Citation: Guchuan Ping, Ling Miao, Abuduheiremu Awati, Xiaoyu Qian, Ting Shi, Yaokang Lv, Yafei Liu, Lihua Gan, Mingxian Liu, Dazhang Zhu. Porous carbon globules with moss-like surfaces from semi-biomass interpenetrating polymer network for efficient charge storage[J]. Chinese Chemical Letters, ;2021, 32(12): 3811-3816. doi: 10.1016/j.cclet.2021.04.055 shu

Porous carbon globules with moss-like surfaces from semi-biomass interpenetrating polymer network for efficient charge storage

Guchuan Ping ^a ,
Ling Miao ^{a, *,} ,
Abuduheiremu Awati ^a ,
Xiaoyu Qian ^a ,
Ting Shi ^a ,
Yaokang Lv ^b ,
Yafei Liu ^a ,
Lihua Gan ^a ,
Mingxian Liu ^{a, c} ,
Dazhang Zhu ^{a, *,}

a.
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
b.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
c.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

1310593@tongji.edu.cn

zhudz@tongji.edu.cn

Received Date: 8 March 2021
Revised Date: 15 April 2021
Accepted Date: 27 April 2021
Available Online: 8 May 2021

Figures(5)

The bio-nanotechnological fabrication of high-surface-area carbons has attracted widespread interest in supercapacitor applications by using readily-available natural products as raw materials or bio-templates, and is expected to refine on pore accessibility for compact energy storage. Here, a renovated design strategy of semi-biomass interpenetrating polymer network (IPN) derived carbon is demonstrated through physically knitting the biomacromolecule (sodium alginate, SA) polymeric chains into the highly crosslinked resorcinol-formaldehyde (RF) network and subsequent thermochemical conversion. Molecule-level interlacing forces in such IPN efficiently relieve the RF skeleton shrinkage when producing carbon, while the other SA network addresses the macrophase separation issue to sacrifice as an in-knitted porogen and a morphology-directing agent. As a result, porous carbon globules are equipped with moss-like surfaces and interconnected pore architecture for high accessible electrode surface (1013 m²/g), and efficient electrochemical responses are reached with the specific capacitance of 312 F/g at 1 A/g. Taking the advantage of 9 mol/kg NaClO₄ complex-solvent electrolyte, the voltage window is extended to 2.4 V, endowing the two-electrode device with the high energy delivery of 32.3 Wh/kg at 240 W/kg.
- Porous carbon electrode,
- Interpenetrating polymer network,
- Biomass,
- Supercapacitor,
- Water-in-salt electrolyte
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