Citation: Shan-Shan Jia, Wen-Shi Xu, Yong Chen, Yu Liu. Pyrrole/macrocycle/MOF supramolecular co-assembly for flexible solid state supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(9): 2773-2776. doi: 10.1016/j.cclet.2021.03.002 shu

Pyrrole/macrocycle/MOF supramolecular co-assembly for flexible solid state supercapacitors

College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

chenyong@nankai.edu.cn

yuliu@nankai.edu.cn

Received Date: 6 January 2021
Revised Date: 24 February 2021
Accepted Date: 1 March 2021
Available Online: 3 March 2021

Figures(7)

Supramolecular assemblies constructed through the encapsulation of conductive polymers (CPs) by macrocyclic molecules have attracted increasing interest in the fields of supramolecular chemistry and electrochemistry. In this work, an effective strategy was reported to improve the stability and conductivity of CPs by electrochemically constructing different supramolecular assemblies composed of macrocycles and CPs. Typically, we uploaded zinc-based MOF (ZIF-8) onto carbon nanotube film (CNTF) and further electrically deposited macrocycles and CPs to gain the flexible conductive electrodes. Herein, five different supramolecular macrocycles, including α-cyclodextrin (α-CD), sulfato-β-cyclodextrin (SCD), sulfonatocalix[4]arene (SC[4]), cucurbit[6]uril (CB[6]) and cucurbit[7]uril (CB[7]) were utilized and the electrochemical performances of the assembly electrodes increased in an order of α-CD < SCD < SC[4] < CB[6] < CB[7], significantly improving the areal capacitance up to 1533 mF/cm². This strategy may provide a new way for the application of macrocyclic supramolecules in electrochemical systems.
- Supramolecular assemblies,
- Macrocycle,
- Conductive polymers,
- Electrochemical performance,
- Cationic radical
1. [1]
  L. Chen, Y. Chen, H.G. Fu, et al., Adv. Sci. 7(2020) 2000803. doi: 10.1002/advs.202000803
2. [2]
  R.J. Dong, Y.F. Zhou, X.H. Huang, et al., Adv. Mater. 27(2015) 498-526. doi: 10.1002/adma.201402975
3. [3]
  T.X. Xiao, L. Zhou, X.Q. Sun, et al., Chin. Chem. Lett. 31(2020) 1-9. doi: 10.1016/j.cclet.2019.05.011
4. [4]
  J. Shi, Y. Chen, C.F. Ke, et al., Angew. Chem. Int. Ed. 47(2008) 7293-7296. doi: 10.1002/anie.200802805
5. [5]
  N. Song, Z.J. Zhang, P.Y. Liu, et al., Adv. Mater. 32(2020) 2004208. doi: 10.1002/adma.202004208
6. [6]
  P.Y. Li, Y. Chen, Y. Liu, Chin. Chem. Lett. 30(2019) 1190-1197. doi: 10.1016/j.cclet.2019.03.035
7. [7]
  D.H. Qu, Q.C. Wang, Q.W. Zhang, et al., Chem. Rev. 115(2015) 7543-7588. doi: 10.1021/cr5006342
8. [8]
  L. Feng, S.S. Jia, Y. Chen, et al., Chem. Eur. J. 26(2020) 14080-14084. doi: 10.1002/chem.202001729
9. [9]
  L. Shao, J.F. Sun, B. Hua, et al., Chem. Commun. 54(2018) 4866-4869. doi: 10.1039/C8CC02077A
10. [10]
  O. Ikkala, G.T. Brinke, Science 295(2003) 2407-2409.
11. [11]
  Q. Zhang, D.H. Qu, Q.C. Wang, et al., Angew. Chem. Int. Ed. 54(2015) 15789-15793. doi: 10.1002/anie.201509071
12. [12]
  P. Cordier, F. Tournilhac, C. Soulié-Ziakovic, Nature 451(2013) 977-980.
13. [13]
  J. Ye, R.M. Zhang, W.J. Yang, et al., Chin. Chem. Lett. 31(2020) 1550-1553. doi: 10.1016/j.cclet.2019.11.041
14. [14]
  P.L. Anelli, M. Asakawa, P.R. Ashton, et al., Chem. Eur. J. 3(1997) 1113-1135. doi: 10.1002/chem.19970030719
