Citation: Pusu Yang, Hui-Zhen Du, Xiang-Yu Zhang, Yong-Liang Xia, Jun-Tao Sun, Qian Peng, Bing-Tao Guan. Well-defined phosphate yttrium dialkyl complexes for catalytic stereo-controllable 1, 4-polymerization of isoprene[J]. Chinese Chemical Letters, ;2022, 33(5): 2402-2406. doi: 10.1016/j.cclet.2021.11.064 shu

Well-defined phosphate yttrium dialkyl complexes for catalytic stereo-controllable 1, 4-polymerization of isoprene

a.
College of Chemistry, Nankai University, Tianjin 300071, China
b.
Department of Chemistry, Fudan University, Shanghai 200438, China

bguan@fudan.edu.cn

Received Date: 23 July 2021
Revised Date: 15 November 2021
Accepted Date: 23 November 2021
Available Online: 27 November 2021

Figures(4)

Oxygen ligation is envisioned to provide a stable and distinctive coordination environment to the strongly oxophilic rare-earth metals. However, the well-defined dialkyl complexes bearing oxyanion ancillary ligand had been rarely addressed for the instability of the complexes and the shortage of easily available ligands. Herein, we report the synthesis of phosphate ligated dialkyl yttrium complexes (PYR₂) featuring a high stability and a tunable ligand. Treated with the borate reagent, the phosphate yttrium complex displays high activity and selectivity in the catalytic cis-1, 4-polymerization of isoprene (up to 96.5%). Furthermore, using AlMe₃ as an additive, the stereoselectivity switches to trans-1, 4-polymerization (up to 92.0%).
- Phosphate,
- Yttrium alkyls,
- Isoprene,
- Stereo-controllable,
- 1, 4-Polymerization
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