Citation: Huimin Wu, Peibo Gao, Jinglin Mu, Zhichao Miao, Pengfei Zhou, Tong Zhou, Jin Zhou. Matryoshka-type carbon-stabilized hollow Si spheres as an advanced anode material for lithium-ion batteries[J]. Chinese Chemical Letters, ;2022, 33(6): 3236-3240. doi: 10.1016/j.cclet.2021.10.039 shu

Matryoshka-type carbon-stabilized hollow Si spheres as an advanced anode material for lithium-ion batteries

Huimin Wu ^a ,
Peibo Gao ^{b, *,} ,
Jinglin Mu ^a ,
Zhichao Miao ^a ,
Pengfei Zhou ^a ,
Tong Zhou ^b ,
Jin Zhou ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, China
b.
School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255049, China

pbgao@sdut.edu.cn

zhoujin@sdut.edu.cn

Received Date: 22 August 2021
Revised Date: 26 September 2021
Accepted Date: 15 October 2021
Available Online: 22 October 2021

Figures(5)

Silicon (Si) is regarded as the potential anode for lithium-ion batteries (LIBs), due to the remarkable theoretical specific capacity and low voltage plateau. However, the rapid capacity decay resulting from volume variation and slow electron/ion transportation of Si limit its practical application. Here, matryoshka-type carbon-stabilized hollow silicon spheres (Si/C/Si/C) are synthesized by an aluminothermic reduction and calcination process. The Si/C/Si/C anode materials prepared at 500 ℃ (Si/C/Si/C-500) exhibit unique structures, in which amorphous region and porous structure are preserved in the Si layers. The anode based on Si/C/Si/C-500 displays an initial specific capacity of 2792 mAh/g at a current density of 100 mA/g. At 1000 mA/g, this anode retains a reversible capacity of 1673 mAh/g, 86.9% of the initial capacity after 200 cycles. Such synthetic strategy can be employed to fabricate other high-capacity anode materials with large volume variation during charge/discharge process
- Lithiun-ion battery,
- Hollow Si,
- Matryoshka structure,
- Anode,
- Molten salts
1. [1]
  J.R. Szczech, S. Jin, Energy Environ. Sci.4 (2011) 56–72. doi: 10.1039/C0EE00281J
2. [2]
  H. Wu, Y. Cui, Nano Today 7 (2012) 414–429. doi: 10.1016/j.nantod.2012.08.004
3. [3]
  N. Liu, K. Huo, M.T. McDowell, J. Zhao, Y. Cui, Sci. Rep. 3 (2013) 1919. doi: 10.1038/srep01919
4. [4]
  X. Su, Q. Wu, J. Li, et al., Adv. Energy Mater. 4 (2014) 1300882. doi: 10.1002/aenm.201300882
5. [5]
  S. Chen, L. Shen, P.A. van Aken, J. Maier, Y. Yu, Adv. Mater. 29 (2017) 1605650. doi: 10.1002/adma.201605650
6. [6]
  S. Heon-Cheol, C.J. A, G.J. L, L.M. Lin, J. Power Sources 139 (2005) 314–320. doi: 10.1016/j.jpowsour.2004.06.073
7. [7]
  B. Liu, X. Wang, H. Chen, et al., Sci. Rep. 3 (2013) 1622. doi: 10.1038/srep01622
8. [8]
  M.Y. Ge, J.P. Rong, X. Fang, C.W. Zhou, Nano Lett. 12 (2012) 2318–2323. doi: 10.1021/nl300206e
9. [9]
  Y. Wang, T. Wang, P. Da, et al., Adv. Mater. 25 (2013) 5177–5195. doi: 10.1002/adma.201301943
10. [10]
  H. Lin, W. Weng, J. Ren, et al., Adv. Mater. 26 (2014) 1217–1222. doi: 10.1002/adma.201304319
11. [11]
  W.S. Kim, Y. Hwa, J.H. Shin, et al., Nanoscale 6 (2014) 4297–4302. doi: 10.1039/c3nr05354g
12. [12]
  J. Ryu, D. Hong, S. Choi, S. Park, ACS Nano 10 (2016) 2843–2851. doi: 10.1021/acsnano.5b07977
13. [13]
  Z.H. Bao, M.R. Weatherspoon, S. Shian, et al., Nature 446 (2007) 172–175. doi: 10.1038/nature05570
14. [14]
