Citation: Dongmin Li, Bao Zhang, Xing Ou, Jiafeng Zhang, Kui Meng, Guanjun Ji, Pengfei Li, Jianhui Xu. Ammonia leaching mechanism and kinetics of LiCoO₂ material from spent lithium-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(7): 2333-2337. doi: 10.1016/j.cclet.2020.11.074 shu

Ammonia leaching mechanism and kinetics of LiCoO₂ material from spent lithium-ion batteries

Dongmin Li ^a ,
Bao Zhang ^a ,
Xing Ou ^a ,
Jiafeng Zhang ^{a, *,} ,
Kui Meng ^{b, *,} ,
Guanjun Ji ^a ,
Pengfei Li ^a ,
Jianhui Xu ^c

a.
School of Metallurgy and Environment, Central South University, Changsha 410083, China
b.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
c.
School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, China

yjyzjf@csu.edu.cn

mengkui@csu.edu.cn

Received Date: 20 July 2020
Revised Date: 11 November 2020
Accepted Date: 30 November 2020
Available Online: 4 December 2020

Figures(4)

In this paper, the ammonia leaching process and high-energy ball milling method were adapted to recover spent LiCoO₂ material. The ammonia reduction leaching mechanism of LiCoO₂ material in the ammonia-sodium sulfite-ammonium chloride system was elucidated. Compared with untreated LiCoO₂ material, the leaching equilibrium time of LiCoO₂ after ball-milled for 5 h was reduced from 48 h to 4 h, and the leaching efficiency of lithium and cobalt was improved from 69.86% and 70.80% to 89.86% and 98.22%, respectively. Importantly, the apparent activation energy and leaching kinetic equation of the reaction was calculated by the shrinking core reaction model, indicating that the reaction was controlled by the chemical reaction.
- Spent LiCoO₂,
- Recycling,
- Ammonia leaching,
- High-energy ball milling,
- Lithium-ion batteries
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Ammonia leaching mechanism and kinetics of LiCoO2 material from spent lithium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Ammonia leaching mechanism and kinetics of LiCoO₂ material from spent lithium-ion batteries