Citation: Hui Dai, Siqi Xiong, Yongqing Zhu, Jian Zheng, Lihong Huang, Changjian Zhou, Jie Deng, Xinfeng Zhang. NiCe bimetallic nanoparticles embedded in hexagonal mesoporous silica (HMS) for reverse water gas shift reaction[J]. Chinese Chemical Letters, ;2022, 33(5): 2590-2594. doi: 10.1016/j.cclet.2021.08.129 shu

NiCe bimetallic nanoparticles embedded in hexagonal mesoporous silica (HMS) for reverse water gas shift reaction

Hui Dai ^{a, b, *,} ,
Siqi Xiong ^a ,
Yongqing Zhu ^a ,
Jian Zheng ^b ,
Lihong Huang ^a ,
Changjian Zhou ^{c, *,} ,
Jie Deng ^d ,
Xinfeng Zhang ^a

a.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China
b.
Department of Chemical Engineering, Sichuan University, Chengdu 610065, China
c.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China
d.
College of Pharmacy and Bioengineering, Chengdu University, Chengdu 610106, China

daihui18@cdut.edu.cn

zcj@ycit.cn

Received Date: 9 August 2021
Revised Date: 30 August 2021
Accepted Date: 31 August 2021
Available Online: 6 September 2021

Figures(5)

