Citation: Zhen Fang, Yuting Liang, Xiaomei Wang, Shuhan Zhang, Jun Yu, Hu Xu, Yuhong Wang. A novel phosphorus oxide quantum dots as an emissive nanomaterial for inorganic ions screening and bioimaging[J]. Chinese Chemical Letters, ;2021, 32(9): 2856-2860. doi: 10.1016/j.cclet.2021.02.024 shu

A novel phosphorus oxide quantum dots as an emissive nanomaterial for inorganic ions screening and bioimaging

Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

xuhu@sit.edu.cn

yuhong_wang502@sit.edu.cn

Received Date: 6 November 2020
Revised Date: 10 January 2021
Accepted Date: 9 February 2021
Available Online: 15 February 2021

Figures(4)

In this work, a novel blue-green fluorescence phosphorous oxide quantum dots (PO QDs) was synthesized by solvothermal method in N-methyl-2-pyrrolidone (NMP) solution without any protection treatment during synthesis. Upon excitation at 400 nm, PO QDs emitted blue-green fluorescence with quantum yield of 0.28. PO QDs exhibited the high inertness to air or moisture, the excellent water solubility, and stable emission intensity in a wide pH range and in high ionic strength solution. Interestingly, PO QDs could give the positive optical response to iron ions (Fe³⁺) and iodine ion (I⁻). The photoluminescence (PL) of PO QDs could be directly quenched by Fe³⁺. While I⁻ quenched the PO QDs PL by means of Ag⁺-mediated PO QDs system via the internal filtration effects (IFE) induced by the formation of AgI. Moreover, the biocompatibility and low toxicity of PO QDs verified in bean sprout and Hela cells indicated the promising application of PO QDs in medicine related fields. Furthermore, PO QDs could also be utilized in luminescent composite film for various application scenarios
- Phosphorus oxide quantum dots,
- Emissive material,
- Bioimaging,
- Ion screening,
- Iodine ion,
- Iron ion
1. [1]
  Z. Sun, H. Xie, S. Tang et al., Angew. Chem. Int. Ed. 54 (2015) 11526-11530 doi: 10.1002/anie.201506154
2. [2]
  H. Wang, X. Yang, W. Shao et al., J. Am. Chem. Soc. 137 (2015) 11376-11382 doi: 10.1021/jacs.5b06025
3. [3]
  D.P. Dubal, N.R. Chodankar, D.H. Kim, P.T. Gomez-Romero, Chem. Soc. Rev. 47 (2018) 2065-2129 doi: 10.1039/c7cs00505a
4. [4]
  A. Hirsch, F. Hauke, Angew Chem. Int. Ed. 57 (2018) 4338-4354 doi: 10.1002/anie.201708211
5. [5]
  J.H. Ryu, H.J. Kim, K. Kim et al., Adv. Funct. Mater. 29 (2019) 1900495 doi: 10.1002/adfm.201900495
6. [6]
  L. Houjing, S. Mingxia, S. Yingying et al., Chem. Commun. 54 (2018) 7987-7990 doi: 10.1039/C8CC04513E
7. [7]
  R.L. Kumawat, B. Pathak, Appl. Surf. Sci. 529 (2020) 147094 doi: 10.1016/j.apsusc.2020.147094
8. [8]
  H. Ren, Y. Zhou, Y. Wang et al., Sens. Actuators B: Chem. 321 (2020) 128520 doi: 10.1016/j.snb.2020.128520
9. [9]
  K. Rathi, K. Pal, ACS Appl. Mater. Interfaces. 12 (2020) 38365-38375 doi: 10.1021/acsami.0c10285
10. [10]
  Q. Yue, Y. Hu, L. Tao et al., Mikrochim. Acta 186 (2019) 640. doi: 10.1007/s00604-019-3768-z
11. [11]
  P. Guo, W.H. Song, S. Yan, Opt. Commun. 406 (2018) 91-94 doi: 10.1016/j.optcom.2017.05.081
12. [12]
  L. Ren, H. Li, J. Du, Microchim. Acta 187 (2020) 229-236 doi: 10.1007/s00604-020-4222-y
13. [13]
  I.E.V. Rosales, L. Rovigatti, E. Bianchi, C.N. Likos, E. Locatelli, Nanoscale 12 (2020) 21188-21197 doi: 10.1039/D0NR05058J
