Citation: Jiabin Shen, Jun Xu, Lei He, Chenfeng Liang, Wanmei Li. Application of Langlois' reagent (NaSO₂CF₃) in C–H functionalisation[J]. Chinese Chemical Letters, ;2022, 33(3): 1227-1235. doi: 10.1016/j.cclet.2021.09.005 shu

Application of Langlois' reagent (NaSO₂CF₃) in C–H functionalisation

College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

liwanmei@hznu.edu.cn

Received Date: 8 July 2021
Revised Date: 31 August 2021
Accepted Date: 1 September 2021
Available Online: 9 September 2021

Figures(28)

The process of selectively introducing a CF₃ group into an organic molecule using inexpensive, stable, and solid sodium trifluoromethanesulfinate has rapidly advanced in recent years to become an eco-friendly method used by organic chemists to synthesize various natural and bioactive molecules. This review focuses on advances made within the last five years regarding C–H functionalisation, namely thermochemical C(sp²)–H (thio)trifluoromethylations, photochemical C(sp²)–H trifluoromethylations, and electrochemical C(sp²)–H trifluoromethylations, using Langlois' reagent (NaSO₂CF₃).
- Trifluoromethylation,
- Langlois' reagent,
- Reaction mechanism,
- Synthetic method,
- C–H activation
1. [1]
  J. R. Pinchman, D. L. Boger, J. Med. Chem. 56 (2013) 4116–4124. doi: 10.1021/jm4004494
2. [2]
  J. L. Gilmore, J. E. Sheppeck, S. H. Watterson, et al., J. Med. Chem. 59 (2016) 6248–6264. doi: 10.1021/acs.jmedchem.6b00373
3. [3]
  L. Yu, M. Huang, T. Xu, et al., Eur. J. Med. Chem. 126 (2017) 1107–1117. doi: 10.1016/j.ejmech.2016.12.006
4. [4]
  J. Wu, Y. Cheng, J. Lan, D. Wu, S. Qian, J. Am. Chem. Soc. 138 (2016), 12803–12812. doi: 10.1021/jacs.6b03890
5. [5]
  S. Li, J.A. Ma, Chem. Soc. Rev. 44 (2015) 7439–7448. doi: 10.1039/C5CS00342C
6. [6]
  N. Meng, Y. Lv, Q. Liu, et al., Chin. Chem. Lett. 32 (2021) 258–262. doi: 10.1016/j.cclet.2020.11.034
7. [7]
  R. Tao, X.J. Yin, K.H. Wang, et al., Chin. Chem. Lett. 26 (2015) 1046–1049. doi: 10.1016/j.cclet.2015.04.015
8. [8]
  K. Muller, C. Faeh, F. Diederich, Science 317 (2007) 1881–1886. doi: 10.1126/science.1131943
9. [9]
  M. Hird, Chem. Soc. Rev. 36 (2007) 2070–2095. doi: 10.1039/b610738a
10. [10]
  K.L. Kirk, Org. Process Res. Dev. 12 (2008) 305–321. doi: 10.1021/op700134j
11. [11]
  H. Mei, A.M. Remete, Y. Zou, et al., Chin. Chem. Lett. 31 (2020) 2401–2413. doi: 10.1016/j.cclet.2020.03.050
12. [12]
  T. Furuya, A.S. Kamlet, T. Ritter, Nature 473 (2011) 470–477. doi: 10.1038/nature10108
13. [13]
  O.A. Tomashenko, V.V. Grushin, Chem. Rev. 111 (2011) 4475–4521. doi: 10.1021/cr1004293
14. [14]
  T. Umemoto, Chem. Rev. 96 (1996) 1757–1777. doi: 10.1021/cr941149u
15. [15]
  L. Ting, R. Shou, H. Mei, C. Cheng, S. Cai, Chin. Chem. Lett. 21 (2010) 1247–1250.
16. [16]
