Citation: Jilei Wang, Jiapeng Cao, Zeyu Du, Xiaomei Liu, Jianian Li, Qingdong Ping, Tingting Zang, Yan Xu. Four novel Z-shaped hexanuclear vanadium oxide clusters as efficient heterogeneous catalysts for cycloaddition of CO₂ and oxidative desulfurization reactions[J]. Chinese Chemical Letters, ;2023, 34(1): 106917. doi: 10.1016/j.cclet.2021.11.005 shu

Four novel Z-shaped hexanuclear vanadium oxide clusters as efficient heterogeneous catalysts for cycloaddition of CO₂ and oxidative desulfurization reactions

Jilei Wang ^a ,
Jiapeng Cao ^a ,
Zeyu Du ^a ,
Xiaomei Liu ^a ,
Jianian Li ^a ,
Qingdong Ping ^a ,
Tingting Zang ^a ,
Yan Xu ^{a, b, *,}

a.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, China
b.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

yanxu@njtech.edu.cn

Received Date: 27 September 2021
Revised Date: 26 October 2021
Accepted Date: 1 November 2021
Available Online: 7 November 2021

Figures(5)

Chemical fixation of CO₂ into C1 source, as a general approach, can effectively alleviate the emission of greenhouse gasses. Whereas, the challenge posed by the need for efficient catalysts with high catalytic active sites still exists. In this work, we reported a series of new hexavanadate clusters, [(C₆H₆ON)₂(C₂H₈N₂)₂(CH₃O)₆V₆^IVO₈] (V₆–1), [(C₆H₆ON)₂(C₃H₁₀N₂)₂(CH₃O)₆V₆^IVO₈] (V₆–2), [(C₆H₆ON)₂(C₆H₁₄N₂)₂(CH₃O)₆V₆^IVO₈] (V₆–3) and [(C₆H₆ON)₂(C₄H₁₁N₂O)₂(CH₃O)₄V₆^IVO₈] (V₆–4), assembled by 2-aminophenol and four different kinds of Lewis bases (LB), ethanediamine (en), 1,2-diaminopropane, 1,2-cyclohexanediamine and N-(2-hydroxyethyl)ethylenediamine (ben) together. Among them, the basic unit {V₆} cluster featured Z-shaped configuration represents a brand-new example of hexanuclear vanadium clusters. Remarkably, the catalytic tests demonstrated that V₆–1 as catalyst displays high catalytic activity in the cycloaddition for the CO₂ fixation into cyclic carbonates by virtue of open V sites. As expected, for oxidative desulfurization of sulfides, V₆–1 also exhibits satisfied catalytic effectiveness. Furthermore, the recycling test confirmed that catalyst V₆–1 may be a bifunctional heterogeneous catalyst with great promise for both CO₂ cycloaddition and oxidative desulfurization reactions.
- Z-shaped,
- Hexavanadate cluster,
- Lewis acid catalyst,
- Cycloaddition of CO₂,
- Oxidative desulfurization
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沈阳化工大学材料科学与工程学院沈阳 110142

Four novel Z-shaped hexanuclear vanadium oxide clusters as efficient heterogeneous catalysts for cycloaddition of CO2 and oxidative desulfurization reactions

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通讯作者: 陈斌, bchen63@163.com

Four novel Z-shaped hexanuclear vanadium oxide clusters as efficient heterogeneous catalysts for cycloaddition of CO₂ and oxidative desulfurization reactions