Citation: Qinglei Meng, Xian Wang, Meiling Xiao, Zhao Jin, Junjie Ge, Changpeng Liu, Wei Xing. Revealing the true origin of size-dependent Pd/C catalytic behavior towards formic acid decomposition[J]. Chinese Chemical Letters, ;2023, 34(1): 107221. doi: 10.1016/j.cclet.2022.02.026 shu

Revealing the true origin of size-dependent Pd/C catalytic behavior towards formic acid decomposition

Qinglei Meng ^{a, b, c} ,
Xian Wang ^{a, b, c} ,
Meiling Xiao ^{a, b, c} ,
Zhao Jin ^{a, b, c} ,
Junjie Ge ^{a, b, c, d, *,} ,
Changpeng Liu ^{a, b, c, d, *,} ,
Wei Xing ^{a, b, c, d, *,}

a.
Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Science and Technology of China, Hefei 230026, China
c.
Jilin Province Key Laboratory of Low Carbon Chemical Power Sources, Changchun 130022, China
d.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

gejj@ciac.ac.cn

liuchp@ciac.ac.cn

xingwei@ciac.ac.cn

Received Date: 1 December 2021
Revised Date: 10 January 2022
Accepted Date: 13 February 2022
Available Online: 15 February 2022

Figures(3)

Formic acid decomposition (FAD) is considered a promising hydrogen production route to facilitate the ambient storage and on demand release of hydrogen energy. To optimize the catalysts for FAD, efforts have been paid to explore the underlying reason for the varied catalytic activity among catalysts with similar composition but differed structure. However, such endeavors are highly challenging due to the deeply intermingled effects of electronic structure, particle size, and facets, etc. Herein, to separately evaluate the respective effects of these factors, a series of catalysts with the same surface electronic structure and different particle size was prepared by cation dipole adjustment method. The performance and characterization results showed that the catalysts with different sizes and facets exhibited similar intrinsic activity with deviation of less than 5%. However, they showed 252% deviation of site stability, indicating that only the optimized electronic structure could enhance the intrinsic activity and a smaller particle size could extend the catalyst's life.
- Hydrogen production,
- Formic acid,
- Catalyst deactivation,
- Size effect,
- Facets effect
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