Citation: Bin Guan, Xun Sun, Yu Zhang, Xian Wu, Yue Qiu, Maoxu Wang, Lishuang Fan, Naiqing Zhang. The discovery of interfacial electronic interaction within cobalt boride@MXene for high performance lithium-sulfur batteries[J]. Chinese Chemical Letters, ;2021, 32(7): 2249-2253. doi: 10.1016/j.cclet.2020.12.051 shu

The discovery of interfacial electronic interaction within cobalt boride@MXene for high performance lithium-sulfur batteries

Bin Guan ^a ,
Xun Sun ^a ,
Yu Zhang ^a ,
Xian Wu ^a ,
Yue Qiu ^a ,
Maoxu Wang ^a ,
Lishuang Fan ^{a, b, *,} ,
Naiqing Zhang ^{a, b, *,}

a.
State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
b.
Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150001, China

fanlsh@hit.edu.cn

znqmww@163.com

Received Date: 13 November 2020
Revised Date: 7 December 2020
Accepted Date: 22 December 2020
Available Online: 31 December 2020

Figures(5)

Lithium-sulfur battery is strongly considered as the most promising next-generation energy storage system because of the high theoretical specific capacity. The serious "shuttle effect" and sluggish reaction kinetic limited the commercial application of lithium-sulfur battery. Many heterostructures were applied to accelerate polysulfides conversion and suppress their migration in lithium-sulfur batteries. Nevertheless, the effect of the interface in heterostructure was not clear. Here, the Co₂B@MXene heterostructure is synthesized through chemical reactions at room temperature and employed as the interlayer material for Li-S batteries. The theoretical calculations and experimental results indicate that the interfacial electronic interaction of Co₂B@MXene induce the transfer of electrons from Co₂B to MXene, enhancing the catalytic ability and favoring fast redox kinetics of the polysulfides, and the theoretical calculations also reveal the underlying mechanisms for the electron transfer is that the two materials have different Fermi energy levels. The cell with Co₂B@MXene exhibits a high initial capacity of 1577 mAh/g at 0.1 C and an ultralow capacity decay of 0.0088% per cycle over 2000 cycles at 2 C. Even at 5.1 mg/cm² of sulfur loading, the cell with Co₂B@MXene delivers 5.2 mAh/cm² at 0.2 C.
- Co₂B@MXene,
- Separator,
- Interfacial electronic interaction,
- Catalytic activity,
- Lithium-sulfur batteries
1. [1]
  Y. Zhong, L. Yin, P. He, et al., J. Am. Chem. Soc. 140 (2018) 1455-1459. doi: 10.1021/jacs.7b11434
2. [2]
  L Fan, H Wu, X Wu, et al., Electrochim. Acta. 295 (2019) 444-451. doi: 10.1016/j.electacta.2018.08.107
3. [3]
  S. Jiang, S. Huang, M. Yao, et al., Chin Chem Lett. 31 (2020) 2347-2352. doi: 10.1016/j.cclet.2020.04.014
4. [4]
  S. Wang, Y. Yang, Y. Dong, et al., J. Adv. Ceram. 8 (2019) 1-18. doi: 10.1007/s40145-018-0292-2
5. [5]
  G. Chen, L. Yan, H. Luo, S. Guo, Adv. Mater. 28 (2016) 7580-7602. doi: 10.1002/adma.201600164
6. [6]
  C. Ye, Y. Jiao, H. Jin, et al., Angew. Chem. Int. Ed. 57 (2018) 16703-16707. doi: 10.1002/anie.201810579
7. [7]
  X. Ji, S. Evers, K.T. Lee, L. Nazar, Chem. Commun. 46 (2010) 1658-1660. doi: 10.1039/b918442b
8. [8]
  G. Zhou, L. Li, C. Ma, et al., Nano Energy 11 (2015) 356-365. doi: 10.1016/j.nanoen.2014.11.025
9. [9]
  B. Ding, L. Shen, G. Xu, P. Nie, X. Zhang, Electrochim. Acta 107 (2013) 78-84. doi: 10.1016/j.electacta.2013.06.009
10. [10]
  D. Cai, L. Wang, L. Li, et al., J. Mater. Chem. A 7 (2019) 806-815. doi: 10.1039/c8ta09906e
