Citation: Dan Wang, Gang Wang, Ke Liu, Jing Li, Zhaolong Wang, Jing Liu, Liping Ding, Rong Miao, Yu Fang. Structure-fluorescence relationships in pyrrole appended o-carborane crystalline materials[J]. Chinese Chemical Letters, ;2022, 33(5): 2532-2536. doi: 10.1016/j.cclet.2021.12.020 shu

Structure-fluorescence relationships in pyrrole appended o-carborane crystalline materials

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China

Received Date: 8 August 2021
Revised Date: 3 December 2021
Accepted Date: 9 December 2021
Available Online: 12 December 2021
Fund Project: the Natural Science Foundation of China 22072084the Natural Science Foundation of China 21820102005111 Project B14041the Fundamental Research Funds for the Central Universities GK202103048the Fundamental Research Funds for the Central Universities GK202001005the Fundamental Research Funds for the Central Universities 2020CSLY008the Innovation Capability Support Program of Shaanxi 2021TD-18

Figures(5)

Based on three rationally designed pyrrole-appended o-carborane derivatives, we present that fluorescence properties of crystalline materials are highly dependent on intermolecular interaction and steric hinderance. Though the three molecules are similar in structure, single crystals of the three compounds showed obvious difference in molecular stacking and fluorescence behavior. Systematic studies indicate that fluorescence quantum yields, thermo-response as well as mechano-response are highly dependent on intermolecular interaction and steric hindrance. In the three crystalline materials, the CB-NMe crystals with weaker intermolecular interaction and looser molecular packing showed superior fluorescence quantum yield and temperature sensitivity. Accordingly, surface temperature detection strip with favorable reversibility is prepared by doping CB-NMe into the polymer. In addition, the CB-NMe aggregates can be used for monitoring bovine serum albumin (BSA) denaturation, as temperature response of the aggregates can be reversed when co-assembled with BSA.
- Fluorescence,
- o-Carborane crystal,
- Steric hinderance,
- Molecular packing,
- Temperature sensing
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