  F. Bull. Swarts Acad. Roy. Belg. 24 (1892) 309–311.
17. [17]
  J.H. Simons, C.J. Lewis, J. Am. Chem. Soc. 60 (1938) 492–493. doi: 10.1021/ja01269a507
18. [18]
  T. Furuya, A.S. Kamlet, T. Ritter, Nature 437 (2011) 470–477. doi: 10.1038/nature10108
19. [19]
  O.A. Tomashenko, E.C. Escudero-Adán, M.M. Belmonte, V.V. Grushin, Angew. Chem. Int. Ed. 50 (2011) 7655–7659. doi: 10.1002/anie.201101577
20. [20]
  Y. Ye, M.S. Sanford, J. Am. Chem. Soc. 134 (2012) 9034–9037. doi: 10.1021/ja301553c
21. [21]
  K. Zhang, X.H. Xu, F.L. Qing, J. Org. Chem. 80 (2015) 7658–7665. doi: 10.1021/acs.joc.5b01295
22. [22]
  J. Hong, G. Wang, L. Huo, C. Zheng, Chin. J. Chem. 35 (2017) 1761–1767. doi: 10.1002/cjoc.201700311
23. [23]
  Z. Bazyar, M. Hosseini-Sarvari, Org. Process Res. Dev. 23 (2019) 2345–2353. doi: 10.1021/acs.oprd.9b00225
24. [24]
  D.H. Yu, J.N. Shao, R.X. He, M. Li, Chin. Chem. Lett. 26 (2015) 564–566. doi: 10.1016/j.cclet.2014.12.017
25. [25]
  R.P. Bhaskaran, B.P. Babu, Adv. Synth. Catal. 362 (2020) 5219–5237. doi: 10.1002/adsc.202000996
26. [26]
  X. Pan, H. Xia, J. Wu, Org. Chem. Front. 3 (2016) 1163–1185. doi: 10.1039/C6QO00153J
27. [27]
  Q. Lefebvre, Synlett. 28 (2017) 19–23.
28. [28]
  S. Barata-Vallejo, A. Postigo, Chem. Eur. J. 26 (2020) 11065–11084. doi: 10.1002/chem.202000856
29. [29]
  O.A. Tomashenko, V.V. Grushin, Chem. Rev. 111 (2011) 4475–4521. doi: 10.1021/cr1004293
30. [30]
  A. Studer, Angew. Chem. Int. Ed. 51 (2012) 8950–8958. doi: 10.1002/anie.201202624
31. [31]
  C. Zhang, Adv. Synth. Catal. 356 (2014) 2895–2906. doi: 10.1002/adsc.201400370
32. [32]
  M. Tordeux, B.R. Langlois, C. Wakselman, J. Org. Chem. 54 (1989) 2452–2453. doi: 10.1021/jo00271a041
33. [33]
  B.R. Langlois, E. Laurent, N. Roidot, Tetrahedron Lett. 32 (1991) 7525–7528. doi: 10.1016/0040-4039(91)80524-A
34. [34]
  B.R. Langlois, T. Billard, J.C. Mulatier, C. Yezegue-lian, J. Fluor. Chem. 128 (2007) 851–856. doi: 10.1016/j.jfluchem.2007.04.012
35. [35]
  H.P. Cao, Q.Y. Chen, J. Fluor. Chem. 128 (2007) 1187–1190. doi: 10.1016/j.jfluchem.2007.04.018
36. [36]
  R.C. Simon, E. Busto, N. Richter, et al., Nat. Commun. 7 (2016) 13323. doi: 10.1038/ncomms13323
37. [37]
  J. Xu, K. Cheng, C. Shen, et al., ChemCatChem 10 (2018) 965–970. doi: 10.1002/cctc.201701596
38. [38]
  X. Shi, X. Li, L. Ma, D. Shi, Catalysts 9 (2019) 278–291. doi: 10.3390/catal9030278
39. [39]
  L.H. Wu, K. Zhao, Z.L. Shen, T.P. Loh, Org. Chem. Front. 4 (2017) 1872–1875. doi: 10.1039/C7QO00416H
40. [40]
  H. B. Yang, N. Selander, Org. Biomol. Chem. 15 (2017) 1771–1775. doi: 10.1039/C7OB00203C
41. [41]
  C. Shen, J. Xu, B. Ying, P. Zhang, ChemCatChem 8 (2016) 3560–3564. doi: 10.1002/cctc.201601068
42. [42]
  S.Z. Sun, H. Xu, H.X. Dai, Chin. Chem. Lett. 30 (2019) 969–972. doi: 10.1016/j.cclet.2019.02.011