15. [15]
  Y.Y. Jin, Y.Q. Wang, J. Yang, et al., Cell Rep. Phys. Sci. 1(2020) 100173. doi: 10.1016/j.xcrp.2020.100173
16. [16]
  G.P. Sun, Z.M. He, M. Hao, et al., Chem. Commun. 55(2019) 10892-10895. doi: 10.1039/C9CC05859A
17. [17]
  L.L. Tan, M.Y. Wei, L. Shang, et al., Adv. Funct. Mater. (2020) 2007277.
18. [18]
  P.R. Joan, S.G. Rafael, I. Stead, et al., Macromolecules 52(2019) 1458-1468. doi: 10.1021/acs.macromol.8b02509
19. [19]
  S.D.P. Fielden, D.A. Leigh, C.T. McTernan, et al., J. Am. Chem. Soc. 140(2018) 6049-6052. doi: 10.1021/jacs.8b03394
20. [20]
  C.C. Zhang, X.L. Liu, Y.P. Liu, et al., Chem. Mater. 32(2020) 8724-8732. doi: 10.1021/acs.chemmater.0c03425
21. [21]
  S. Angelos, Y.W. Yang, K. Patel, et al., Angew. Chem. 120(2008) 2254-2258. doi: 10.1002/ange.200705211
22. [22]
  Y.L. Sun, B.J. Yang, X.A. Sean, et al., Chem. Eur. J. 18(2012) 9212-9216. doi: 10.1002/chem.201201083
23. [23]
  O. Reany, A. Li, M. Yefet, et al., J. Am. Chem. Soc. 139(2017) 8138-8145. doi: 10.1021/jacs.6b13005
24. [24]
  W.H. Wang, Q. Gao, A.L. Li, et al., Chin. Chem. Lett. 29(2018) 336-338. doi: 10.1016/j.cclet.2017.08.033
25. [25]
  W.J. Gong, J. Ma, Z.Y. Zhao, et al., J. Org. Chem. 82(2017) 3298-3301. doi: 10.1021/acs.joc.6b02971
26. [26]
  S.K. Kim, K.M. Park, K. Singha, et al., Chem. Commun. 46(2010) 692-694. doi: 10.1039/B920753H
27. [27]
  S.W. Choi, J.W. Lee, Y.H. Ko, et al., Macromolecules 35(2002) 3526-3531. doi: 10.1021/ma011759d
28. [28]
  D. Tuncel, J.H.G. Steinke, Chem. Commun. (1999) 1509-1510. doi: 10.1039/A902990G
29. [29]
  D. Tuncel, J.H.G. Steinke, Chem. Commun. (2001) 253-254.
30. [30]
  Y.H. Ling, A.E. Kaifer, Chem. Mater. 18(2006) 5944-5949. doi: 10.1021/cm061629p
31. [31]
  Y.C. Zhang, L. Chen, H. Wang, et al., Chin. Chem. Lett. 27(2016) 817-821. doi: 10.1016/j.cclet.2016.03.041
32. [32]
  C. Yang, J. Xu, D.D. Yang, et al., Chin. Chem. Lett. 29(2018) 1421-1424. doi: 10.1016/j.cclet.2018.02.014
33. [33]
  Z.S. Lv, Y.X. Tang, Z.Q. Zhu, et al., Adv. Mater. 30(2018) 1805468. doi: 10.1002/adma.201805468
1. [1]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
2. [2]
  Yu-Jie Long , Xiao-Ni Han , Ying Han , Chuan-Feng Chen . Recent advances in supramolecular luminescent materials based on macrocyclic arenes. Chinese Chemical Letters, 2025, 36(6): 110600-. doi: 10.1016/j.cclet.2024.110600
3. [3]
  Shuo Li , Qianfa Liu , Lijun Mao , Xin Zhang , Chunju Li , Da Ma . Benzothiadiazole-based water-soluble macrocycle: Synthesis, aggregation-induced emission and selective detection of spermine. Chinese Chemical Letters, 2024, 35(11): 109791-. doi: 10.1016/j.cclet.2024.109791
4. [4]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
5. [5]
  Hongyu Tang , Dongming Liu , Jinfu Huang , Liang Zhang , Yang Tang , Bin Huang , Yanwei Li , Shunhua Xiao , Yiling Sun , Renheng Wang . Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping. Chinese Chemical Letters, 2025, 36(6): 109987-. doi: 10.1016/j.cclet.2024.109987
6. [6]
  Le Li , Shaofeng Jia , Shi Yue , Yuanyuan Yang , Chao Tan , Conghui Wang , Hengwei Qiu , Yongqiang Ji , Minghui Cao , Zige Tai , Dan Zhang . Vanadium doping inhibit the Jahn−Teller effect of Mn³⁺ for high-performance aqueous zinc ion battery. Chinese Chemical Letters, 2025, 36(10): 111009-. doi: 10.1016/j.cclet.2025.111009
