys. 22 (2020) 22066–22077. doi: 10.1039/D0CP02973D
21. [21]
  J. Yu, C. He, C. Pu, et al., Chin. Chem. Lett. 32 (2021) 3149–3154. doi: 10.1016/j.cclet.2021.02.046
22. [22]
  J. Jiang, P. Nie, S. Fang, et al., Chin. Chem. Lett. 29 (2018) 624–628. doi: 10.1016/j.cclet.2018.01.029
23. [23]
  H. Chakraborty, S. Mogurampelly, V.K. Yadav, U.V. Waghmare, M.L. Klein, Nanoscale 10 (2018) 22148–22154. doi: 10.1039/C8NR07373B
24. [24]
  A. Prakash, K.B. Sundaram, Appl. Surf. Sci. 396 (2017) 484–491. doi: 10.1016/j.apsusc.2016.10.180
25. [25]
  J. Houska, P. Steidl, J. Vlcek, J. Martan, Ceram. Int. 42 (2016) 4361–4369. doi: 10.1016/j.ceramint.2015.11.115
26. [26]
  X. Zhao, M. Zheng, Z. Zhang, et al., J. Mater. Chem. A 9 (2021) 16427–16435. doi: 10.1039/D1TA04142H
27. [27]
  X. Zhao, Z. Yang, A.V. Kuklin, et al., ACS Appl. Mater. Interfaces 12 (2020) 31419–31430. doi: 10.1021/acsami.0c06649
28. [28]
  F. Ni, Y. Ma, J. Chen, W. Luo, J. Yang, Chin. Chem. Lett. 32 (2021) 2073–2078. doi: 10.1016/j.cclet.2021.03.042
29. [29]
  M. Zheng, T. Yuan, J. Shi, W. Cai, X. Wang, ACS Catal. 9 (2019) 8068–8072. doi: 10.1021/acscatal.9b02550
30. [30]
  X. Zhao, C. Xiang, F. Zhang, et al., ACS Appl. Mater. Interfaces 11 (2019) 43214–43222. doi: 10.1021/acsami.9b15395
31. [31]
  Z. Chen, M. Lu, Sens. Actuators B: Chem. 273 (2018) 253–259. doi: 10.1016/j.snb.2018.06.053
32. [32]
  M. Li, X. Peng, X. Liu, et al., RSC Adv. 11 (2021) 28988–28995. doi: 10.1039/D1RA05517H
33. [33]
  Y. Zhu, X. Wang, P. Wang, et al., Ecotox. Environ. Saf. 225 (2021) 112745. doi: 10.1016/j.ecoenv.2021.112745
34. [34]
  F. Ma, M. Wang, Y. Shao, et al., J. Mater. Chem. C 5 (2017) 2559–2565. doi: 10.1039/C7TC00131B
35. [35]
  A.A. Moya, J. Phys. Chem. C 120 (2016) 6543–6552. doi: 10.1021/acs.jpcc.5b12087
36. [36]
  L.J. Chang, S.H. Luo, H.L. Zhang, et al., Chin. Chem. Lett. 25 (2014) 1569–1572. doi: 10.1016/j.cclet.2014.09.002
37. [37]
  K. Ariyoshi, M. Tanimoto, Y. Yamada, Electrochim. Acta 364 (2020) 137292. doi: 10.1016/j.electacta.2020.137292
38. [38]
  H. Huang, L. Kong, W. Shuang, et al., Chin. Chem. Lett. 33 (2021) 1037–1041. doi: 10.3390/catal11091037
39. [39]
  M.S. Pontes, D.R. Antunes, I.P. Oliveira, et al., Environ. Sci. Nano 8 (2021) 1336–1351. doi: 10.1039/d0en01128b
40. [40]
  S. Vinoth, P. Mary Rajaitha, A. Pandikumar, Compos. Sci. Technol. 195 (2020) 108192. doi: 10.1016/j.compscitech.2020.108192
41. [41]
  T. Morooka, H. Tahara, T. Sagara, Electrochim. Acta 251 (2017) 355–362. doi: 10.1016/j.electacta.2017.08.133
42. [42]
  J. Tashkhourian, M. Daneshi, F. Nami-Ana, M. Behbahani, A. Bagheri, J. Hazard. Mater. 318 (2016) 117–124.
43. [43]
  H. Hou, B. Wang, Int. J. Quantum Chem. 121 (2021) e26757.
44. [44]
  P.Y. Tang, L.J. Han, F.S. Hegner, et al., Adv. Energy Mater. 9 (2019) 1901836. doi: 10.1002/aenm.201901836
45. [45]
  J. Fangmeyer, A. Behrens, B. Gleede, S.R. Waldvogel, U. Karst, Angew. Chem. Int. Ed. 59 (2020) 20428–20433. doi: 10.1002/anie.202010134
46. [46]
  J. Zhang, Z. Lin, Y. Qin, et al., ACS Omega 4 (2019) 18398–18404. doi: 10.1021/acsomega.9b02658
47. [47]
  T. Nasir, G. Herzog, M. Hébrant, et al., ACS Sens. 3 (2018) 484–493. doi: 10.1021/acssensors.7b00920
48. [48]
  P.B. Deroco, D. Wachholz Junior, L.T. Kubota, Chemosensors 9 (2021) 61. doi: 10.3390/chemosensors9040061
