Citation: Sijian Chen, Huanxi Zhao, Lili Jiao, Zhenhuan Wang, Mengya Zhao, Lu Tian, Yang Xiu, Shuying Liu. Facile detection of pesticides using atmospheric pressure matrix-assisted laser desorption ionization mass spectrometry with multi-walled carbon nanotubes-based matrix[J]. Chinese Chemical Letters, ;2023, 34(1): 107286. doi: 10.1016/j.cclet.2022.03.009 shu

Facile detection of pesticides using atmospheric pressure matrix-assisted laser desorption ionization mass spectrometry with multi-walled carbon nanotubes-based matrix

Sijian Chen ^a ,
Huanxi Zhao ^a ,
Lili Jiao ^a ,
Zhenhuan Wang ^a ,
Mengya Zhao ^a ,
Lu Tian ^a ,
Yang Xiu ^{a, *,} ,
Shuying Liu ^{a, b, *,}

a.
Jilin Ginseng Academy, Changchun University of Chinese Medicine, Changchun 130117, China
b.
Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, China

ys830805@sina.com

10.1016/j.cclet.2022.03.009

Received Date: 30 November 2021
Revised Date: 24 January 2022
Accepted Date: 2 March 2022
Available Online: 7 March 2022

Figures(3)

A novel atmospheric pressure matrix-assisted laser desorption ionization mass spectrometry (AP-MALDI-MS) method was established for the facile detection of pesticides in ambient environment. Four kinds of multi-walled carbon nanotubes (MWCNTs)-based matrix were synthesized and utilized to enhance the ionization efficiency of pesticides. Organophosphorus, anilinopyrimidine, carbamate, triazine, triazole and benzimidazole pesticides were directly desorbed and ionized from MWCNTs-based matrix in ambient environment, showing clear background and good sensitivity. In a comparison, Fe₃O₄-doped MWCNTs improved the intensity of pesticide ions more than the other three matrices. Moreover, MWCNTs-based matrix exhibited better performance than organic matrix. Quantitative analysis of pesticides using AP-MALDI-MS was validated to be adequate linearity, repeatability and sensitivity. Overall, AP-MALDI-MS combined with MWCNTs-based matrix enables the directly qualitative and quantitative analysis of pesticides in ambient environment.
- Atmospheric pressure MALDI,
- Pesticides,
- MWCNTs-based matrix,
- Ambient ionization
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