Citation: Shuandi Wang, Xiaodong Zhang, Guozhu Chen, Bao Liu, Hongmei Li, Junhua Hu, Junwei Fu, Min Liu. Hydroxyl radical induced from hydrogen peroxide by cobalt manganese oxides for ciprofloxacin degradation[J]. Chinese Chemical Letters, ;2022, 33(12): 5208-5212. doi: 10.1016/j.cclet.2022.01.055 shu

Hydroxyl radical induced from hydrogen peroxide by cobalt manganese oxides for ciprofloxacin degradation

Shuandi Wang ^a ,
Xiaodong Zhang ^a ,
Guozhu Chen ^a ,
Bao Liu ^a ,
Hongmei Li ^a ,
Junhua Hu ^b ,
Junwei Fu ^{a, *,} ,
Min Liu ^{a, *,}

a.
Hunan Joint International Research Center for Carbon Dioxide Resource Utilization, School of Physics and Electronics, State Key Laboratory of Powder Metallurgy, Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha 410083, China
b.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China

fujunwei@csu.edu.cn

minliu@csu.edu.cn

Received Date: 30 September 2021
Revised Date: 5 December 2021
Accepted Date: 19 January 2022
Available Online: 25 January 2022

Figures(5)

Advanced oxidation processes (AOPs) are promising technology to remove organic pollutant in water. However, the main problem in the AOPs is the low generation of hydroxyl radical (^•OH) owing to the low decomposition efficiency of hydrogen peroxide (H₂O₂). Herein, the spinel type cobalt acid manganese (MnCo₂O₄) with flower morphology was fabricated through a co-precipitation method. In situ Fourier transform infrared spectroscopy confirms that the MnCo₂O₄ with the optimal molar ratio of Co and Mn precursors (CM3, Co: Mn = 3) has more Lewis acid sites compared with single metal oxide catalysts (Co₃O₄ and Mn₂O₃), leading to the excellent performances for H₂O₂ decomposition rate constant on CM3, which is about 15.03 and 4.21 times higher than those of Co₃O₄ and Mn₂O₃, respectively. As a result, the obtained CM3 shows a higher ciprofloxacin degradation ratio than that of Co₃O₄ and Mn₂O₃. Furthermore, CM3 shows an excellent stability during several cycles. This work proposes effective catalysts for ciprofloxacin decomposition and provides feasible route for treating practical environmental problems.
- Catalytic decomposition,
- Hydrogen peroxide,
- Advanced oxidation processes,
- Ciprofloxacin,
- Pollutant degradation
1. [1]
  Q.Q. Zhang, G.G. Ying, C.G. Pan, Y.S. Liu, J.L. Zhao, Environ. Sci. Technol. 49 (2015) 6772–6782. doi: 10.1021/acs.est.5b00729
2. [2]
  Z. Cai, A.D. Dwivedi, W.N. Lee, et al., Environ. Sci. : Nano 5 (2018) 27–47. doi: 10.1039/C7EN00644F
3. [3]
  J. Duan, H. Ji, T. Xu, et al., Chem. Eng. J. 406 (2021) 126752. doi: 10.1016/j.cej.2020.126752
4. [4]
  J. Ma, L. Chen, Y. Liu, et al., J. Hazard. Mater. 418 (2021) 126180. doi: 10.1016/j.jhazmat.2021.126180
5. [5]
  S. Li, T. Huang, P. Du, W. Liu, J. Hu, Water Res. 185 (2020) 116286. doi: 10.1016/j.watres.2020.116286
6. [6]
  J. Yang, J.J. Pignatello, B. Pan, B. Xing, Environ. Sci. Technol. 51 (2017) 8972–8980. doi: 10.1021/acs.est.7b01087
