Citation: Jinrong Huo, Ling Fu, Chenxu Zhao, Chaozheng He. Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure[J]. Chinese Chemical Letters, ;2021, 32(7): 2269-2273. doi: 10.1016/j.cclet.2020.12.059 shu

Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure

Jinrong Huo ^{a, c} ,
Ling Fu ^d ,
Chenxu Zhao ^{b, c} ,
Chaozheng He ^{b, c, *,}

a.
School of Sciences, Xi'an Technological University, Xi'an 710021, China
b.
Shaanxi Key Laboratory of Optoelectronic Functional Materials and Devices, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
c.
Institute of Environmental and Energy Catalysis, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
d.
College of Resources and Environmental Engineering, Tianshui Normal University, Tianshui 741001, China

hecz2019@xatu.edu.cn

Received Date: 11 December 2020
Revised Date: 28 December 2020
Accepted Date: 29 December 2020
Available Online: 5 January 2021

Figures(5)

In this paper, the process of ammonia borane (AB) hydrolysis generate H₂ on the transition metal Fe@Co core-shell structure has been obtained. According to the different roles played by H₂O molecules and the number of H₂O molecules involved, there are three schemes of reaction paths. Route Ⅰ does not involve the dissociation of H₂O molecules and all H atoms come from AB. Moreover, the H₂O molecule has no effect on the breaking of the BH bond or the NH bond. The reaction absorbs more heat during the formation of the second and third H₂ molecules. Route Ⅱ includes the dissociation of H₂O molecules and the cleavage of BH or NH bonds, respectively, and the reaction shows a slight exotherm. Route Ⅲ started from the break of the BN bond and obtained 3H₂ molecules through the participation of different numbers of H₂O molecules. After multiple comparative analyses, the optimal hydrolysis reaction path has been obtained, and the reaction process can proceed spontaneously at room temperature.
- Fe₂₂@Co₅₈ core-shell,
- Hydrolysis reaction,
- Catalyst,
- Ammonia borane,
- Hydrogen generation
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Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure