Citation: Lilin Zhang, Yinbing Tian, Yuanyuan Wang, Liyi Dai. Enhanced conversion of α-cellulose to 5-HMF in aqueous biphasic system catalyzed by FeCl₃-CuCl₂[J]. Chinese Chemical Letters, ;2021, 32(7): 2233-2238. doi: 10.1016/j.cclet.2020.12.030 shu

Enhanced conversion of α-cellulose to 5-HMF in aqueous biphasic system catalyzed by FeCl₃-CuCl₂

Shanghai Key Laboratory of Green Chemistry and Green Process, College of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China

yywang@chem.ecnu.edu.cn

ydai@chem.ecnu.edu.cn

Received Date: 6 November 2020
Revised Date: 14 December 2020
Accepted Date: 18 December 2020
Available Online: 5 January 2021

Figures(7)

This study was to investigate the optimal additions of the cellulose decomposition reaction to obtain the most yield of 5-HMF and other furan derivatives in various biphasic systems with FeCl₃-CuCl₂ mixed catalysts, and explore its depolymerization kinetics. A series of controllable reactions have been performed under mild environmentally friendly atmosphere. The experiment results showed that 49.13 wt% of 5-HMF was the maximum production along with 2.98 wt% other furan derivatives catalyzed by mixed Lewis acid FeCl₃-CuCl₂ under the two phases which included high concentration NaCl aqueous phase and n-butanol organic phase at 190 ℃ for 45 min. The conclusion suggested that two-phase systems benefited the yield of 5-HMF, furan derivatives via extracting the target products from reaction phase to organic phase to avoid rehydration of 5-HMF. The kinetic calculation revealed the conversion with mixed catalysts had lower reaction apparent activation energy (21.65 kJ/mol, 190-230 ℃) and the reaction rate was faster than that with acid-based catalysts. Based on experiment exploration, the probable mechanism of cellulose decomposition with FeCl₃-CuCl₂ was proposed.
- Cellulose,
- Two phase,
- Mixed catalysts,
- Depolymerization,
- 5-HMF
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Enhanced conversion of α-cellulose to 5-HMF in aqueous biphasic system catalyzed by FeCl3-CuCl2

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通讯作者: 陈斌, bchen63@163.com

Enhanced conversion of α-cellulose to 5-HMF in aqueous biphasic system catalyzed by FeCl₃-CuCl₂