Citation: Hui Dai, Siqi Xiong, Yongqing Zhu, Jian Zheng, Lihong Huang, Changjian Zhou, Jie Deng, Xinfeng Zhang. NiCe bimetallic nanoparticles embedded in hexagonal mesoporous silica (HMS) for reverse water gas shift reaction[J]. Chinese Chemical Letters, ;2022, 33(5): 2590-2594. doi: 10.1016/j.cclet.2021.08.129 shu

NiCe bimetallic nanoparticles embedded in hexagonal mesoporous silica (HMS) for reverse water gas shift reaction

Hui Dai ^{a, b, *,} ,
Siqi Xiong ^a ,
Yongqing Zhu ^a ,
Jian Zheng ^b ,
Lihong Huang ^a ,
Changjian Zhou ^{c, *,} ,
Jie Deng ^d ,
Xinfeng Zhang ^a

a.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China
b.
Department of Chemical Engineering, Sichuan University, Chengdu 610065, China
c.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China
d.
College of Pharmacy and Bioengineering, Chengdu University, Chengdu 610106, China

daihui18@cdut.edu.cn

zcj@ycit.cn

Received Date: 9 August 2021
Revised Date: 30 August 2021
Accepted Date: 31 August 2021
Available Online: 6 September 2021

Figures(5)

Reverse water gas shift (RWGS) reaction is a crucial process in CO₂ utilization. Herein, Ni- and NiCe-containing hexagonal mesoporous silica (Ni-HMS and NiCe-HMS) catalysts were synthesized using an in-situ one-pot method and applied for RWGS reaction. At certain reaction temperatures 500-750 ℃, Ni-HMS samples displayed a higher selectivity to the preferable CO than that of conventionally impregnated Ni/HMS catalyst. This could be originated from the smaller NiO nanoparticles over Ni-HMS catalyst. NiCe-HMS exhibited higher activity compared to Ni-HMS. The catalysts were characterized by means of TEM, XPS, XRD, H₂-TPR, CO₂-TPD, EPR and N₂ adsorption-desortion technology. It was found that introduction of Ce created high concentration of oxygen vacancies, served as the active site for activating CO₂. Also, this work analyzed the effect of the H₂/CO₂ molar ratio on the best NiCe-HMS. When reaction gas H₂/CO₂ molar ratio was 4 significantly decreased the selectivity to CO at low temperature, but triggered a higher CO₂ conversion which is close to the equilibrium.
- Greenhouse gases,
- Reverse water gas shift reaction,
- CO selectivity,
- CeO₂,
- Hexagonal mesoporous silica
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