14. [14]
  Y.T. Yew, Z. Sofer, C.C. Mayorga-Martineza, M. Pumera, Mater. Chem. Front. 1 (2017) 1130-1136 doi: 10.1039/C6QM00341A
15. [15]
  J. Zhou, Z. Li, M. Ying, et al., Nanoscale 10 (2018) 5060-5064 doi: 10.1039/C7NR08900G
16. [16]
  Z. Hua, Y. Lia, E. Hussaina, et al., Talanta 197 (2019) 270-276 doi: 10.1016/j.talanta.2019.01.023
17. [17]
  J. Peng, Y. Lai, Y. Chen et al., Small 13 (2017) 1603589 doi: 10.1002/smll.201603589
18. [18]
  W. Gu, Y.H. Yan, X.Y. Pei et al., Sen. Actuators B: Chem. 250 (2017) 601-607 doi: 10.1016/j.snb.2017.05.017
19. [19]
  W. Gu, X. Pei, Y. Cheng et al., ACS Sens. 2 (2017) 576-582 doi: 10.1021/acssensors.7b00102
20. [20]
  Z.Y. Xu, L. Hu, J. Yuan et al., Adv. Mater. Interfaces. 7 (2020) 1902075 doi: 10.1002/admi.201902075
21. [21]
  J. Kang, J.D. Wood, S.A. Wells et al., ACS Nano 9 (2015) 3596-3604 doi: 10.1021/acsnano.5b01143
22. [22]
  Z.N. Guo, H. Zhang, S.B. Lu et al., Adv. Funct. Mater. 25 (2015) 6996-7002 doi: 10.1002/adfm.201502902
23. [23]
  J.H. Brannon, D. Magde, J. Phys. Chem. 82 (1978) 706-709
24. [24]
  Z. Shen, S. Sun, W. Wang et al., J. Mater. Chem. A 3 (2015) 3285-3288 doi: 10.1039/C4TA06871H
25. [25]
  A.G. Kannan, N.R. Choudhury, N.K. Dutta, Org. Lett. 48 (2007) 7078-7086
26. [26]
  J. Wang, R. Sheng, H. Li et al., Biosens. Bioelectron. 97 (2017) 157-163 doi: 10.3847/1538-4357/aa937f
27. [27]
  P. Wang, Y. Xia, P.P. Wu, et al., J. Phys. Chem. C 118 (2014) 8891-8898 doi: 10.1021/jp410413s
1. [1]
  Longhao Hu , Lingshan Gong , Wenlong Ye , Hao Chen , Xiao-Li Lai , Yingxiang Ye . Luminescent hydrogen-bonded organic frameworks: From design to applications. Chinese Journal of Structural Chemistry, 2025, 44(11): 100703-100703. doi: 10.1016/j.cjsc.2025.100703
2. [2]
  Yunlong Li , Xinyu Zhang , Shuang Liu , Chunsheng Li , Qiang Wang , Jin Ye , Yong Lu , Jiating Xu . Engineered iron-based metal-organic frameworks nanoplatforms for cancer theranostics: A mini review. Chinese Chemical Letters, 2025, 36(2): 110501-. doi: 10.1016/j.cclet.2024.110501
3. [3]
  Hui Guo , Wen-Wen Li , Mei-Yin Wu , Jian-Bo Hu , Jun Wang , Yun Liu , Yang Zou , Chu-Luo Yang , Kai-Lu Zheng . Indolizine-benzophenone hybrid acceptors enable TADF materials for bioimaging and photodynamic therapy in living cells. Chinese Chemical Letters, 2026, 37(1): 111721-. doi: 10.1016/j.cclet.2025.111721
4. [4]
  Chuanfeng Fan , Jian Gao , Yingkai Gao , Xintong Yang , Gaoning Li , Xiaochun Wang , Fei Li , Jin Zhou , Haifeng Yu , Yi Huang , Jin Chen , Yingying Shan , Li Chen . A non-peptide-based chymotrypsin-targeted long-wavelength emission fluorescent probe with large Stokes shift and its application in bioimaging. Chinese Chemical Letters, 2024, 35(10): 109838-. doi: 10.1016/j.cclet.2024.109838
5. [5]
  Bin Fang , Jiaqi Yang , Limin Wang , Haoqin Li , Jiaying Guo , Jiaxin Zhang , Qingyuan Guo , Bo Peng , Kedi Liu , Miaomiao Xi , Hua Bai , Li Fu , Lin Li . A mitochondria-targeted H₂S-activatable fluorogenic probe for tracking hepatic ischemia-reperfusion injury. Chinese Chemical Letters, 2024, 35(6): 108913-. doi: 10.1016/j.cclet.2023.108913
6. [6]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
