Citation: Zhishu Zeng, Yunqian Zhang, Xiaodong Zhang, Guangyan Luo, Jun Xie, Zhu Tao, Qianjun Zhang. Selective detection of Zn²⁺ and Cd²⁺ ions in water using a host-guest complex between chromone and Q[7][J]. Chinese Chemical Letters, ;2021, 32(8): 2572-2576. doi: 10.1016/j.cclet.2021.03.071 shu

Selective detection of Zn²⁺ and Cd²⁺ ions in water using a host-guest complex between chromone and Q[7]

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

qjzhang@gzu.edu.cn

Received Date: 29 December 2020
Revised Date: 24 March 2021
Accepted Date: 25 March 2021
Available Online: 27 March 2021

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In this paper, the host-guest interaction of cucurbit[7]uril (Q[7]) and chromone (CMO) has been developed as a fluorescent probe for the highly selective detection of Zn²⁺ and Cd²⁺ in water based on a chelation-enhanced fluorescence (CHEF) mechanism. There was a good linear relationship between the fluorescence intensity of the CMO@Q[7] probe and the concentration of Zn²⁺ or Cd²⁺ in the range of 0–3.0 × 10^–5 mol/L and the detection limit for Zn²⁺ and Cd²⁺ was found to be 2.03 × 10^–6 mol/L and 1.89 × 10^–6 mol/L, respectively. The X-ray crystal structure indicated that different coordination fashions were triggered by Zn²⁺ and Cd²⁺ in the CMO@Q[7] complexes, respectively. However, both metal ions coordinated with the carbonyl oxygen of CMO, which was encapsulated in the cavity of Q[7], thus leading to the enhancement of recognition fluorescence emission of CMO.
- Chromone,
- Cucurbit[7]uril,
- Host-guest interaction,
- Selective detection,
- Zn²⁺ and Cd²⁺
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沈阳化工大学材料科学与工程学院沈阳 110142

Selective detection of Zn2+ and Cd2+ ions in water using a host-guest complex between chromone and Q[7]

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通讯作者: 陈斌, bchen63@163.com

Selective detection of Zn²⁺ and Cd²⁺ ions in water using a host-guest complex between chromone and Q[7]