Citation: Ziyuan Gao, Jia Jia, Wentong Fan, Tong Liao, Xingfeng Zhang. Zirconium metal organic cages: From phosphate selective sensing to derivate forming[J]. Chinese Chemical Letters, ;2022, 33(9): 4415-4420. doi: 10.1016/j.cclet.2021.12.035 shu

Zirconium metal organic cages: From phosphate selective sensing to derivate forming

College of Material and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

jiajia17@cdut.edu.cn

Received Date: 3 September 2021
Revised Date: 14 October 2021
Accepted Date: 14 December 2021
Available Online: 20 December 2021

Figures(5)

Luminescent metal organic cages (MOCs) have attracted great interest as a unique class of sensing substrates. In this work, intrinsically fluorescent Zr-MOCs were successfully used as fluorescent probes for the sensitive and selective detection of phosphate anions in water and real samples. When the ligand and Zr ion clusters form a cage, the intrinsic fluorescence of the ligand was tuned from high to weak emission due to the ligand-to-metal charge transfer (LMCT) effect, and this weakened fluorescence can be restored by the addition of phosphate. The degree of fluorescence enhancement is positively correlated with the added phosphate concentration, and the efficacy of this strategy is demonstrated by a linear phosphate detection range of 5–500 µmol/L and a detection limit of 1.06 µmol/L. We discuss the interaction between phosphate and Zr in scattering spectrum and MS, respectively. In comparison to phosphate adsorption on Zr-metal organic frameworks (MOFs), where phosphate connects different numbers of cages, both blocking the LMCT effect and causing the cages to aggregate. We also found that the phosphate displaces the ligand from the cage when the phosphate concentration is further expanded, resulting in the formation of new derivatives. This derivative was shown to be useful as a Lewis acid catalyst and as a rare earth ion adsorbent.
- Zirconium metal organic cage,
- Phosphate sensing,
- Derivant forming,
- Fluorescence enhancement,
- Mass spectrometry
1. [1]
  J. Casida, M. Eto, R. Baron, Nature 191 (1961) 1396. doi: 10.1038/1911396a0
2. [2]
  F. Xie, F. Wu, G. Liu, et al., Environ. Sci. Technol. 48 (2014) 582–590. doi: 10.1021/es4037379
3. [3]
  J. Wu, X.S. Li, Y. Zhao, et al., J. Chromatogr. A 1218 (2011) 2944–2953. doi: 10.1016/j.chroma.2011.03.019
4. [4]
  S. Lee, J.H. Lee, J.C. Kim, et al., ACS Appl. Mater. Interfaces 10 (2018) 8685–8691. doi: 10.1021/acsami.7b18836
5. [5]
  Q. Tang, Y. Sun, H.Y. Li, et al., Appl. Organomet. Chem. 33 (2019) e4814. doi: 10.1002/aoc.4814
6. [6]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
7. [7]
  Q. Liu, R. Zhang, B. Yu, A. Liang, Z. Jiang, Sens. Actuators B 344 (2021) 130288. doi: 10.1016/j.snb.2021.130288
8. [8]
  J.H. Zhang, S.M. Xie, M. Zi, L.M. Yuan, J. Sep. Sci. 43 (2020) 134–149. doi: 10.1002/jssc.201900762
9. [9]
  X. Huang, Z. Huang, L. Zhang, R. Liu, Y. Lv, Sens. Actuators B 312 (2020) 127952. doi: 10.1016/j.snb.2020.127952
10. [10]
  L. Li, S. Shen, W. Ai, et al., Sens. Actuators B 267 (2018) 542–548. doi: 10.1016/j.snb.2018.04.064
11. [11]
  W. Zuo, L. Liang, F. Ye, S. Zhao, Sens. Actuators B 345 (2021) 130345. doi: 10.1016/j.snb.2021.130345
12. [12]
  D. Nam, J. Huh, J. Lee, et al., Chem. Sci. 8 (2017) 7765–7771. doi: 10.1039/C7SC03847J