7. [7]
  U. Jans, C. Prasse, U. von Gunten, Environ. Sci. Technol. 55 (2021) 3313–3321. doi: 10.1021/acs.est.0c07662
8. [8]
  Y. Wang, C. Zhou, J. Wu, J. Niu, Chin. Chem. Lett. 31 (2020) 2673–2677. doi: 10.1016/j.cclet.2020.03.073
9. [9]
  Y. Zhou, Y. Gao, S.Y. Pang, et al., Water Res. 145 (2018) 210–219. doi: 10.1016/j.watres.2018.08.026
10. [10]
  Y. Zhang, C. Liu, B. Xu, F. Qi, W. Chu, Appl. Catal. B 199 (2016) 447–457. doi: 10.1016/j.apcatb.2016.06.003
11. [11]
  L. Ling, Y. Liu, D. Pan, et al., Chem. Eng. J. 381 (2020) 122607. doi: 10.1016/j.cej.2019.122607
12. [12]
  X. Yang, X. Cheng, A.A. Elzatahry, et al., Chin. Chem. Lett. 30 (2019) 324–330. doi: 10.1016/j.cclet.2018.06.026
13. [13]
  S. Chen, T. Luo, K. Chen, et al., Angew. Chem. Int. Ed. 60 (2021) 16607–16614. doi: 10.1002/anie.202104480
14. [14]
  J. Zheng, D. Song, H. Chen, et al., Chin. Chem. Lett. 31 (2020) 1109–1113. doi: 10.1016/j.cclet.2019.09.037
15. [15]
  J. Zhan, M. Li, X. Zhang, et al., Chin. Chem. Lett. 31 (2020) 715–720. doi: 10.1016/j.cclet.2019.09.001
16. [16]
  B. Shen, C. Dong, J. Ji, M. Xing, J. Zhang, Chin. Chem. Lett. 30 (2019) 2205–2210. doi: 10.1016/j.cclet.2019.09.052
17. [17]
  C. Guo, D. Yue, S. Wang, X. Qian, Y. Zhao, Chin. Chem. Lett. 31 (2020) 1978–1981. doi: 10.1016/j.cclet.2019.11.049
18. [18]
  Z. Wang, M. Liu, F. Xiao, et al., Chin. Chem. Lett. 33 (2022) 653–662. doi: 10.3390/machines10080653
19. [19]
  Z. Guo, Y. Xie, J. Xiao, et al., J. Am. Chem. Soc. 141 (2019) 12005–12010. doi: 10.1021/jacs.9b04569
20. [20]
  S. Afzal, X. Quan, J. Zhang, Appl. Catal. B 206 (2017) 692–703. doi: 10.1016/j.apcatb.2017.01.072
21. [21]
  Y. Ding, J. Wang, S. Xu, K.Y.A. Lin, S. Tong, Sep. Purif. Technol. 207 (2018) 92–98. doi: 10.1016/j.seppur.2018.06.027
22. [22]
  Y. Lee, D. Gerrity, M. Lee, et al., Environ. Sci. Technol. 50 (2016) 3809–3819. doi: 10.1021/acs.est.5b04904
23. [23]
  Y. Yao, Y. Cai, G. Wu, et al., J. Hazard. Mater. 296 (2015) 128–137. doi: 10.1016/j.jhazmat.2015.04.014
24. [24]
  X. Ao, W. Liu, Chem. Eng. J. 313 (2017) 629–637. doi: 10.1016/j.cej.2016.12.089
25. [25]
  M. Du, Q. Yi, J. Ji, et al., Chin. Chem. Lett. 31 (2020) 2803–2808. doi: 10.1016/j.cclet.2020.08.002
26. [26]
  S. Zhu, S.H. Ho, C. Jin, X. Duan, S. Wang, Environ. Sci. -Nano 7 (2020) 368–396. doi: 10.1039/c9en01250h
27. [27]
  X. Yan, Y. Song, X. Wu, et al., Nanoscale 9 (2017) 2317–2323. doi: 10.1039/C6NR08473G
28. [28]
  H. Liang, R. Liu, X. An, et al., Chem. Eng. J. 414 (2021) 128669. doi: 10.1016/j.cej.2021.128669
29. [29]
  H. Li, J. Shang, Z. Yang, et al., Environ. Sci. Technol. 51 (2017) 5685–5694. doi: 10.1021/acs.est.7b00040
30. [30]
  M. Liu, Z. Feng, X. Luan, et al., Environ. Sci. Technol. 55 (2021) 6042–6051. doi: 10.1021/acs.est.0c08018
31. [31]
  X. Qi, H. Tian, X. Dang, et al., Anal. Methods 11 (2019) 1111–1124. doi: 10.1039/c8ay02514b
32. [32]
