Citation: Qifei Li, Xiangxiang Ye, Hong Yu, Chengfeng Du, Wenping Sun, Weiling Liu, Hongge Pan, Xianhong Rui. Pre-potassiated hydrated vanadium oxide as cathode for quasi-solid-state zinc-ion battery[J]. Chinese Chemical Letters, ;2022, 33(5): 2663-2668. doi: 10.1016/j.cclet.2021.09.091 shu

Pre-potassiated hydrated vanadium oxide as cathode for quasi-solid-state zinc-ion battery

Qifei Li ^a ,
Xiangxiang Ye ^a ,
Hong Yu ^{b, *,} ,
Chengfeng Du ^b ,
Wenping Sun ^{c, d} ,
Weiling Liu ^e ,
Hongge Pan ^{c, d} ,
Xianhong Rui ^{a, *,}

a.
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
b.
Center of Advanced Lubrication and Seal Materials, Northwestern Polytechnical University, Xi'an 710072, China
c.
Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an 710021, China
d.
School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China
e.
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

yh@nwpu.edu.cn

xhrui@gdut.edu.cn

Received Date: 22 July 2021
Revised Date: 11 September 2021
Accepted Date: 25 September 2021
Available Online: 30 September 2021

Figures(5)

Zinc-ion batteries (ZIBs), in particular quasi-solid-state ZIBs, occupy a crucial position in the field of energy storage devices owing to the superiorities of abundant zinc reserve, low cost, high safety and high theoretical capacity of zinc anode. However, as divalent Zn²⁺ ions experience strong electrostatic interactions when intercalating into the cathode materials, which poses challenges to the structural stability and higher demand in Zn²⁺ ions diffusion kinetics of the cathode materials. Here, a microwave-assisted hydrothermal method is adopted to prepare pre-potassiated hydrated vanadium pentoxide (K_0.52V₂O₅·0.29H₂O, abbreviated as KHVO) cathode material, in which the potassium ions pre-inserted into the interlayers can act as "pillars" to stabilize the lamellar structure, and crystal water can act as "lubricant" to improve the diffusion efficiency of Zn²⁺ ions. Consequently, the KHVO displays high electrochemical properties with high capacity (~300 mAh/g), superior rate capability (69 mAh/g at 5 A/g) and ultralong cycling performance (> 1500 cycles at 2 A/g) in quasi-solid-state ZIBs. These superior Zn storage properties result from the large diffusion coefficient and highly stable and reversible Zn²⁺ (de)intercalation reaction of KHVO.
- Quasi-solid-state,
- Zinc-ion batteries,
- Hydrated vanadium oxide,
- Pre-potassiated,
- Electrochemical kinetics
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