Reverse water gas shift (RWGS) reaction is a crucial process in CO₂ utilization. Herein, Ni- and NiCe-containing hexagonal mesoporous silica (Ni-HMS and NiCe-HMS) catalysts were synthesized using an in-situ one-pot method and applied for RWGS reaction. At certain reaction temperatures 500-750 ℃, Ni-HMS samples displayed a higher selectivity to the preferable CO than that of conventionally impregnated Ni/HMS catalyst. This could be originated from the smaller NiO nanoparticles over Ni-HMS catalyst. NiCe-HMS exhibited higher activity compared to Ni-HMS. The catalysts were characterized by means of TEM, XPS, XRD, H₂-TPR, CO₂-TPD, EPR and N₂ adsorption-desortion technology. It was found that introduction of Ce created high concentration of oxygen vacancies, served as the active site for activating CO₂. Also, this work analyzed the effect of the H₂/CO₂ molar ratio on the best NiCe-HMS. When reaction gas H₂/CO₂ molar ratio was 4 significantly decreased the selectivity to CO at low temperature, but triggered a higher CO₂ conversion which is close to the equilibrium.
- Greenhouse gases,
- Reverse water gas shift reaction,
- CO selectivity,
- CeO₂,
- Hexagonal mesoporous silica
1. [1]
  N. Charisiou, G. Siakavelas, L. Tzounis, et al., Int. J. Hydrogen Energy 43 (2018) 18955-18976 doi: 10.1016/j.ijhydene.2018.08.074
2. [2]
  Y.H. Wu, Q. Chen, S. Liu, et al., Chin. Chem. Lett. 30 (2019) 2186-2190 doi: 10.1016/j.cclet.2019.08.014
3. [3]
  G. Zhou, B. Dai, H. Xie, et al., J. CO₂ Utilization 21 (2017) 292-301 doi: 10.1016/j.jcou.2017.07.004
4. [4]
  H. Yang, C. Zhang, P. Gao, et al., Catal. Sci. Technol. 7 (2017) 4580-4598 doi: 10.1039/C7CY01403A
5. [5]
  Y. Wang, H. Arandiyan, S.A. Bartlett, et al., Appl. Catal. B: Environ. 277 (2020) 119029 doi: 10.1016/j.apcatb.2020.119029
6. [6]
  Y.H. Dai, M. Xu, Q.J. Wang, et al., Appl. Catal. B: Environ. 277 (2020) 119271 doi: 10.1016/j.apcatb.2020.119271
7. [7]
  S.M. Lee, H. Eom, S.S. Kim, Environ. Technol. 40 (2019) 182–192. doi: 10.1080/09593330.2017.1384070
8. [8]
  F.C. Meunier, D. Tibiletti, A. Goguet, D. Reid, R. Burch, Appl. Catal. A: Gen. 289 (2005) 104-112 doi: 10.1016/j.apcata.2005.04.018
9. [9]
  M. Maestri, K. Reuter, Chem. Eng. Sci. 74 (2012) 296-299 doi: 10.1016/j.ces.2012.02.043
10. [10]
  A.A. Upadhye, I. Ro, X. Zeng, et al., Catal. Sci. Technol. 5 (2015) 2590-2601 doi: 10.1039/C4CY01183J
11. [11]
  X. Hu, X.S. Hu, Q.X. Guan, et al., Sustain. Energy Fuels 4 (2020) 2937-2949 doi: 10.1039/d0se00147c
12. [12]
  C.A. Galvan, J. Schumann, M. Behrens, et al., Appl. Catal. B: Environ. 195 (2016) 104-111 doi: 10.1016/j.apcatb.2016.05.007
13. [13]
  Q. Zhang, L. Pastor-Perez, W. Jin, et al., Appl. Catal. B: Environ. 244 (2019) 889-898 doi: 10.1016/j.apcatb.2018.12.023
14. [14]
  J.X. Chen, Q.W. Long, K. Xiao, et al., Sci. Bull. 66 (2021) 1063-1072 doi: 10.1109/tcpmt.2021.3084966
15. [15]
  B. Dong, J.Y. Xie, Z. Tong, et al., Chin. J. Catal. 41 (2020) 1782-1789 doi: 10.1016/S1872-2067(20)63621-X
16. [16]
  L.L. Zeng, L.J. Yang, J. Lu, et al., Chin. Chem. Lett. 29 (2018) 1875-1878 doi: 10.1016/j.cclet.2018.10.026
17. [17]
  X.D. Zhang, K. Liu, J.W. Fu, et al., Front. Phys. Beijing 16 (2021) 63500 doi: 10.1007/s11467-021-1079-4
18. [18]
  C.S. Chen, W.H. Cheng, S.S. Lin, Chem. Commun. (2001) 1770-1771
19. [19]
  A. Ranjbar, A. Irankhah, S.F. Aghamiri, Res. Chem. Int. 45 (2019) 5125-5141 doi: 10.1007/s11164-019-03905-1
20. [20]
  F.M. Sun, C.F. Yan, Z.D. Wang, C.Q. Guo, S.L. Huang, Int. J. Hydrogen Energy 40 (2015) 15985-15993 doi: 10.1016/j.ijhydene.2015.10.004
21. [21]
  L. Yang, L. Pastor-Perez, S. Gu, A. Sepulveda-Escribano, T.R. Reina, Appl. Catal. B: Environ. 232 (2018) 464-471 doi: 10.1016/j.apcatb.2018.03.091
22. [22]
  B.W. Lu, K. Kawamoto, RSC Adv. 2 (2012) 6800-6805 doi: 10.1039/c2ra20344h
23. [23]
