Citation: Lingling Yao, Defeng Zhu, Lei Wang, Jie Liu, Yicheng Zhang, Pinhua Li. Visible-light-induced chemoselective reactions of quinoxalin-2(1H)-ones with alkylboronic acids under air/N₂ atmosphere[J]. Chinese Chemical Letters, ;2021, 32(12): 4033-4037. doi: 10.1016/j.cclet.2021.06.005 shu

Visible-light-induced chemoselective reactions of quinoxalin-2(1H)-ones with alkylboronic acids under air/N₂ atmosphere

Lingling Yao ^a ,
Defeng Zhu ^a ,
Lei Wang ^{a, b, *,} ,
Jie Liu ^{a, *,} ,
Yicheng Zhang ^a ,
Pinhua Li ^{a, c, *,}

a.
Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Department of Chemistry, Huaibei Normal University, Huaibei 235000, China
b.
Advanced Research Institute and Department of Chemistry, Taizhou University, Taizhou 318000, China
c.
Anhui Laboratory of Clean Catalytic Engineering, Anhui Laboratory of Functional Complexes for Materials Chemistry and Application, College of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu 241000, China

leiwang@chnu.edu.cn

jieliu_1024@163.com

pphuali@126.com

Received Date: 28 March 2021
Revised Date: 2 June 2021
Accepted Date: 3 June 2021
Available Online: 11 June 2021

Figures(8)

A visible-light-induced chemoselective reactions of quinoxalin-2(1H)-ones with alkylboronic acids in the presence of air (O₂) and N₂ atmosphere was developed under transition-metal free conditions, providing 3-alkylquinoxalin-2(1H)-ones and 3, 4-dihydroquinoxalin-2(1H)-ones, respectively. The overall strategy accommodates a broad scope of substituted quinoxalin-2(1H)-ones and alkylboronic acids with good to excellent product yields.
- Quinoxalin-2(1H)-ones,
- Alkylboronic acids,
- Visible-light-induced transformation,
- Transition-metal-free conditions
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沈阳化工大学材料科学与工程学院沈阳 110142

Visible-light-induced chemoselective reactions of quinoxalin-2(1H)-ones with alkylboronic acids under air/N2 atmosphere

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通讯作者: 陈斌, bchen63@163.com

Visible-light-induced chemoselective reactions of quinoxalin-2(1H)-ones with alkylboronic acids under air/N₂ atmosphere