Citation: Hui Yu, Xiang Wu, Qiaoqiao Mu, Zhihe Wei, Yindong Gu, Xuzhou Yuan, Yongtao Lu, Zhao Deng, Yang Peng. Robust photocatalytic hydrogen production on metal-organic layers of Al-TCPP with ultrahigh turnover numbers[J]. Chinese Chemical Letters, ;2021, 32(12): 3833-3836. doi: 10.1016/j.cclet.2021.05.035 shu

Robust photocatalytic hydrogen production on metal-organic layers of Al-TCPP with ultrahigh turnover numbers

Hui Yu ^{a, b} ,
Xiang Wu ^{a, b} ,
Qiaoqiao Mu ^{a, b} ,
Zhihe Wei ^{a, b} ,
Yindong Gu ^{a, b} ,
Xuzhou Yuan ^{a, b} ,
Yongtao Lu ^{a, b, *,} ,
Zhao Deng ^{a, b} ,
Yang Peng ^{a, b, *,}

a.
Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou 215006, China
b.
Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, China

sudalyt@suda.edu.cn

ypeng@suda.edu.cn

Received Date: 27 April 2021
Revised Date: 11 May 2021
Accepted Date: 18 May 2021
Available Online: 25 May 2021

Figures(4)

The development of robust photocatalytic systems is key to harvest the solar power for hydrogen production. In the current study, a series of aluminum-based porphyrinic metal organic frameworks (Al-TCPP) with various morphologies of bulk, carambola-like and nanosheets are synthesized with modulated layer thickness. Morphology-dependent photocatalytic activities in hydrogen production are witnessed and inversely correlate to the thickness of the Al-TCPP micro-platelets or nanosheets. Particularly, the exfoliated metal organic layers (MOLs) of Al-TCPP demonstrated a high hydrogen yield rate of 1.32 × 10⁴ µmol h⁻¹ g⁻¹ that is 21-fold of that from the bulk catalyst, as well as an exceptional TON of 6704 that seldom seen in literature. Through comprehensive photochemical characterizations, the remarkable photocatalytic performance of Al-TCPP-MOL is attributed to the great charge separation efficiency and transfer kinetics endowed by the ultrathin 2D morphology with extended active surface area.
- Photocatalysis,
- Metal organic layers,
- Al-TCPP,
- Hydrogen production,
- Turnover numbers
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