13. [13]
  M. Zhou, G. Liu, Z. Ju, et al., Cryst. Growth Des. 20 (2020) 4127–4134. doi: 10.1021/acs.cgd.0c00407
14. [14]
  W.H. Xing, H.Y. Li, X.Y. Dong, S.Q. Zang, J. Mater. Chem. A 6 (2018) 7724–7730. doi: 10.1039/C8TA00858B
15. [15]
  X. Chen, S.B. Li, Z.Y. Liu, Y.T. Zhang, J. Solid State Chem. 296 (2021) 121998. doi: 10.1016/j.jssc.2021.121998
16. [16]
  Y. Bai, Y. Dou, L.H. Xie, et al., Chem. Soc. Rev. 45 (2016) 2327–2367. doi: 10.1039/C5CS00837A
17. [17]
  D. Feng, W.C. Chung, Z. Wei, et al., J. Am. Chem. Soc. 135 (2013) 17105–17110. doi: 10.1021/ja408084j
18. [18]
  H.L. Jiang, D. Feng, K. Wang, et al., J. Am. Chem. Soc. 135 (2013) 13934–13938. doi: 10.1021/ja406844r
19. [19]
  X. Zhu, J. Gu, J. Yang, et al., J. Mater. Chem. B. 3 (2015) 4242–4248. doi: 10.1039/C5TB00113G
20. [20]
  C.W. Abney, K.M.L. TaylorPashow, S.R. Russell, et al., Chem. Mater. 26 (2014) 5231–5243. doi: 10.1021/cm501894h
21. [21]
  J. Yang, Y. Dai, X. Zhu, et al., J. Mater. Chem. A 3 (2015) 7445–7452. doi: 10.1039/C5TA00077G
22. [22]
  Y.D. Yuan, J. Dong, J. Liu, et al., Nat. Commun. 11 (2020) 1–10. doi: 10.1038/s41467-019-13993-7
23. [23]
  G. Liu, X. Zhang, Y. Yuan, et al., ACS Mater. Lett. 3 (2021) 268–274.
24. [24]
  E.S.M. ElSayed, D. Yuan, Chem. Lett. 49 (2020) 28–53. doi: 10.1246/cl.190731
25. [25]
  G. Liu, Y. Yuan, J. Wang, et al., J. Am. Chem. Soc. 140 (2018) 6231–6324.
26. [26]
  Y. Cheng, X. Wang, W. Li, D. Chang, J. Mol. Model. 22 (2016) 1. doi: 10.1007/s00894-015-2876-x
1. [1]
  Tian Feng , Yun-Ling Gao , Di Hu , Ke-Yu Yuan , Shu-Yi Gu , Yao-Hua Gu , Si-Yu Yu , Jun Xiong , Yu-Qi Feng , Jie Wang , Bi-Feng Yuan . Chronic sleep deprivation induces alterations in DNA and RNA modifications by liquid chromatography-mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(8): 109259-. doi: 10.1016/j.cclet.2023.109259
2. [2]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
3. [3]
  Junmeng Luo , Qiongqiong Wan , Suming Chen . Chemistry-driven mass spectrometry for structural lipidomics at the C=C bond isomer level. Chinese Chemical Letters, 2025, 36(1): 109836-. doi: 10.1016/j.cclet.2024.109836
4. [4]
  Keqiang Shi , Xiujuan Hong , Dongyan Xu , Tao Pan , Huiwen Wang , Hongru Feng , Cheng Guo , Yuanjiang Pan . Analysis of RNA modifications in peripheral white blood cells from breast cancer patients by mass spectrometry. Chinese Chemical Letters, 2025, 36(3): 110079-. doi: 10.1016/j.cclet.2024.110079
5. [5]
  Yongyi Li , Jin Han , Xiangyu Wang , Zhenwei Wei . In-situ reaction monitoring and kinetics study of photochemical reactions by optical focusing inductive electrospray mass spectrometry. Chinese Chemical Letters, 2025, 36(9): 110708-. doi: 10.1016/j.cclet.2024.110708
6. [6]
  Rui Su , Xiaowei Fang , Peng Zeng , Yong Qian , Xuanzhu Li , Huiyu Xing , Jiamei Lin , Jiaquan Xu . Mass spectrometry for non-destructive detection of the average diameter of micro copper wires. Chinese Chemical Letters, 2025, 36(10): 110748-. doi: 10.1016/j.cclet.2024.110748
7. [7]
  Shu-Yi Gu , Tian Feng , Fang-Yin Gang , Si-Yu Yu , Wan Chan , Zhao-Cheng Ma , Yao-Hua Gu , Bi-Feng Yuan . Persistent organic pollutant perfluorooctanoic acid induces alterations in epigenetic modifications of DNA and RNA. Chinese Chemical Letters, 2025, 36(12): 110957-. doi: 10.1016/j.cclet.2025.110957
8. [8]
