Citation: Tao Mei, Dawei Yang, Linan Su, Baomin Wang, Jingping Qu. Construction of a low-valent thiolate-bridged dicobalt platform and its reactivity toward hydrogen activation and evolution[J]. Chinese Chemical Letters, ;2022, 33(5): 2477-2480. doi: 10.1016/j.cclet.2021.11.014 shu

Construction of a low-valent thiolate-bridged dicobalt platform and its reactivity toward hydrogen activation and evolution

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

yangdw@dlut.edu.cn

Received Date: 16 September 2021
Revised Date: 3 November 2021
Accepted Date: 3 November 2021
Available Online: 11 November 2021

Figures(4)

Low-valence transition metallic complexes have drawn longstanding attention due to their high reactivity toward catalytic transformation of various small molecules. Among these known complexes, the low-valence metal centres are commonly stabilized by neutral bulky ligands with strong electron-donating capacity. However, low-valence bimetallic complexes supported by anionic sulfur and cyclopentadienyl ligands are still difficult to obtain in high isolated yield. Herein, we report the synthesis and characterization of two scarce thiolate-bridged Co^ⅠCo^Ⅱ and Co^ⅠCo^Ⅰ complexes bearing sterically demanding ligands through two stepwise one-electron reduction processes. Interestingly, the Co^ⅠCo^Ⅱ complex can facilely promote the homolytic cleavage of dihydrogen across the short Co−Co metallic bond to give a Co^ⅡCo^Ⅲ dihydride bridged complex, which is capable of serving as a competent hydrogen atom transfer agent. Moreover, the anionic Co^ⅠCo^Ⅰ complex can trigger a stepwise hydrogen generation cycle involving several isolated and structurally well-characterized intermediates.
- Low-valence,
- Thiolate-bridged,
- Cobalt,
- Homolytic H₂ cleavage,
- Hydride,
- Hydrogen evolution
1. [1]
  K. Gao, N. Yoshikai, Acc. Chem. Res.47 (2014) 1208–1219. doi: 10.1021/ar400270x
2. [2]
  T.J. Hadlington, M. Driess, C. Jones, Chem. Soc. Rev. 47 (2018) 4176–4197. doi: 10.1039/C7CS00649G
3. [3]
  S. Yoshioka, S. Saito, Chem. Commun. 54 (2018) 13319–13330. doi: 10.1039/c8cc06543h
4. [4]
  C. -. S. Cao, Y. Shi, H. Xu, B. Zhao, Coord. Chem. Rev. 365 (2018) 122–144. doi: 10.1016/j.ccr.2018.03.017
5. [5]
  Y. Liu, J. Cheng, L. Deng, Acc. Chem. Res. 53 (2020) 244–254. doi: 10.1021/acs.accounts.9b00492
6. [6]
  J.C. Fontecilla-Camps, A. Volbeda, C. Cavazza, Y. Nicolet, Chem. Rev. 107 (2007) 4273–4303. doi: 10.1021/cr050195z
7. [7]
  W. Lubitz, H. Ogata, O. Rüdiger, E. Reijerse, Chem. Rev. 114 (2014) 4081–4148. doi: 10.1021/cr4005814
8. [8]
  J.L. Dempsey, B.S. Brunschwig, J.R. Winkler, H.B. Gray, Acc. Chem. Res. 42 (2009) 1995–2004. doi: 10.1021/ar900253e
9. [9]
  N. Queyriaux, R.T. Jane, J. Massin, V. Artero, M. Chavarot-Kerlidou, Coord. Chem. Rev. 304-305 (2015) 3–19. doi: 10.1016/j.ccr.2015.03.014
10. [10]
  D.Z. Zee, T. Chantarojsiri, J.R. Long, C.J. Chang, Acc. Chem. Res. 48 (2015) 2027–2036. doi: 10.1021/acs.accounts.5b00082
11. [11]
  N.K. Szymczak, L.A. Berben, J.C. Peters, Chem. Commun. (2009) 6729–6731. doi: 10.1039/b913946j
12. [12]
  S. Mandal, S. Shikano, Y. Yamada, et al., J. Am. Chem. Soc. 135 (2013) 15294–15297. doi: 10.1021/ja408080z
13. [13]
  S. Kal, A.S. Filatov, P.H. Dinolfo, Inorg. Chem. 53 (2014) 7137–7145. doi: 10.1021/ic500121f
