Citation: Ping Zhang, Wenju Chang, Hongyun Jiao, Yanshang Kang, Wenxuan Zhao, Peipei Cui, Yong Liang, Wei-Yin Sun, Yi Lu. Selective annulation of benzamides with internal alkynes catalyzed by an electron-deficient rhodium catalyst[J]. Chinese Chemical Letters, ;2021, 32(5): 1717-1720. doi: 10.1016/j.cclet.2021.01.024 shu

Selective annulation of benzamides with internal alkynes catalyzed by an electron-deficient rhodium catalyst

Ping Zhang ^a ,
Wenju Chang ^b ,
Hongyun Jiao ^b ,
Yanshang Kang ^a ,
Wenxuan Zhao ^b ,
Peipei Cui ^a ,
Yong Liang ^b ,
Wei-Yin Sun ^a ,
Yi Lu ^{a, *}

a.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
b.
State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

luyi@nju.edu.cn

Received Date: 27 October 2020
Revised Date: 10 January 2021
Accepted Date: 20 January 2021
Available Online: 20 January 2021

Figures(4)

An electron-deficient [Cp^ERhCl₂]₂ catalyzed annulation of N-pentafluorophenylbenzamides with internal alkynes was successfully established under mild reaction conditions, with the assistance of Lewis acid silver salt. Particularly, electron-deficient benzamide substrates were smoothly transformed into the desired products in this catalytic system. The catalytic system showed a broad tolerance for different substituents on the aromatic rings or aryl, alkyl-substituted alkynes.
- Electron-deficient rhodium,
- C–H activation,
- Annulation,
- Benzamide,
- Alkyne
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