Citation: Xuerong Li, Haoyan Cheng, Hao Hu, Kunming Pan, Tongtong Yuan, Wanting Xia. Recent advances of vanadium-based cathode materials for zinc-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(12): 3753-3761. doi: 10.1016/j.cclet.2021.04.045 shu

Recent advances of vanadium-based cathode materials for zinc-ion batteries

Xuerong Li ^{a, b, 1} ,
Haoyan Cheng ^{a, 1} ,
Hao Hu ^{a, *,} ,
Kunming Pan ^{a, b, *,} ,
Tongtong Yuan ^a ,
Wanting Xia ^a

a.
School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China
b.
Henan Key Laboratory of High-temperature Structural and Functional Materials, National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials, Henan University of Science and Technology, Luoyang 471003, China

huhao@haust.edu.cn

pankunming2008@haust.edu.cn

Received Date: 16 March 2021
Revised Date: 16 April 2021
Accepted Date: 21 April 2021
Available Online: 28 April 2021

Figures(7)

Zn-ion batteries (ZIBs) have gained great attention as promising next-generation power sources, because of their low cost, enviable safety and high theoretical capacity. Recently, massive researches have been devoted to vanadium-based materials as cathodes in ZIBs, owing to their multiple valence states, competitive gravimetric energy density, but the capacity degradation, sluggish kinetics, low operating voltage hinder further optimization of their performance in ZIBs. This review summarizes recent progress to increase the interlayer spacing, structural stability, and the diffusion ability of the guest Zn ions, including the insertion of different ions, introduction of defects, design of diverse morphologies, the combination of other materials. We also focus on approaches to promoting the valuable performance of vanadium-based cathodes, along with the related ongoing scientific challenges and limitations. Finally, the future perspectives and research directions of vanadium-based aqueous ZIBs are provided.
- Aqueous zinc-ion batteries,
- Vanadium-based materials,
- Cathodes,
- Energy storage,
- Design strategy
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沈阳化工大学材料科学与工程学院沈阳 110142