43. [43]
  Y. Zhu, J. Tian, X. Gu, Y. Wang, J. Org. Chem. 83 (2018) 13267–13275. doi: 10.1021/acs.joc.8b02073
44. [44]
  G.B. Li, C. Zhang, Chun Song, Y.D. Ma, Beilstein J. Org. Chem. 14 (2018) 155–181. doi: 10.3762/bjoc.14.11
45. [45]
  Y.A. Konik, M. Kudrjashova, N. Konrad, et al., Org. Biomol. Chem. 15 (2017) 4635–4643. doi: 10.1039/C7OB00680B
46. [46]
  Q. Wang, P. Shi, R. Zeng, RSC Adv. 8 (2018) 25961–25965. doi: 10.1039/C8RA04088E
47. [47]
  J. Xu, L. Qiao, J. Shen, et al., Org. Lett. 19 (2017) 5661–5664. doi: 10.1021/acs.orglett.7b02823
48. [48]
  C. Li, K. Suzuki, K. Yamaguchi, N. Mizuno, New J. Chem. 41 (2017) 1417–1420. doi: 10.1039/C6NJ03654F
49. [49]
  H.L. Huang, H. Yan, G.L. Gao, C. Yang, W. Xia, Asian J. Org. Chem. 7 (2015) 674–677. doi: 10.1002/ajoc.201500096
50. [50]
  D. Liang, Q. Dong, P. Xu, et al., J. Org. Chem. 83 (2018) 11978–11986. doi: 10.1021/acs.joc.8b01861
51. [51]
  F. Gao, F.X. Meng, J.Y. Du, S. Zhang, H.L. Huang, Eur. J. Org. Chem. 2020 (2020) 209–212. doi: 10.1002/ejoc.201901636
52. [52]
  N. Meng, L. Wang, Q. Liu, et al., J. Org. Chem. 85 (2020) 6888–6896. doi: 10.1021/acs.joc.9b03505
53. [53]
  L. H. Lu, Z. Wang, W. Xia, et al., Chin. Chem. Lett. 30 (2019) 1237–1240. doi: 10.1016/j.cclet.2019.04.033
54. [54]
  Z. Lu, O. Hennis, J. Gentry, B. Xu, G.B. Hammond, Org. Lett. 22 (2020) 4383–4388. doi: 10.1021/acs.orglett.0c01395
55. [55]
  D. Wang, G.J. Deng, S. Chen, H. Gong, Green Chem. 18 (2016) 5967–5970. doi: 10.1039/C6GC02000C
56. [56]
  L. Wang, Y. Zhang, F. Li, et al., Adv. Synth. Catal. 360 (2018) 3969–3977. doi: 10.1002/adsc.201800863
57. [57]
  J.M. Lear, J.Q. Buquoi, X. Gu, et al., Chem. Commun. 55 (2019) 8820–8823. doi: 10.1039/c9cc03498f
58. [58]
  Z. Wu, Y. He, C. Ma, et al., Asian J. Org. Chem. 5 (2016) 724–728. doi: 10.1002/ajoc.201600128
59. [59]
  X. Xua, F. Liu, Org. Chem. Front. 4 (2017) 2306–2310. doi: 10.1039/C7QO00635G
60. [60]
  Z. Tan, S. Zhang, Y. Zhang, et al., J. Org. Chem. 82 (2017) 9384–9399. doi: 10.1021/acs.joc.7b01359
61. [61]
  Y. Yang, L. Xu, S. Yu, et al., Chem. Eur. J. 22 (2016) 858–863. doi: 10.1002/chem.201504790
62. [62]
  S. Lu, W. Chen, Q. Shen, Chin. Chem. Lett. 30 (2019) 2279–2281. doi: 10.1016/j.cclet.2019.07.060
63. [63]
  Y. Guo, M.W. Huang, X.L. Fu, et al., Chin. Chem. Lett. 28 (2017) 719–728. doi: 10.1016/j.cclet.2017.02.006
64. [64]
  M.J. Bu, G.P. Lu, C. Cai, Org. Chem. Front. 4 (2017) 266–270. doi: 10.1039/C6QO00622A
65. [65]
  D.W. Sun, X. Jiang, M. Jiang, Y. Lin, J.T. Liu, Eur. J. Org. Chem. (2017) 3505–3511. doi: 10.1002/ejoc.201700661
66. [66]
  Q. Yan, L. Jiang, W. Yi, Q. Liu, W. Zhang, Adv. Synth. Catal. 359 (2017) 2471–2480. doi: 10.1002/adsc.201700270
67. [67]
  X. Zhao, A. Wei, B. Yang, et al., J. Org. Chem. 82 (2017) 9175–9181. doi: 10.1021/acs.joc.7b01226
