Citation: Zixin Jia, Youning Wang, Jiaqi Chen, Zhijie Cao, Shugang Pan, Yan Zhou, Jingwen Sun, Junwu Zhu, Xin Wang, Yongsheng Fu. Metal-organic frameworks derived low-crystalline NiCo₂S₄/Co₃S₄ nanocages with dual heterogeneous interfaces for high-performance supercapacitors[J]. Chinese Chemical Letters, ;2023, 34(1): 107137. doi: 10.1016/j.cclet.2022.01.030 shu

Metal-organic frameworks derived low-crystalline NiCo₂S₄/Co₃S₄ nanocages with dual heterogeneous interfaces for high-performance supercapacitors

Zixin Jia ^a ,
Youning Wang ^a ,
Jiaqi Chen ^{a, b} ,
Zhijie Cao ^c ,
Shugang Pan ^{a, d} ,
Yan Zhou ^a ,
Jingwen Sun ^a ,
Junwu Zhu ^a ,
Xin Wang ^a ,
Yongsheng Fu ^{a, *,}

a.
Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China
b.
Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huaiyin 223300, China
c.
Ningxia University, Yinchuan 750021, China
d.
Changzhou Institute of Technology, Changzhou 213032, China

fuyongsheng@njust.edu.cn

Received Date: 16 November 2021
Revised Date: 31 December 2021
Accepted Date: 11 January 2022
Available Online: 16 January 2022

Figures(5)

Nickel cobalt bimetallic heterogeneous sulfides are attractive battery-type materials for electrochemical energy storage. However, the precise synthesis of electrode materials that integrate highly efficient ions/electrons diffusion with abundant charge transfer channels has always been challenging. Herein, an effective and concise controllable hydrothermal approach is reported for tuning the crystalline and integrated structures of MOF-derived bimetallic sulfides to accelerate the charge transfer kinetics, and thus enabling rich Faradaic redox reaction. The as-obtained low-crystalline heterogeneous NiCo₂S₄/Co₃S₄ nanocages exhibit a high specific capacity (1023 C/g at 1 A/g), remarkable rate performance (560 C/g at 10 A/g), and outstanding cycling stability (89.6% retention after 5000 cycles). Furthermore, hybrid supercapacitors fabricated with NiCo₂S₄/Co₃S₄ and nitrogen-doped reduced graphene oxide display an outstanding energy density of 40.8 Wh/kg at a power density of 806.3 W/kg, with an excellent capacity retention of 88.3% after 10000 charge-discharge cycles.
- Metal-organic frameworks,
- Nickel cobalt heterogeneous sulfides,
- Low-crystalline nanostructure,
- High-performance supercapacitors,
- High energy density
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Metal-organic frameworks derived low-crystalline NiCo2S4/Co3S4 nanocages with dual heterogeneous interfaces for high-performance supercapacitors

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通讯作者: 陈斌, bchen63@163.com

Metal-organic frameworks derived low-crystalline NiCo₂S₄/Co₃S₄ nanocages with dual heterogeneous interfaces for high-performance supercapacitors