Citation: Yuan Su, Mengchu Lu, Ruidian Su, Weizhi Zhou, Xing Xu, Qian Li. A 3D MIL-101@rGO composite as catalyst for efficient conversion of straw cellulose into valuable organic acid[J]. Chinese Chemical Letters, ;2022, 33(5): 2573-2578. doi: 10.1016/j.cclet.2021.08.078 shu

A 3D MIL-101@rGO composite as catalyst for efficient conversion of straw cellulose into valuable organic acid

Yuan Su ^{a, 1} ,
Mengchu Lu ^{b, 1} ,
Ruidian Su ^b ,
Weizhi Zhou ^c ,
Xing Xu ^{b, *} ,
Qian Li ^{b, *}

a.
School of Mathematic and Quantitative Economics, Shandong University of Finance and Economics, Ji'nan 250014, China
b.
Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao 266200, China
c.
School of Civil Engineering, Shandong University, Ji'nan 250100, China

xuxing@sdu.edu.cn

qianli@sdu.edu.cn

Received Date: 17 June 2021
Revised Date: 23 July 2021
Accepted Date: 18 August 2021
Available Online: 21 August 2021

Figures(4)

Efficient conversion of straw cellulose to chemicals or fuels is an attracting topic today for the utilization of biomass to substitute for fossil resources. The development of catalysts is of vital importance. In this work, a composite catalyst metal-organic frameworks (MOFs) immobilized on three-dimensional reduced graphene oxide (3D-rGO) were synthesized by in situ growth of the MIL-101(Cr) within the 3D-rGO matrix. The supporting of 3D-rGO guaranteed the dispersion and acid site density of MIL-101(Cr). The MIL-101(Cr)@3D-rGO nanocomposite possesses excellent catalytic activity, stability, recyclability and is an idea catalyst for the efficient degradation of straw cellulose into formic acid (FA), acetic acid (AA) and oxalic acid (OA). A maximum FA conversion rates of 95.36% was obtained by using MIL-101(Cr)@3D-rGO(1:1) as catalyst and hydrothermal reaction at mild conditions of 200 ℃ for 1h in alkaline aqueous medium. The MIL-101(Cr)@3D-rGO nanocomposite can be reused with high catalytic activity without any collapse of structure or leaching of chromium.
- Straw cellulose,
- MIL-101(Cr),
- Three-dimensional graphene,
- Catalystic conversion,
- Organic acid
1. [1]
  L. Zhang, Y. Tian, Y. Wang, et al., Chin. Chem. Lett. 32(2021) 2233-2238. doi: 10.1016/j.cclet.2020.12.030
2. [2]
  Z. Tang, J.H. Su, Carbohyd. Res. 481(2019) 52-59. doi: 10.1016/j.carres.2019.06.010
3. [3]
  T. Luo, H. Huang, Z. Mei, et al., Chin. Chem. Lett. 30(2019) 1219-1223. doi: 10.1016/j.cclet.2019.03.018
4. [4]
  C. Yuan, X. Wang, X. Yang, et al., Chin. Chem. Lett. 32(2021) 2079-2085. doi: 10.1016/j.cclet.2020.11.027
5. [5]
  Q. Zhao, L. Wang, S. Zhao, Fuel 90(2011) 2289-2293. doi: 10.1016/j.fuel.2011.02.022
6. [6]
  G.Z. Wang, X.F. Tan, H. Lv, Ind. Eng. Chem. Res. 55(2016) 5263-5270. doi: 10.1021/acs.iecr.6b00518
7. [7]
  L. Yan, J.D. Xu, T.T. Duan, B. Zhao, Y. Fan, J. Taiwan Inst. Chem. E 99(2019) 201-206. doi: 10.1016/j.jtice.2019.03.022
8. [8]
  D. Fang, C.N. Jiang, J. Chem. Sci. 125(2013) 751-754. doi: 10.1007/s12039-013-0460-4
9. [9]
  Y.P. Xia, C.X. Wang, M.H. Yu, X.H. Bu, Chin. Chem. Lett. 32(2021) 1153-1156. doi: 10.1016/j.cclet.2020.09.014
10. [10]
  M. Zhu, Y. Liu, M. Chen, et al., Chin. Chem. Lett. 31(2020) 2683-2688. doi: 10.1016/j.cclet.2020.04.011
11. [11]
  M. Rimsha, I. Naseem, N. Tayyaba, Electrochim. Acta 255(2017) 195-204. doi: 10.1016/j.electacta.2017.09.164
12. [12]
  Y. Li, M.Z. Wu, D.M. Chen, Mol. Catal. 477(2019) 110542-110550. doi: 10.1016/j.mcat.2019.110542
13. [13]
  J. Han, Y. Wang, J. Wan, Y. Ma, Environ. Sci. Pollut. Res. 26(2019) 15345-15353. doi: 10.1007/s11356-019-04923-7
14. [14]
  J. Chen, R. Liu, Y. Guo, ACS Cataly. 5(2015) 722-733. doi: 10.1021/cs5012926
15. [15]
  H.K. Li, H.L. Ye, X.X. Zhao, et al., Chin. Chem. Lett. 32(2021) 2851-2855. doi: 10.1016/j.cclet.2021.02.042
16. [16]
  Y. Shang, Xi. Duan, S. Wang, Q. Yue, B. Gao, X. Xu, Chin. Chem. Lett. 33(2022) 663-673. doi: 10.1016/j.cclet.2021.07.050
17. [17]
  P. Huang, L. Yan, Chinese J. Chem. Phys. 29(2016) 742-748. doi: 10.1063/1674-0068/29/cjcp1604073
18. [18]
  M. Jahan, Z. Liu, K.P. Loh, Adv. Funct. Mater. 23(2013) 5363-5372. doi: 10.1002/adfm.201300510
19. [19]
  Y. Chen, B. Yin, Z. Yu, N. Liang, Diam. Relat. Mater. 97(2019) 107508-107515. doi: 10.1016/j.diamond.2019.107508
20. [20]
  Y. Zheng, F.C. Chu, B. Zhang, J. Yan, Y.L. Chen, Micropor. Mesopor. Mat. 263(2018) 71-76. doi: 10.1016/j.micromeso.2017.12.007
21. [21]
  R. Bulánek, P. Čičmanec, J. Kotera, I. Boldog, Catal Today 324(2019) 106-114. doi: 10.1016/j.cattod.2018.07.034
22. [22]
  Y. Li, S.F. Li, Int. J. Hydrogen Energ. 4(2019) 10433-10441. doi: 10.1016/j.ijhydene.2018.10.224
23. [23]
  L. Yan, J.D. Xu, T.T. Duan, B. Zhao, Y. Fan, J. Taiwan Inst. Chem. 99(2019) 201-206. doi: 10.1016/j.jtice.2019.03.022
24. [24]
  Y. Kojima, M. Takayasu, M. Toma, S. Koda, Ultrason. Sonochem. 51(2019) 419-423. doi: 10.1016/j.ultsonch.2018.07.030
25. [25]
  L. Nirumand, S. Farhadi, A. Zabardasti, A. Khataee, Ultrason. Sonochem. 42(2018) 647-658. doi: 10.1016/j.ultsonch.2017.12.033
26. [26]
  A. Sharma M. Thakur, V. Ahlawat, Mater. Sci. Energy Technol. 3(2020) 328-334. doi: 10.1016/j.mset.2019.12.005
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2. [2]
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