68. [68]
  Z. Q. Liu, D. Liu, J. Org. Chem. 82 (2017) 1649–1656. doi: 10.1021/acs.joc.6b02812
69. [69]
  K. Lu, X. Wei, Q. Li, et al., Org. Chem. Front. 6 (2019) 3766–3770. doi: 10.1039/c9qo00940j
70. [70]
  Q. Lefebvre, N. Hoffmann, M. Rueping, Chem. Commun. 52 (2016) 2493–2496. doi: 10.1039/C5CC09881E
71. [71]
  S. Corsico, M. Fagnoni, D. Ravelli, Photochem. Photobiol. Sci. 16 (2017) 1375–1380. doi: 10.1039/C7PP00179G
72. [72]
  S. A. Miller, B. van Beek, T. A. Hamlin, et al., J. Fluor. Chem. 214 (2018) 94–100. doi: 10.1016/j.jfluchem.2018.08.005
73. [73]
  Q. Zhou, S. Xu, R. Zhang, Tetrahedron Lett. 60 (2019) 734–738. doi: 10.1016/j.tetlet.2019.02.003
74. [74]
  A. Murugan, V. N. Babu, A. Polu, et al., J. Org. Chem. 84 (2019) 7796–7803. doi: 10.1021/acs.joc.9b00676
75. [75]
  Z. Wei, S. Qi, Y. Xu, et al., Adv. Synth. Catal. 361 (2019) 5490–5498. doi: 10.1002/adsc.201900885
76. [76]
  Z. Bazyar, M. Hosseini-Sarvari, Org. Process Res. Dev. 23 (2019) 2345–2353. doi: 10.1021/acs.oprd.9b00225
77. [77]
  Y. Wang, X. Wang, M. Antonietti, Angew. Chem. Int. Ed. 51 (2012) 68–89. doi: 10.1002/anie.201101182
78. [78]
  I. Ghosh, J. Khamrai, A. Savateev, et al., Science 365 (2019) 360–366. doi: 10.1126/science.aaw3254
79. [79]
  C. Xia, K. Wang, G. Wang, G. Duan, Org. Biomol. Chem. 16 (2018) 2214–2218.
80. [80]
  C. Tian, Q. Wang, X. Wang, G. An, G. Li, J. Org. Chem. 84 (2019) 14241–14247. doi: 10.1021/acs.joc.9b01987
81. [81]
  L. Zhao, P. Li, H. Zhang, L. Wang, Org. Chem. Front. 6 (2019) 87–93. doi: 10.1039/c8qo01079j
82. [82]
  A. Abramov, H. Vernickel, C. Saldías, D. D. Díaz, Molecules 24 (2019) 29–40.
83. [83]
  Z. Jia, Y. Yuan, X. Zong, B. Wu, J. Ma, Chin. Chem. Lett. 30 (2019) 1488–1494.
84. [84]
  L. Li, X. Mu, W. Liu, et al., J. Am. Chem. Soc. 138 (2016) 5809–5812. doi: 10.1021/jacs.6b02782
85. [85]
  N. Lin, Y. Li, X. Hao, et al., J. Fluor. Chem. 214 (2018) 42–47.
86. [86]
  J. Wang, B. Sun, L. Zhang, et al., Asian J. Org. Chem. 8 (2019) 1942–1946. doi: 10.1002/ajoc.201900414
87. [87]
  L. Zhao, P. Li, X. Xie, L. Wang, Org. Chem. Front. 5 (2018) 1689–1697.
88. [88]
  L. Zou, P. Li, B. Wang, L. Wang, Chem. Commun. 55 (2019) 3437–3470.
89. [89]
  I. Abdiaj, C. Bottecchia, J. Alcazar, T. Noёl, Synthesis 49 (2017) 4978–4985.
90. [90]
  Y. Qiu, A. Scheremetjew, L. Ackermann, J. Am. Chem. Soc. 141 (2019) 2731–2738. doi: 10.1021/jacs.8b13692
91. [91]
  T. Gieshoff, A. Kehl, D. Schollmeyer, K.D. Moeller, S.R. Waldvogel, J. Am. Chem. Soc. 139 (2017) 12317–12324. doi: 10.1021/jacs.7b07488
92. [92]
  B.K. Peters, K.X. Rodriguez, S.H. Reisberg, et al., Science 363 (2019) 838–845. doi: 10.1126/science.aav5606
93. [93]
  H. Hong, Y. Li, L. Chen, J. Org. Chem. 84 (2019) 5980–5986. doi: 10.1021/acs.joc.9b00766