49. [49]
  M. Ghalkhani, S. Maghsoudi, R. Saeedi, S.S. Khaloo, J. Iran. Chem. Soc. 16 (2019) 1301–1309. doi: 10.1007/s13738-019-01605-6
50. [50]
  L.C.S. de Figueiredo-Filho, M. Baccarin, B.C. Janegitz, O. Fatibello-Filho, Sens. Actuators B: Chem. 240 (2017) 749–756. doi: 10.1016/j.snb.2016.08.157
51. [51]
  J. Li, W. Lei, Y. Xu, et al., Electrochim. Acta 174 (2015) 464–471. doi: 10.1016/j.electacta.2015.06.028
52. [52]
  M.A. El Mhammedi, M. Bakasse, A. Chtaini, Electroanalysis 19 (2007) 1727–1733. doi: 10.1002/elan.200703927
53. [53]
  K. Charoenkitamorn, C. Chotsuwan, S. Chaiyo, W. Siangproh, O. Chailapakul, Sens. Actuat. B: Chem. 315 (2020) 128089. doi: 10.1016/j.snb.2020.128089
1. [1]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
2. [2]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
3. [3]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
4. [4]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
5. [5]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
6. [6]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
7. [7]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
8. [8]
  Yijian Zhao , Jvzhe Li , Yunyi Shi , Jie Hu , Meiyi Liu , Yao Shen , Xinglin Hou , Qiuyue Wang , Qi Wang , Zhiyi Yao . A label-free and ratiometric fluorescent sensor based on porphyrin-metal-organic frameworks for sensitive detection of ochratoxin A in cereal. Chinese Chemical Letters, 2025, 36(4): 110132-. doi: 10.1016/j.cclet.2024.110132
9. [9]
  Ren Shen , Yanmei Fang , Chunxiao Yang , Quande Wei , Pui-In Mak , Rui P. Martins , Yanwei Jia . UV-assisted ratiometric fluorescence sensor for one-pot visual detection of Salmonella. Chinese Chemical Letters, 2025, 36(4): 110143-. doi: 10.1016/j.cclet.2024.110143
10. [10]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
11. [11]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
12. [12]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
13. [13]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
14. [14]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
15. [15]
  Junying LI , Xinyan CHEN , Xihui DIAO , Muhammad Yaseen , Chao CHEN , Hao WANG , Chuansong QI , Wei LI . Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084
16. [16]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
17. [17]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
18. [18]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
19. [19]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
20. [20]
  Xubin Qian , Lei Xu , Xu Ge , Zhun Liu , Cheng Fang , Jianbing Wang , Junfeng Niu . Can perfluorooctanoic acid be effectively degraded using β-PbO₂ reactive electrochemical membrane?. Chinese Chemical Letters, 2024, 35(7): 109218-. doi: 10.1016/j.cclet.2023.109218

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(634)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fe2O3-decorated boron/nitrogen-co-doped carbon nanosheets as an electrochemical sensing platform for ultrasensitive determination of paraquat in natural water

Metrics

通讯作者: 陈斌, bchen63@163.com

Fe₂O₃-decorated boron/nitrogen-co-doped carbon nanosheets as an electrochemical sensing platform for ultrasensitive determination of paraquat in natural water