14. [14]
  C. Di Giovanni, C. Gimbert-Surinach, M. Nippe, et al., Chem. Eur. J. 22 (2016) 361–369. doi: 10.1002/chem.201503567
15. [15]
  P. Tong, W. Xie, D. Yang, et al., Dalton Trans. 45 (2016) 18559–18565. doi: 10.1039/C6DT03275C
16. [16]
  K.K. Kpogo, S. Mazumder, D. Wang, et al., Chem. -Eur. J. 23 (2017) 9272–9279. doi: 10.1002/chem.201701982
17. [17]
  Y. Zhang, P. Tong, D. Yang, et al., Chem. Commun. 53 (2017) 9854–9857. doi: 10.1039/C7CC05092E
18. [18]
  C. Wang, J. Li, D. Yang, et al., Eur. J. Inorg. Chem. (2020) 2757–2764. doi: 10.1002/ejic.202000369
19. [19]
  A.D. Wilson, R.H. Newell, M.J. McNevin, et al., J. Am. Chem. Soc. 128 (2006) 358–366. doi: 10.1021/ja056442y
20. [20]
  Y. Maenaka, T. Suenobu, S. Fukuzumi, J. Am. Chem. Soc. 134 (2012) 367–374. doi: 10.1021/ja207785f
21. [21]
  A.Z. Haddad, D. Kumar, K. Ouch Sampson, et al., J. Am. Chem. Soc. 137 (2015) 9238–9241. doi: 10.1021/jacs.5b05561
22. [22]
  Y. Chen, Y. Zhou, P. Chen, et al., J. Am. Chem. Soc. 130 (2008) 15250–15251. doi: 10.1021/ja805025w
23. [23]
  Y. Chen, L. Liu, Y. Peng, et al., J. Am. Chem. Soc. 133 (2011) 1147–1149. doi: 10.1021/ja105948r
24. [24]
  Y. Li, Y. Li, B. Wang, et al., Nature Chem. 5 (2013) 320–326. doi: 10.1038/nchem.1594
25. [25]
  P. Tong, D. Yang, Y. Li, B. Wang, J. Qu, Organometallics 34 (2015) 3571–3576. doi: 10.1021/acs.organomet.5b00387
26. [26]
  X. Zhao, D. Yang, Y. Zhang, B. Wang, J. Qu, Chem. Commun. 54 (2018) 11112–11115. doi: 10.1039/c8cc05738a
27. [27]
  Y. Zhang, D. Yang, Y. Li, et al., Catal. Sci. Technol. 9 (2019) 6492–6502. doi: 10.1039/c9cy01667h
28. [28]
  N. Wei, D. Yang, J. Zhao, et al., Organometallics 40 (2021) 1434–1442. doi: 10.1021/acs.organomet.1c00031
29. [29]
  H. Wu, J. Li, D. Yang, et al., Inorg. Chem. Front. 6 (2019) 2185–2193. doi: 10.1039/c9qi00423h
30. [30]
  J. Li, D. Yang, P. Tong, et al., Inorg. Chem. 59 (2020) 8203–8212. doi: 10.1021/acs.inorgchem.0c00542
31. [31]
  J.J. Schneider, U. Specht, Z. Naturforsch. 50b (1995) 684–686. doi: 10.1515/znb-1995-0436
32. [32]
  S. Venkataramani, U. Jana, M. Dommaschk, et al., Science 331 (2011) 445–448. doi: 10.1126/science.1201180
33. [33]
  N.A. Arnet, T.R. Dugan, F.S. Menges, et al., J. Am. Chem. Soc. 137 (2015) 13220–13223. doi: 10.1021/jacs.5b06841
34. [34]
  D. Yang, Y. Li, B. Wang, et al., Inorg. Chem. 54 (2015) 10243–10249. doi: 10.1021/acs.inorgchem.5b01508
35. [35]
  J.J. Warren, T.A. Tronic, J.M. Mayer, Chem. Rev. 110 (2010) 6961–7001. doi: 10.1021/cr100085k
36. [36]
  I.M. Riddlestone, N.A. Rajabi, J.P. Lowe, et al., J. Am. Chem. Soc. 138 (2016) 11081–11084. doi: 10.1021/jacs.6b05243
37. [37]
  P.I. Georgakaki, L.M. Thomson, E.J. Lyon, M.B. Hal, M.Y. Darensbourg, Coord. Chem. Rev. 238-239 (2003) 255–266. doi: 10.1016/S0010-8545(02)00326-0
38. [38]
  J.F. Capon, F. Gloaguen, F.Y. Pétillon, P. Schollhammer, J. Talarmin, Coord. Chem. Rev. 253 (2009) 1476–1494. doi: 10.1016/j.ccr.2008.10.020
39. [39]
  D. Schilter, J.M. Camara, M.T. Huynh, S. Hammes-Schiffer, T.B. Rauchfuss, Chem. Rev. 116 (2016) 8693–8749. doi: 10.1021/acs.chemrev.6b00180
40. [40]
  S. Ogo, Coord. Chem. Rev. 334 (2017) 43–53. doi: 10.1016/j.ccr.2016.07.001
41. [41]
  D.J. Elliot, D.G. Holah, A.N. Hughes, H.A. Mirza, E. Zawada, J. Chem. Soc., Chem. Commun. (1990) 32–33.