94. [94]
  Y. Deng, F. Lu, S. You, et al., Chin. J. Chem. 37 (2019) 817–820. doi: 10.1002/cjoc.201900168
95. [95]
  Y. Qiu, A. Scheremetjew, L.H. Finger, L. Ackermann, Chem. Eur. J. 26 (2020) 3241–3246. doi: 10.1002/chem.201905774
96. [96]
  C. Xua, Y. Liua, H. Liua, et al., Tetrahedron Lett. 61 (2020) 152226–152230.
97. [97]
  H. Zhang, W. Wu, Y. Mo, Comput. Theor. Chem. 1116 (2017) 50–58. doi: 10.1016/j.comptc.2017.02.005
98. [98]
  G. Choi, G.S. Lee, B. Park, D. Kim, S.H. Hong, Angew. Chem. Int. Ed. 60 (2021) 5467–5474. doi: 10.1002/anie.202012263
1. [1]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
2. [2]
  Ao Sun , Zipeng Li , Shuchun Li , Xiangbao Meng , Zhongtang Li , Zhongjun Li . Stereoselective synthesis of α-3-deoxy-D-manno-oct-2-ulosonic acid (α-Kdo) derivatives using a C3-p-tolylthio-substituted Kdo fluoride donor. Chinese Chemical Letters, 2025, 36(3): 109972-. doi: 10.1016/j.cclet.2024.109972
3. [3]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
4. [4]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
5. [5]
  Zhigang Zeng , Changzhou Liao , Lei Yu . Molecules for COVID-19 treatment. Chinese Chemical Letters, 2024, 35(7): 109349-. doi: 10.1016/j.cclet.2023.109349
6. [6]
  Xinlong Han , Huiying Zeng , Chao-Jun Li . Trifluoromethylative homo-coupling of carbonyl compounds. Chinese Chemical Letters, 2025, 36(1): 109817-. doi: 10.1016/j.cclet.2024.109817
7. [7]
  Yuhan Liu , Jingyang Zhang , Gongming Yang , Jian Wang . Highly enantioselective carbene-catalyzed δ-lactonization via radical relay cross-coupling. Chinese Chemical Letters, 2025, 36(1): 109790-. doi: 10.1016/j.cclet.2024.109790
8. [8]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
9. [9]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
10. [10]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
11. [11]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
12. [12]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
13. [13]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
14. [14]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
15. [15]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
16. [16]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
17. [17]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
18. [18]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
19. [19]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
20. [20]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172

Get Citation

PDF

XML

Metrics

PDF Downloads(52)
Abstract views(953)
HTML views(284)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Application of Langlois' reagent (NaSO2CF3) in C–H functionalisation

Metrics

通讯作者: 陈斌, bchen63@163.com

Application of Langlois' reagent (NaSO₂CF₃) in C–H functionalisation