Citation: Shuandi Wang, Xiaodong Zhang, Guozhu Chen, Bao Liu, Hongmei Li, Junhua Hu, Junwei Fu, Min Liu. Hydroxyl radical induced from hydrogen peroxide by cobalt manganese oxides for ciprofloxacin degradation[J]. Chinese Chemical Letters, ;2022, 33(12): 5208-5212. doi: 10.1016/j.cclet.2022.01.055 shu

Hydroxyl radical induced from hydrogen peroxide by cobalt manganese oxides for ciprofloxacin degradation

Shuandi Wang ^a ,
Xiaodong Zhang ^a ,
Guozhu Chen ^a ,
Bao Liu ^a ,
Hongmei Li ^a ,
Junhua Hu ^b ,
Junwei Fu ^{a, *,} ,
Min Liu ^{a, *,}

a.
Hunan Joint International Research Center for Carbon Dioxide Resource Utilization, School of Physics and Electronics, State Key Laboratory of Powder Metallurgy, Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha 410083, China
b.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China

fujunwei@csu.edu.cn

minliu@csu.edu.cn

Received Date: 30 September 2021
Revised Date: 5 December 2021
Accepted Date: 19 January 2022
Available Online: 25 January 2022

Figures(5)

Advanced oxidation processes (AOPs) are promising technology to remove organic pollutant in water. However, the main problem in the AOPs is the low generation of hydroxyl radical (^•OH) owing to the low decomposition efficiency of hydrogen peroxide (H₂O₂). Herein, the spinel type cobalt acid manganese (MnCo₂O₄) with flower morphology was fabricated through a co-precipitation method. In situ Fourier transform infrared spectroscopy confirms that the MnCo₂O₄ with the optimal molar ratio of Co and Mn precursors (CM3, Co: Mn = 3) has more Lewis acid sites compared with single metal oxide catalysts (Co₃O₄ and Mn₂O₃), leading to the excellent performances for H₂O₂ decomposition rate constant on CM3, which is about 15.03 and 4.21 times higher than those of Co₃O₄ and Mn₂O₃, respectively. As a result, the obtained CM3 shows a higher ciprofloxacin degradation ratio than that of Co₃O₄ and Mn₂O₃. Furthermore, CM3 shows an excellent stability during several cycles. This work proposes effective catalysts for ciprofloxacin decomposition and provides feasible route for treating practical environmental problems.
- Catalytic decomposition,
- Hydrogen peroxide,
- Advanced oxidation processes,
- Ciprofloxacin,
- Pollutant degradation
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