42. [42]
  T.E. Bitterwolf, J. Organomet. Chem. 363 (1989) 189–195. doi: 10.1016/0022-328X(89)88053-2
43. [43]
  C. Tejel, M.A. Ciriano, M. Millaruelo, et al., Inorg. Chem. 42 (2003) 4750–4758. doi: 10.1021/ic034225x
44. [44]
  G.A.N. Felton, R.S. Glass, D.L. Lichtenberger, D.H. Evans, Inorg. Chem. 45 (2006) 9181–9184. doi: 10.1021/ic060984e
45. [45]
  B.E. Barton, T.B. Rauchfuss, J. Am. Chem. Soc. 132 (2010) 14877–14885. doi: 10.1021/ja105312p
46. [46]
  M.E. Carroll, B.E. Barton, T.B. Rauchfuss, P.J. Carroll, J. Am. Chem. Soc. 134 (2012) 18843–18852. doi: 10.1021/ja309216v
47. [47]
  M. Wang, L. Chen, L. Sun, Energy Environ. Sci. 5 (2012) 6763–6778. doi: 10.1039/c2ee03309g
48. [48]
  M.E. Ahmed, S. Dey, M.Y. Darensbourg, A. Dey, J. Am. Chem. Soc. 140 (2018) 12457–12468. doi: 10.1021/jacs.8b05983
49. [49]
  P. Sun, D. Yang, Y. Li, B. Wang, J. Qu, Dalton Trans. 49 (2020) 2151–2158. doi: 10.1039/c9dt04493k
50. [50]
  V. Artero, M. Fontecave, Chem. Soc. Rev. 4 (2013) 2338–2356.
51. [51]
  M. Fang, M.H. Engelhard, Z. Zhu, M.L. Helm, J.A.S. Roberts, ACS Catal. 4 (2013) 90–98.
1. [1]
  Ali Niazi , Ateesa Yazdanipour . Simultaneous spectrophotometric determination of cobalt,copper and nickel using 1-(2-thiazolylazo)-2-naphthol by chemometrics methods. Chinese Chemical Letters, 2008, 19(7): 860-864. doi: 10.1016/j.cclet.2008.04.047
2. [2]
  Tao Zheng , Min Ren , Song-Song Bao , Li-Min Zheng . M₂(pbtcH)(phen)₂(H₂O)₂ [M(II)=Co, Ni]：Mixed-ligated metal phosphonates based on 5-phosphonatophenyl-1,2,4-tricarboxylic acid showing double chain structures. Chinese Chemical Letters, 2014, 25(6): 835-838. doi: 10.1016/j.cclet.2014.05.005
3. [3]
  Wen-Jia Cai , Lin-Ping Qian , Bin Yue , Xue-Ying Chen , He-Yong He . Reforming of CH₄ with CO₂ over Co/Mγ-Al oxide catalyst. Chinese Chemical Letters, 2013, 24(9): 777-779.