  J.T. Mefford, W.G. Hardin, S. Dai, K.P. Johnston, K.J. Stevenson, Nat. Mater. 13 (2014) 726–732. doi: 10.1038/nmat4000
33. [33]
  C. Li, X. Han, F. Cheng, et al., Nat. Commun. 6 (2015) 7345. doi: 10.1038/ncomms8345
34. [34]
  L. Luo, Y. Zhang, F. Li, et al., Anal. Chim. Acta 788 (2013) 46–51. doi: 10.1016/j.aca.2013.06.028
35. [35]
  M. Li, Y. Xiong, X. Liu, et al., Nanoscale 7 (2015) 8920–8930. doi: 10.1039/C4NR07243J
36. [36]
  S. Saha, S.B. Abd Hamid, RSC Adv. 6 (2016) 96314–96326. doi: 10.1039/C6RA21221B
37. [37]
  H. Li, K. Liu, J. Fu, et al., Nano Energy 82 (2021) 105767. doi: 10.1016/j.nanoen.2021.105767
38. [38]
  X. Mi, Y. Li, X. Ning, et al., Chem. Eng. J. 358 (2019) 299–309. doi: 10.1016/j.cej.2018.10.047
39. [39]
  K. Chen, H. Li, Y. Xu, et al., Nanoscale 11 (2019) 5967–5973. doi: 10.1039/c9nr01637f
40. [40]
  J. Fu, L. Zhu, K. Jiang, et al., Chem. Eng. J. 415 (2021) 128982. doi: 10.1016/j.cej.2021.128982
41. [41]
  K. Chen, K. Liu, P. An, et al., Nat. Commun. 11 (2020) 4173. doi: 10.1038/s41467-020-18062-y
42. [42]
  R. Yuan, H. Li, X.A. Zhang, et al., J. Energy Storage 29 (2020) 101300. doi: 10.1016/j.est.2020.101300
43. [43]
  J. Fu, K. Liu, K. Jiang, et al., Adv. Sci. 6 (2019) 1900796. doi: 10.1002/advs.201900796
44. [44]
  X. Xie, C. Ni, Z. Lin, et al., Chem. Eng. J. 396 (2020) 125205. doi: 10.1016/j.cej.2020.125205
45. [45]
  L. Pi, N. Yang, W. Han, et al., Chem. Eng. J. 334 (2018) 1297–1308. doi: 10.1016/j.cej.2017.11.006
46. [46]
  K. Lei, X. Han, Y. Hu, et al., Chem. Commun. 51 (2015) 11599–11602. doi: 10.1039/C5CC03155A
47. [47]
  K. Cheng, F. Yang, G. Wang, J. Yin, D. Cao, J. Mater. Chem. A 1 (2013) 1669–1676. doi: 10.1039/C2TA00219A
48. [48]
  Z. Wang, B. Song, J. Li, X. Teng, Chemosphere 270 (2021) 128652. doi: 10.1016/j.chemosphere.2020.128652
49. [49]
  Y. Zhang, X. Xu, J. Cai, Y. Pan, M. Zhou, Chemosphere 266 (2021) 129063. doi: 10.1016/j.chemosphere.2020.129063
50. [50]
  C. Ma, S. Feng, J. Zhou, et al., Appl. Catal. B 259 (2019) 118015. doi: 10.1016/j.apcatb.2019.118015
51. [51]
  Y. Qin, Y. Sun, Y. Li, et al., Chin. Chem. Lett. 31 (2020) 774–778. doi: 10.1016/j.cclet.2019.09.016
52. [52]
  P. Thanekar, P.R. Gogate, Sep. Purif. Technol. 239 (2020) 116563. doi: 10.1016/j.seppur.2020.116563
53. [53]
  J. Duan, H. Ji, X. Zhao, et al., Chem. Eng. J. 393 (2020) 124692. doi: 10.1016/j.cej.2020.124692
54. [54]
  J. Duan, H. Ji, W. Liu, et al., Chem. Eng. J. 359 (2019) 1617–1628. doi: 10.1016/j.cej.2018.11.008
55. [55]
  H. Liang, R. Liu, C. Hu, et al., J. Hazard. Mater. 406 (2021) 0304–3894.
56. [56]
  M. Yu, H. Liang, R. Zhan, L. Xu, J. Niu, Chin. Chem. Lett. 32 (2021) 2155–2158. doi: 10.1016/j.cclet.2020.11.069
57. [57]
  F. Yang, X. Chu, J. Sun, et al., Chin. Chem. Lett. 31 (2020) 2784–2788. doi: 10.1016/j.cclet.2020.07.033
58. [58]
  Q. Yang, Z. Feng, M. Liu, et al., Chin. Chem. Lett. 32 (2021) 3393–3397. doi: 10.1016/j.cclet.2021.1005.1066
59. [59]