  Guoxing Liu , Yixin Li , Changming Tian , Yongmei Xiao , Lijie Liu , Zhanqi Cao , Song Jiang , Xin Zheng , Caoyuan Niu , Yun-Lai Ren , Liangru Yang , Xianfu Zheng , Yong Chen . Highly reversible photomodulated hydrosoluble stiff-stilbene supramolecular luminophor induced by cucurbituril. Chinese Chemical Letters, 2024, 35(8): 109403-. doi: 10.1016/j.cclet.2023.109403
9. [9]
  Yang Feng , Yang-Qing Tian , Yong-Qiang Zhao , Sheng-Jun Chen , Bi-Feng Yuan . Dynamic deformylation of 5-formylcytosine and decarboxylation of 5-carboxylcytosine during differentiation of mouse embryonic stem cells into mouse neurons. Chinese Chemical Letters, 2024, 35(11): 109656-. doi: 10.1016/j.cclet.2024.109656
10. [10]
  Qiongqiong Wan , Yanan Xiao , Guifang Feng , Xin Dong , Wenjing Nie , Ming Gao , Qingtao Meng , Suming Chen . Visible-light-activated aziridination reaction enables simultaneous resolving of C=C bond location and the sn-position isomers in lipids. Chinese Chemical Letters, 2024, 35(4): 108775-. doi: 10.1016/j.cclet.2023.108775
11. [11]
  Yao-Hua Gu , Yu Chen , Qing Li , Neng-Bin Xie , Xue Xing , Jun Xiong , Min Hu , Tian-Zhou Li , Ke-Yu Yuan , Yu Liu , Tang Tang , Fan He , Bi-Feng Yuan . Metabolome profiling by widely-targeted metabolomics and biomarker panel selection using machine-learning for patients in different stages of chronic kidney disease. Chinese Chemical Letters, 2024, 35(11): 109627-. doi: 10.1016/j.cclet.2024.109627
12. [12]
  Yimin Guo , Yiting Luo , Shuwen Hua , Chuan-Fan Ding , Yinghua Yan . Application of magnetic nanomaterials in peptidomics: A review in the past decade. Chinese Chemical Letters, 2025, 36(6): 110070-. doi: 10.1016/j.cclet.2024.110070
13. [13]
  Xiaoli Zhong , Liangsheng Chen , Hao Xu , Tianhang Jiang , Zhengyi Hua , Fancheng Tan , Xiaoya Mao , Ziquan Fan , Zhiwei Li , Jun Zeng , Shu-Hai Lin . Development of a comprehensive computational pipeline for cardiolipin atlas in an intermittent fasting model. Chinese Chemical Letters, 2025, 36(12): 111027-. doi: 10.1016/j.cclet.2025.111027
14. [14]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
15. [15]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
16. [16]
  Xin Chen , Meng Zhao , Yan-Yuan Jia . Stable Eu(III)-based metal-organic framework for fluorescence sensing of benzaldehyde and its analogues. Chinese Journal of Structural Chemistry, 2025, 44(3): 100445-100445. doi: 10.1016/j.cjsc.2024.100445
17. [17]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
18. [18]
  Ya-Ru Qu , Kai-Li Tian , Han-Jun Huang , Jia-Jun Tu , Ai-Hao Chen , Hai-Jun Sun , Maxim V. Bermeshev , Shao-Jie Wang , Wen-Bin Li , Xiang-Kui Ren . Fluorescence enhancement of perylene diimide: Design strategy and application. Chinese Journal of Structural Chemistry, 2025, 44(12): 100756-100756. doi: 10.1016/j.cjsc.2025.100756
19. [19]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
20. [20]
  Xinrui Chen , Wenjian Huang , Xiaoyang Zhao , Songyao Zhang , Xinrui Miao . Structural regulation of alkynyl-based covalent organic frameworks for multi-stimulus fluorescence sensing. Chinese Journal of Structural Chemistry, 2025, 44(7): 100604-100604. doi: 10.1016/j.cjsc.2025.100604

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1685)
HTML views(168)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142