7. [7]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
8. [8]
  Jing Liu , Fei Wang , Huijie Wei , Yong Liu , Xiaoliang Zhai , Sifan Wen , Qiaobao Zhang . Fabrication and application of binder-free cathodes in high-performance lithium-chalcogen (S, Se, Te) batteries: A review. Chinese Chemical Letters, 2025, 36(11): 110475-. doi: 10.1016/j.cclet.2024.110475
9. [9]
  Qihan Lin , Jiabin Xing , Yue-Yang Liu , Gang Wu , Shi-Jia Liu , Hui Wang , Wei Zhou , Zhan-Ting Li , Dan-Wei Zhang . taBOX: A water-soluble tetraanionic rectangular molecular container for conjugated molecules and taste masking for berberine and palmatine. Chinese Chemical Letters, 2024, 35(5): 109119-. doi: 10.1016/j.cclet.2023.109119
10. [10]
  Baoqi Wu , Rongzhi Tang , Zhi-Wei Li , Feng Lin , Zongyu Sun , Huanyu Xia , Lin Jiang , Yu Tan . Selective encapsulation of azo compounds by tetracationic cyclophane in water and photo-controlled reversible release. Chinese Chemical Letters, 2025, 36(9): 110896-. doi: 10.1016/j.cclet.2025.110896
11. [11]
  Xin Zhang , Zhihao Lu , Tianci Ren , Junxiang Tang , Shuo Li , Chenghao Zhu , Lijun Mao , Da Ma . Fluorescent "Texas-sized" macrocyclic receptors for the recognition and detection of nucleotides in water. Chinese Chemical Letters, 2025, 36(11): 110946-. doi: 10.1016/j.cclet.2025.110946
12. [12]
  Qiao Wang , Ziling Jiang , Chuang Yu , Liping Li , Guangshe Li . Research progress of inorganic sodium ion conductors for solid-state batteries. Chinese Chemical Letters, 2025, 36(6): 110006-. doi: 10.1016/j.cclet.2024.110006
13. [13]
  Ziling Jiang , Chen Liu , Jie Yang , Xia Li , Chaochao Wei , Qiyue Luo , Zhongkai Wu , Lin Li , Liping Li , Shijie Cheng , Chuang Yu . Designing F-doped Li₃InCl₆ electrolyte with enhanced stability for all-solid-state lithium batteries in a wide voltage window. Chinese Chemical Letters, 2025, 36(6): 109741-. doi: 10.1016/j.cclet.2024.109741
14. [14]
  Pan-Pan Hua , Hui-Jun Feng , Shu-Ning Lan , Francisco Aznarez , Li-Fang Zhang . Post-modification-induced supramolecular transformation of Hopf link to macrocycle. Chinese Chemical Letters, 2025, 36(6): 110684-. doi: 10.1016/j.cclet.2024.110684
15. [15]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
16. [16]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
17. [17]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
18. [18]
  Huili Zhao , Xiao Tan , Huining Chai , Lin Hu , Hongbo Li , Lijun Qu , Xueji Zhang , Guangyao Zhang . Recent advances in conductive MOF-based electrochemical sensors. Chinese Chemical Letters, 2025, 36(8): 110571-. doi: 10.1016/j.cclet.2024.110571
19. [19]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
20. [20]
  Ying Chen , Lun Li , Guohao Han , Ren Liu , Guanghui An , Yi Zhu . Macromolecular coumarin sulfonium salt with side chain effect constructed by copolymerization strategy for free radical, cationic, and hybrid photopolymerizations. Chinese Chemical Letters, 2025, 36(7): 110458-. doi: 10.1016/j.cclet.2024.110458

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1351)
HTML views(150)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142