  N.B. Gao, M.X. Cheng, C. Quan, Y.P. Zheng, Fuel 273 (2020) 117702 doi: 10.1016/j.fuel.2020.117702
24. [24]
  G.L. Zhou, F.Q. Xie, L.D. Deng, G.Z. Zhang, H.M. Xie, Int. J. Hydrogen Energy 45 (2020) 11380-11393 doi: 10.1016/j.ijhydene.2020.02.058
25. [25]
  B.C. Dai, G.L. Zhou, S.B. Ge, et al., Can. J. Chem. Eng. 95 (2017) 634-642 doi: 10.1002/cjce.22730
26. [26]
  L.H. Wang, H. Liu, Y. Liu, Y. Chen, S.Q. Yang, J. Rare Earth 31 (2013) 969-974 doi: 10.1016/S1002-0721(13)60014-9
27. [27]
  B.W. Lu, K. Kawamoto, Mater. Res. Bull. 53 (2014) 70-78 doi: 10.1016/j.materresbull.2014.01.043
28. [28]
  V. Parvulescu, C. Dascalescu, B.L. Su, Nanotechnol. Mesostruct. Mater. 146 (2003) 629-632
29. [29]
  R. Wojcieszak, S. Monteverdi, M. Mercy, et al., Appl. Catal. A: Gen. 268 (2004) 241-253 doi: 10.1016/j.apcata.2004.03.047
30. [30]
  T. Kang, Y. Park, J. Yi, J. Mol. Catal. A: Chem. 244 (2006) 151-159 doi: 10.1016/j.molcata.2005.09.003
31. [31]
  T.R. Pauly, Y. Liu, T.J. Pinnavaia, S.J.L. Billinge, T.P. Rieker, J. Am. Chem. Soc. 121 (1999) 8835-8842 doi: 10.1021/ja991400t
32. [32]
  P.T. Tanev, T.J. Pinnavaia, Chem. Mater. 8 (1996) 2068-2079 doi: 10.1021/cm950549a
33. [33]
  Y.Y. Liu, K. Murata, M. Inaba, N. Mimura, Appl. Catal. A: Gen. 309 (2006) 91-105 doi: 10.1016/j.apcata.2006.04.042
34. [34]
  S.S. Bhoware, S. Shylesh, K.R. Kamble, A.P. Singh, J. Mol. Catal. A: Chem. 255 (2006) 123-130 doi: 10.1016/j.molcata.2006.03.072
35. [35]
  E. Lira, C.M. Lopez, F. Oropeza, et al., J. Mol. Catal. A: Chem. 281 (2008) 146-153 doi: 10.1016/j.molcata.2007.11.014
36. [36]
  I.S. Ke, S.T. Liu, Appl. Catal. A: Gen. 317 (2007) 91-96 doi: 10.1016/j.apcata.2006.10.007
37. [37]
  M. Wang, Q. Zhang, T. Zhang, et al., Chem. Engin. J. 313 (2017) 1370-1381 doi: 10.1016/j.cej.2016.11.055
38. [38]
  G.W. Wang, H.L. Zhang, Q.Q. Zhu, et al., J. Catal. 351 (2017) 90-94 doi: 10.1016/j.jcat.2017.04.018
39. [39]
  M. Thommes, K. Kaneko, A.V. Neimark, et al., Pure Appl. Chem. 87 (2015) 1051-1069 doi: 10.1515/pac-2014-1117
40. [40]
  D.Y. Zhao, J.L. Feng, Q.S. Huo, et al., Science 279 (1998) 548-552 doi: 10.1126/science.279.5350.548
41. [41]
  J.X. Chen, J.J. Zhou, R.J. Wang, J.Y. Zhang, Ind. Eng. Chem. Res. 48 (2009) 3802-3811 doi: 10.1021/ie801792h
42. [42]
  J.E. Spanier, R.D. Robinson, F. Zheng, S.W. Chan, I.P. Herman, Phys. Rev. B64 (2001) 245407 doi: 10.1103/PhysRevB.64.245407
43. [43]
  M. Peymani, S.M. Alavi, M. Rezaei, Int. J. Hydrogen Energy 41 (2016) 6316-6325 doi: 10.1016/j.ijhydene.2016.03.033
44. [44]
  C. Alvarez-Galvan, J.L. Martinez, M. Capel-Sanchez, L. Pascual, J.A. Alonso, Adv. Sustain. Syst. (2021) 2100029 doi: 10.1002/adsu.202100029
45. [45]
  Z.Y. Zakaria, J. Linnekoski, N.A.S. Amin, Chem. Engin. J. 207 (2012) 803-813
46. [46]
  X. Chen, X. Su, B. Liang, et al., J. Energy Chem. 25 (2016) 1051-1057 doi: 10.1016/j.jechem.2016.11.011
47. [47]
  G. Zhou, H. Liu, K. Cui, et al., Int. J. Hydrogen Energy 42 (2017) 16108-16117 doi: 10.1016/j.ijhydene.2017.05.154
48. [48]
  Y. Liu, Z. Li, H. Xu, Y. Han, Catal. Commun. 76 (2016) 1-6 doi: 10.1016/j.catcom.2015.12.011
49. [49]
  C. Italiano, J. Llorca, L. Pino, et al., Appl. Catal. B: Environ. 264 (2020) 118494 doi: 10.1016/j.apcatb.2019.118494
50. [50]
  Y.C. Huang, H.B. Li, M.S. Balogun, et al., ACS Appl. Mater. Int. 6 (2014) 22920-22927 doi: 10.1021/am507641k
51. [51]
  A. Ranjbar, A. Irankhah, S.F. Aghamiri, J. f Environ. Chem. Engin. 6 (2018) 4945-4952 doi: 10.1016/j.jece.2018.07.032
52. [52]
  S. Choi, B.I. Sang, J. Hong, et al., Sci. Reports 7 (2017) 41207
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4. [4]
  Yanzhe WANG , Xiaoming GUO , Qiangsheng GUO , Liang LI , Bin LU , Peihang YE . Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO₂ methanation. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2218-2228. doi: 10.11862/CJIC.20250202
5. [5]
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