  C. Dong, J. Ji, B. Shen, M. Xing, J. Zhang, Environ. Sci. Technol. 52 (2018) 11297–11308. doi: 10.1021/acs.est.8b02403
60. [60]
  N. Yan, F. Liu, Q. Xue, et al., Chem. Eng. J. 274 (2015) 61–68. doi: 10.1016/j.cej.2015.03.056
61. [61]
  H. Zhang, W. Yang, I.I. Roslan, S. Jaenicke, G.K. Chuah, J. Catal. 375 (2019) 56–67. doi: 10.1016/j.jcat.2019.05.020
62. [62]
  A.N. Naveen, S. Selladurai, Electrochim. Acta 125 (2014) 404–414. doi: 10.1016/j.electacta.2014.01.161
63. [63]
  Y. Lin, K. Liu, K. Chen, et al., ACS Catal. 11 (2021) 6304–6315. doi: 10.1021/acscatal.0c04966
1. [1]
  João Restivo , Raquel P. Rocha , Adrián M. T. Silva , José J. M. Órfão , Manuel F. R. Pereira , José L. Figueiredo . Catalytic performance of heteroatom-modified carbon nanotubes in advanced oxidation processes. Chinese Journal of Catalysis, 2014, 35(6): 896-905. doi: 10.1016/S1872-2067(14)60103-0
2. [2]
  Zhi Chao Wang , Lai Jun Wang , Ping Zhang , Song Zhe Chen , Jing Ming Xu , Jing Chen . Effect of preparation methods on Pt/alumina catalysts for the hydrogen iodide catalytic decomposition. Chinese Chemical Letters, 2009, 20(1): 102-105. doi: 10.1016/j.cclet.2008.09.059
3. [3]
  Qing Hua Zhang , Shou Feng Wang , Zi Qiang Lei . Baeyer-Villiger oxidation of ketones with hydrogen peroxide catalyzed by Sn-aniline complex. Chinese Chemical Letters, 2007, 18(1): 4-6. doi: 10.1016/j.cclet.2006.11.036
4. [4]
  Xue Ming Chen , Djalma Ribeiro da Silva , Carlos A. Martínez-Huitle . Application of advanced oxidation processes for removing salicylic acid from synthetic wastewaters. Chinese Chemical Letters, 2010, 21(1): 101-104. doi: 10.1016/j.cclet.2009.08.001
5. [5]
  Zhu Meng , Zhang Longshuai , Liu Shanshan , Wang Dengke , Qin Yuancheng , Chen Ying , Dai Weili , Wang Yuehua , Xing Qiuju , Zou Jianping . Degradation of 4-nitrophenol by electrocatalysis and advanced oxidation processes using Co₃O₄@C anode coupled with simultaneous CO₂ reduction via SnO₂/CC cathode. Chinese Chemical Letters, 2020, 31(7): 1961-1965. doi: 10.1016/j.cclet.2020.01.017
6. [6]
  Shu-Qin Cui , Xu-Yang Ji , Fu-Xin Liang , Zhen-Zhong Yang . Ionic liquid functionalized polymer composite nanotubes toward dye decomposition. Chinese Chemical Letters, 2015, 26(8): 942-945. doi: 10.1016/j.cclet.2015.04.034
7. [7]
  Hassan HOSSEINI-MONFARED , Sohaila ALAVI , Milosz SICZEK . Synthesis, structural analysis and evaluation of the catalytic activity of a non-symmetric N-(salicylidene)diethylenetriamine complex of copper(II). Chinese Journal of Catalysis, 2013, 34(7): 1456-1461. doi: 10.1016/S1872-2067(12)60616-0
8. [8]
  Changjiu Xia , Long Ju , Yi Zhao , Hongyi Xu , Bin Zhu , Feifei Gao , Min Lin , Zhenyu Dai , Xiaodong Zou , Xingtian Shu . Heterogeneous oxidation of cyclohexanone catalyzed by TS-1: Combined experimental and DFT studies. Chinese Journal of Catalysis, 2015, 36(6): 845-854. doi: 10.1016/S1872-2067(15)60859-2
9. [9]