4. [4]
  Jahan-Bakhsh Raoof , Sayed Reza Hosseini , Seyedeh Zeinab Mousavi-Sani . Improved hydrogen evolution on glassy carbon electrode modified with novel Pt/cetyltrimethylammonium bromide nanoscale aggregates. Chinese Journal of Catalysis, 2015, 36(2): 216-220. doi: 10.1016/S1872-2067(14)60207-2
5. [5]
  Dong Jin Qian , Ai Rong Liu , Chikashi Nakamura , Stephan Olav Wenk , Jun Miyake . Photoinduced hydrogen evolution in an artificial system containing photosystem I,hydrogenase,methyl viologen and mercaptoacetic acid. Chinese Chemical Letters, 2008, 19(5): 607-610. doi: 10.1016/j.cclet.2008.03.015
6. [6]
  Mingjun Ma , Haiqing Wang , Hong Liu . Steering spatially separated dual sites on nano-TiO₂ through SMSI and lattice matching for robust photocatalytic hydrogen evolution. Chinese Chemical Letters, 2021, 32(11): 3613-3618. doi: 10.1016/j.cclet.2021.04.012
7. [7]
  Jie Wang , Wu Yang , Jie Ren , Miao Guo , Xiao Dong Chen , Wen Bin Wang , Jin Zhang Gao . Trace determination of cobalt ion by using malic acid-malonic acid double substrate oscillating chemical system. Chinese Chemical Letters, 2008, 19(9): 1103-1107. doi: 10.1016/j.cclet.2008.06.012
8. [8]
  Ezzat Rafiee , Nasibeh Rahpeyma . Selective oxidation of sulfurs and oxidation desulfurization of model oil by 12-tungstophosphoric acid on cobalt-ferrite nanoparticles as magnetically recoverable catalyst. Chinese Journal of Catalysis, 2015, 36(8): 1342-1349. doi: 10.1016/S1872-2067(15)60862-2
9. [9]
  Min GU , Fang Zu YANG , Ling HUANG , Shi Bing YAO , Shao Min ZHOU . Identification of Different Cobalt Nucleation on Glassy Carbon. Chinese Chemical Letters, 2004, 15(8): 981-984.
10. [10]
  Men Yana , Su Jun , Wang Xiangli , Cai Ping , Cheng Gongzhen , Luo Wei . NiPt nanoparticles supported on CeO₂ nanospheres for efficient catalytic hydrogen generation from alkaline solution of hydrazine. Chinese Chemical Letters, 2019, 30(3): 634-637. doi: 10.1016/j.cclet.2018.11.010
11. [11]
  Sanjay Srivastava , Pravakar Mohanty , Jigisha K. Parikh , Ajay K. Dalai , S. S. Amritphale , Anup K. Khare . Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derived α-, β-unsaturated aldehyde to alcohol. Chinese Journal of Catalysis, 2015, 36(7): 933-942. doi: 10.1016/S1872-2067(15)60870-1
12. [12]
  Shuvo Jit Datta , Kyung Byung Yoon . Co-ETS-10 and Co-AM-6 as active catalysts for the oxidation of styrene to styrene oxide and benzaldehyde using molecular oxygen. Chinese Journal of Catalysis, 2015, 36(6): 897-905. doi: 10.1016/S1872-2067(15)60864-6
13. [13]
  Yuan-Ye Jiang , Hai-Zhu Yu , Jing Shi . Mechanistic study on the regioselectivity of Co-catalyzed hydroacylation of 1,3-dienes. Chinese Chemical Letters, 2015, 26(1): 58-62. doi: 10.1016/j.cclet.2014.10.021
14. [14]
  Pan Jinbo , Shen Sheng , Zhou Wei , Tang Jie , Ding Hongzhi , Wang Jinbo , Chen Lang , Au Chak-Tong , Yin Shuang-Feng . Recent Progress in Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2020, 36(3): 1905068-0. doi: 10.3866/PKU.WHXB201905068
15. [15]
  Song Dengmeng , Gao Xuyun , Li Bo , Li Jun , Sun Xuzhuo , Li Chengbo , Zhao Jiale , Chen Lin , Wang Ning . Synthesis, structure and electrocatalytic H₂-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases. Chinese Chemical Letters, 2020, 31(9): 2483-2486. doi: 10.1016/j.cclet.2020.01.033
16. [16]
  Li Weidong , Liu Yuan , Wang Boyang , Song Haoqiang , Liu Zhongyi , Lu Siyu , Yang Bai . Kilogram-scale synthesis of carbon quantum dots for hydrogen evolution, sensing and bioimaging. Chinese Chemical Letters, 2019, 30(12): 2323-2327. doi: 10.1016/j.cclet.2019.06.040
17. [17]
  Wang Yixuan , He Fengting , Chen Lin , Shang Jie , Wang Jiajia , Shuaijun Wang , Song Huimin , Zhang Jinqiang , Zhao Chaocheng , Wang Shaobin , Sun Hongqi . Acidification and bubble template derived porous g-C₃N₄ for efficient photodegradation and hydrogen evolution. Chinese Chemical Letters, 2020, 31(10): 2668-2672. doi: 10.1016/j.cclet.2020.08.003
18. [18]
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19. [19]
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20. [20]
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