11. [11]
  B. Cao, Y. Chen, D. Li, L. Yin, Y. Mo, ChemSusChem 9 (2016) 3338-3344. doi: 10.1002/cssc.201601145
12. [12]
  Z. Xing, G. Li, S. Sy, Z. Chen, Nano Energy 54 (2018) 1-9. doi: 10.1016/j.nanoen.2018.09.034
13. [13]
  T. Zhou, W. Lv, J. Li, et al., Energy Environ. Sci. 10 (2017) 1694-1703. doi: 10.1039/C7EE01430A
14. [14]
  Y. Song, W. Zhao, L. Kong, et al., Energy Environ. Sci. 11 (2018) 2620-2630. doi: 10.1039/c8ee01402g
15. [15]
  H. Wang, K. Xie, Y. You, et al., Adv. Energy Mater. 9 (2019) 1901806. doi: 10.1002/aenm.201901806
16. [16]
  H. Liu, Z. Chen, L. Zhou, et al., Adv. Energy Mater. 9 (2019) 1901667. doi: 10.1002/aenm.201901667
17. [17]
  J. Song, X. Guo, J. Zhang, et al., J. Mater. Chem. A 7 (2019) 6507-6513. doi: 10.1039/c9ta00212j
18. [18]
  J. Nan, X. Guo, J. Xiao, et al., Small (2019) e1902085.
19. [19]
  X. Guo, W. Zhang, J. Zhang, et al., ACS Nano 14 (2020) 3651-3659. doi: 10.1021/acsnano.0c00177
20. [20]
  J. Liu, T. Chen, P. Juan, et al., ChemSusChem 11 (2018) 3758-3765. doi: 10.1002/cssc.201802098
21. [21]
  B. Guan, Y. Zhang, L. Fan, et al., ACS Nano 13 (2019) 6742-6750. doi: 10.1021/acsnano.9b01329
22. [22]
  Y. Zhang, Z. Mu, C. Yang, et al., Adv. Funct. Mater. 28 (2018) 1707578. doi: 10.1002/adfm.201707578
23. [23]
  J.Y. Zhang, G. Yang, S.G. Wang, et al., J. Appl. Phys. 116 (2014) 163905. doi: 10.1063/1.4900193
24. [24]
  Z. Shen, M. Cao, Z. Zhang, et al., Adv. Funct. Mater. 30 (2019) 1906661. doi: 10.1002/adfm.201906661
25. [25]
  Z.A. Ghazi, X. He, A.M. Khattak, et al., Adv. Mater. 29 (2017) 1606817. doi: 10.1002/adma.201606817
26. [26]
  L. Jiao, C. Zhang, C. Geng, et al., Adv. Energy Mater. 9 (2019) 1900219. doi: 10.1002/aenm.201900219
1. [1]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
2. [2]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
3. [3]
  Na Li , Wenxue Wang , Peng Wang , Zhanying Sun , Xinlong Tian , Xiaodong Shi . Dual-defect engineering of catalytic cathode materials for advanced lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110731-. doi: 10.1016/j.cclet.2024.110731
4. [4]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
5. [5]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
6. [6]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
7. [7]
  Tengfei Yang , Jingshuai Xiao , Xiao Sun , Yan Song , Chaozheng He . Facilitating the polysulfides conversion kinetics by porous LaOCl nanofibers towards long-cycling lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 109691-. doi: 10.1016/j.cclet.2024.109691
8. [8]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
9. [9]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
10. [10]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
11. [11]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
12. [12]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
13. [13]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
14. [14]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
15. [15]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
16. [16]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
17. [17]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
18. [18]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725
19. [19]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
20. [20]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1083)
HTML views(113)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142