  M.Y. Ge, J.P. Rong, X. Fang, et al., Nano Res. 6 (2013) 174–181. doi: 10.1007/s12274-013-0293-y
15. [15]
  Z. Zhou, L. Pan, Y. Liu, X. Zhu, X. Xie, Chin. Chem. Lett. 30 (2019) 610–617. doi: 10.1016/j.cclet.2018.08.018
16. [16]
  D. Vrankovic, M. Graczyk-Zajac, C. Kalcher, et al., ACS Nano 11 (2017) 11409–11416. doi: 10.1021/acsnano.7b06031
17. [17]
  J. Hu, Q. Wang, L. Fu, et al., ACS Appl. Mater. Interfaces 12 (2020) 48467–48475. doi: 10.1021/acsami.0c10418
18. [18]
  S. Geng, T. Zhou, M. Jia, et al., Energy Environ. Sci. 14 (2021) 3184–3193. doi: 10.1039/d1ee00193k
19. [19]
  N. Liu, H. Wu, M.T. McDowell, et al., Nano Lett. 12 (2012) 3315–3321. doi: 10.1021/nl3014814
20. [20]
  P. Gao, X. Huang, Y. Zhao, et al., ACS Nano 12 (2018) 11481–11490. doi: 10.1021/acsnano.8b06528
21. [21]
  N. Lin, Y. Han, J. Zhou, et al., Energy Environ. Sci. 8 (2015) 3187–3191. doi: 10.1039/C5EE02487K
22. [22]
  W. Weng, C. Zeng, W. Xiao, ACS Appl. Mater. Interfaces 11 (2019) 9156–9163. doi: 10.1021/acsami.9b00265
23. [23]
  W. Xiao, D. Wang, Chem. Soc. Rev. 43 (2014) 3215–3228. doi: 10.1039/c3cs60327j
24. [24]
  W. Luo, X. Wang, C. Meyers, et al., Sci. Rep. 3 (2013) 2222. doi: 10.1038/srep02222
25. [25]
  L. Wang, N. Lin, J. Zhou, Y. Zhu, Y. Qian, Chem. Commun. 51 (2015) 2345–2348. doi: 10.1039/C4CC09233C
26. [26]
  L. Lin, X. Xu, C. Chu, M.K. Majeed, J. Yang, Angew. Chem. Int. Ed. 55 (2016) 14063–14066. doi: 10.1002/anie.201608146
27. [27]
  B. Wang, X. Li, X. Zhang, et al., Adv. Mater. 25 (2013) 3560–3565. doi: 10.1002/adma.201300844
28. [28]
  N.H. Hai, I. Grigoriants, A. Gedanken, J. Phys. Chem. C 113 (2009) 10521–10526. doi: 10.1021/jp809432t
29. [29]
  P. Gao, H. Tang, A. Xing, Z. Bao, Electrochim. Acta 228 (2017) 545–552. doi: 10.1016/j.electacta.2017.01.119
30. [30]
  L. Zhenda, L. Nian, L. Hyun-Wook, et al., ACS Nano 9 (2015) 2540–2547. doi: 10.1021/nn505410q
31. [31]
  B. Gao, K. Kakimoto, J. Cryst. Growth 396 (2014) 7–13. doi: 10.1016/j.jcrysgro.2014.03.034
32. [32]
  Y. An, Y. Tian, C. Wei, et al., ACS Nano 13 (2019) 13690–13701. doi: 10.1021/acsnano.9b06653
33. [33]
  L. Ding, J.P. Raskin, G. Lumbeeck, D. Schryvers, H. Idrissi, Mater. Charact. 161 (2020) 110174. doi: 10.1016/j.matchar.2020.110174
34. [34]
  H.F. Lopez, H. Mendoza, ISRN Nanomater. 2013 (2013) 208614.
35. [35]
  A. Magasinski, P. Dixon, B. Hertzberg, et al., Nat. Mater. 9 (2010) 353–358. doi: 10.1038/nmat2725
36. [36]
  X. Huang, X. Guo, Y. Ding, et al., Chin. Chem. Lett. 32 (2021) 598–603. doi: 10.1016/j.cclet.2020.11.041
37. [37]
  P. Gao, S. Xu, Z. Chen, et al., ACS Appl. Mater. Interfaces 10 (2018) 3938–3947. doi: 10.1021/acsami.7b16174
38. [38]
  W. Yang, W. Yang, A. Song, et al., J. Power Sources 348 (2017) 175–182. doi: 10.1504/IJCSM.2017.083756
39. [39]
  W. -. S. Kim, J. Choi, S. -. H. Hong, Nano Res. 9 (2016) 2174–2181. doi: 10.1007/s12274-016-1106-x
40. [40]
  X.H. Liu, L. Zhong, S. Huang, et al., ACS Nano 6 (2012) 1522–1531. doi: 10.1021/nn204476h
41. [41]
  F. Shi, Z. Song, P.N. Ross, et al., Nat. Commun. 7 (2016) 11886. doi: 10.1038/ncomms11886
42. [42]
  R. Fang, S. Zhao, P. Hou, et al., Adv. Mater. 28 (2016) 3374–3382. doi: 10.1002/adma.201506014
43. [43]
  F. Dai, J.T. Zai, R. Yi, et al., Nat. Commun. 5 (2014) 3605. doi: 10.1038/ncomms4605
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