Citation: Lin Wang, Xinzhe Li, Chengjie Pei, Cong Wei, Jie Dai, Xiao Huang, Hai Li. Single- and few-layer 2H-SnS₂ and 4H-SnS₂ nanosheets for high-performance photodetection[J]. Chinese Chemical Letters, ;2022, 33(5): 2611-2616. doi: 10.1016/j.cclet.2021.09.094 shu

Single- and few-layer 2H-SnS₂ and 4H-SnS₂ nanosheets for high-performance photodetection

Key Laboratory of Flexible Electronic (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University, Nanjing 211816, China

iamxhuang@njtech.edu.cn

iamhli@njtech.edu.cn

Received Date: 20 August 2021
Revised Date: 23 September 2021
Accepted Date: 26 September 2021
Available Online: 30 September 2021

Figures(6)

The properties of two-dimensional (2D) materials are highly dependent on their phase and thickness. Various phases exist in tin disulfide (SnS₂), resulting in promising electronic and optical properties. Hence, accurately identifying the phase and thickness of SnS₂ nanosheets is prior to their optoelectronic applications. Herein, layered 2H-SnS₂ and 4H-SnS₂ crystals were grown by chemical vapor transportation and the crystalline phase of SnS₂ was characterized by X-ray diffraction, ultralow frequency (ULF) Raman spectroscopy and high-resolution transmission electron microscope. As-grown crystals were mechanically exfoliated to single- and few-layer nanosheets, which were investigated by optical microscopy, atomic force microscopy and ULF Raman spectroscopy. Although the 2H-SnS₂ and 4H-SnS₂ nanosheets have similar optical contrast on SiO₂/Si substrates, their ULF Raman spectra obviously show different shear and breathing modes, which are highly dependent on their phases and thicknesses. Interestingly, the SnS₂ nanosheets have shown phase-dependent electrical properties. The 4H-SnS₂ nanosheet shows a current on/off ratio of 2.58 × 10⁵ and excellent photosensitivity, which are much higher than those of the 2H-SnS₂ nanosheet. Our work not only offers an accurate method for identifying single- and few-layer SnS₂ nanosheets with different phases, but also paves the way for the application of SnS₂ nanosheets in high-performance optoelectronic devices.
- Tin disulfide,
- 2H and 4H phases,
- Phase-dependent behavior,
- Ultralow-frequency Raman spectroscopy,
- Photodetection
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Single- and few-layer 2H-SnS2 and 4H-SnS2 nanosheets for high-performance photodetection

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通讯作者: 陈斌, bchen63@163.com

Single- and few-layer 2H-SnS₂ and 4H-SnS₂ nanosheets for high-performance photodetection