Citation: Hongwei Zhao, Yanqiu Zhang, Li Lixiang, Xin Geng, Haiming Yang, Weimin Zhou, Chengguo Sun, Baigang An. Synthesis of an ordered porous carbon with the dual nitrogen-doped interfaces and its ORR catalysis performance[J]. Chinese Chemical Letters, ;2021, 32(1): 140-145. doi: 10.1016/j.cclet.2020.11.035 shu

Synthesis of an ordered porous carbon with the dual nitrogen-doped interfaces and its ORR catalysis performance

Hongwei Zhao ^{a, b} ,
Yanqiu Zhang ^{a, b} ,
Li Lixiang ^{a, b, *,} ,
Xin Geng ^{a, b} ,
Haiming Yang ^{a, b} ,
Weimin Zhou ^{a, b} ,
Chengguo Sun ^{a, b} ,
Baigang An ^{a, b, **,}

a.
School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
b.
Key Laboratory of Energy Materials and Electrochemistry Research Liaoning Province, Anshan 114051, China

^**

lxli2005@126.com

bgan@ustl.edu.cn

Received Date: 24 September 2020
Revised Date: 25 October 2020
Accepted Date: 11 November 2020
Available Online: 20 November 2020

Figures(8)

Both nitrogen-doping feature and pore structure are critical factors for developing nitrogen-doped carbons based catalysts with a high performance toward oxygen reduction reaction (ORR). Herein, a simple one-step CVD of acetylene and acetonitrile vapor method using silanized SBA-15 as a template has been developed to synthesize an ordered porous carbon (OPC) with dual nitrogen-doped interfaces. The optimized sample as prepared with the CVD of 4 h at 750 ℃ contains two types of ordered mesopores that one type is the ordered cylindrical pores inheriting from the pores of SBA-15 and has a pore width of 4.0~5.0 nm, the other type is the ordered quasi-hexagonal pores with a width of 3.0~4.0 nm produced by etching the pore walls of SBA-15. These two types of pores whose pore walls are built by the nitrogen doped carbon layers resulted by the CVD and thus it actually makes the dual nitrogen-doped interfaced OPC (DN-OPC). Meanwhile, DN-OPC contains a few of micropores and a large SSA of 1430 m²/g. This dual-ordered pores and dual nitrogen-doped interfaces cannot only facilitate mass transport but also utilize the active sites of DN-OPC for ORR. Therefore, as metal-free ORR catalyst, DN-OPC exhibits a good activity close to commercial Pt/C catalyst, and an excellent durability and methanol tolerance.
- Silanized SBA-15,
- Nitrogen-doped,
- Dual-ordered pores,
- CVD of acetonitrile,
- Oxygen reduction reaction
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