7. [7]
  Lixian Fu , Yiyun Tan , Yue Ding , Weixia Qing , Yong Wang . Water–soluble and polarity–sensitive near–infrared fluorescent probe for long–time specific cancer cell membranes imaging and C. Elegans label. Chinese Chemical Letters, 2024, 35(4): 108886-. doi: 10.1016/j.cclet.2023.108886
8. [8]
  Haixian Ren , Yuting Du , Xiaojing Yang , Fangjun Huo , Le Zhang , Caixia Yin . Development of ESIPT-based specific fluorescent probes for bioactive species based on the protection-deprotection of the hydroxyl. Chinese Chemical Letters, 2025, 36(2): 109867-. doi: 10.1016/j.cclet.2024.109867
9. [9]
  Fan Zheng , Runsha Xiao , Shuai Huang , Zhikang Chen , Chen Lai , Anyao Bi , Heying Yao , Xueping Feng , Zihua Chen , Wenbin Zeng . Accurate visualization colorectal cancer by monitoring viscosity variations with a novel mitochondria-targeted fluorescent probe. Chinese Chemical Letters, 2025, 36(2): 109876-. doi: 10.1016/j.cclet.2024.109876
10. [10]
  Meiling Zhao , Yao Lu , Yutao Zhang , Haoyun Xue , Zhiqian Guo . Ultra-high signal-to-noise ratio near-infrared chemiluminescent probe for in vivo sensing singlet oxygen. Chinese Chemical Letters, 2025, 36(5): 110105-. doi: 10.1016/j.cclet.2024.110105
11. [11]
  Zhanheng Yan , Weiqing Su , Weiwei Xu , Qianhui Mao , Lisha Xue , Huanxin Li , Wuhua Liu , Xiu Li , Qiuhui Zhang . Carbon-based quantum dots/nanodots materials for potassium ion storage. Chinese Chemical Letters, 2025, 36(4): 110217-. doi: 10.1016/j.cclet.2024.110217
12. [12]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
13. [13]
  Xinyu Guo , Chang Li , Wenjun Deng , Yi Zhou , Yan Chen , Yushuang Xu , Rui Li . Phase engineering and heteroatom incorporation enable defect-rich MoS₂ for long life aqueous iron-ion batteries. Chinese Chemical Letters, 2025, 36(3): 109715-. doi: 10.1016/j.cclet.2024.109715
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
16. [16]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
17. [17]
  Fanjun Kong , Jing Zhang , Yuting Tang , Chencheng Sun , Chunfu Lin , Tao Zhang , Wangsheng Chu , Li Song , Liang Zhang , Shi Tao . Introducing high-valence element into P2-type layered cathode material for high-rate sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110993-. doi: 10.1016/j.cclet.2025.110993
18. [18]
  Lu Cheng , Jinghua Quan , Hongyan Li . Recent advances in antimony-based anode materials for potassium-ion batteries: Material selection, structural design and storage mechanisms. Chinese Chemical Letters, 2025, 36(9): 110685-. doi: 10.1016/j.cclet.2024.110685
19. [19]
  Wenya Li , Yuanqi Yang , Yuqing Yang , Min Liang , Huizi Li , Xi Ke , Liying Liu , Yan Sun , Chunsheng Li , Zhicong Shi , Su Ma . Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110388-. doi: 10.1016/j.cclet.2024.110388
20. [20]
  Long Huang , Jian Pu , Yunyu Zhao , Xiangxiang Fang , Yingjian Yu , Yuan Li , Jinyan Ma , Yuejin Zhu , Fang Hu , Chuang Yue . Phosphorus-doped carbon as an effective protective layer for advanced aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110989-. doi: 10.1016/j.cclet.2025.110989

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1465)
HTML views(101)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142