  Zhi Huan Weng , Jin Yan Wang , Xi Gao Jian . Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst. Chinese Chemical Letters, 2007, 18(8): 936-938. doi: 10.1016/j.cclet.2007.06.007
10. [10]
  Gholam Reza Najafi . A green and efficient oxidation of benzylic alcohols using H₂O₂ catalyzed by Montmorillonite-K10 supported MnCl₂. Chinese Chemical Letters, 2010, 21(10): 1162-1164. doi: 10.1016/j.cclet.2010.05.031
11. [11]
  Ali Ezabadi , Ghloam Reza Najafi , Mohammad M. Hashemi . A green and efficient oxidation of benzylic alcohols using H₂O₂ catalyzed by montmorillonite K-10 supported CoCl₂. Chinese Chemical Letters, 2008, 19(11): 1277-1280. doi: 10.1016/j.cclet.2008.09.010
12. [12]
  YUAN Mingming , LI Difan , ZHAO Xiuge , MA Wenbao , KONG Kang , NI Wenxiu , GU Qingwen , HOU Zhenshan . Selective Oxidation of Glycerol with Hydrogen Peroxide Using Silica-Encapsulated Heteropolyacid Catalyst. Acta Physico-Chimica Sinica, 2018, 34(8): 886-895. doi: 10.3866/PKU.WHXB201711151
13. [13]
  Reza Ojani , Parisa Hamidi , Jahan-Bakhsh Raoof . Efficient nonenzymatic hydrogen peroxide sensor in acidic media based on Prussian blue nanoparticles-modified poly (o-phenylenediamine)/glassy carbon electrode. Chinese Chemical Letters, 2016, 27(03): 481-486. doi: 10.1016/j.cclet.2015.12.030
14. [14]
  Zong Yuan Chen , Wei Zhang . Oxidative aromatization of Hantzsch 1,4-dihydropyridines by aqueous hydrogen peroxide-acetic acid. Chinese Chemical Letters, 2007, 18(12): 1443-1446. doi: 10.1016/j.cclet.2007.10.010
15. [15]
  Du Junqun , Zhang Baogang , Li Jiaxin , Lai Bo . Decontamination of heavy metal complexes by advanced oxidation processes: A review. Chinese Chemical Letters, 2020, 31(10): 2575-2582. doi: 10.1016/j.cclet.2020.07.050
16. [16]
  Ruicheng Ji , Jiabin Chen , Tongcai Liu , Xuefei Zhou , Yalei Zhang . Critical review of perovskites-based advanced oxidation processes for wastewater treatment: Operational parameters, reaction mechanisms, and prospects. Chinese Chemical Letters, 2022, 33(2): 643-652. doi: 10.1016/j.cclet.2021.07.043
17. [17]
  Ke Tian , Limin Hu , Letian Li , Qingzhu Zheng , Yanjun Xin , Guangshan Zhang . Recent advances in persulfate-based advanced oxidation processes for organic wastewater treatment. Chinese Chemical Letters, 2022, 33(10): 4461-4477. doi: 10.1016/j.cclet.2021.12.042
18. [18]
  Jiali Peng , Yongli He , Chenying Zhou , Shijun Su , Bo Lai . The carbon nanotubes-based materials and their applications for organic pollutant removal: A critical review. Chinese Chemical Letters, 2021, 32(5): 1626-1636. doi: 10.1016/j.cclet.2020.10.026
19. [19]
  Lei Xiaoman , You Menghan , Pan Fei , Liu Min , Yang Peng , Xia Dongsheng , Li Qiang , Wang Yanting , Fu Jie . CuFe₂O₄@GO nanocomposite as an effective and recoverable catalyst of peroxymonosulfate activation for degradation of aqueous dye pollutants. Chinese Chemical Letters, 2019, 30(12): 2216-2220. doi: 10.1016/j.cclet.2019.05.039

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