Citation: Yang Zhou, Yanqiang Li, Qingran Ding, Youchao Liu, Yangxin Chen, Xitao Liu, Xiaoying Huang, Lina Li, Sangen Zhao, Junhua Luo. Noncentrosymmetric K₂Mn₃(SO₄)₃F₂·4H₂O and Rb₂Mn₃(SO₄)₃F₂·2H₂O with pseudo-KTP structures[J]. Chinese Chemical Letters, ;2021, 32(1): 263-265. doi: 10.1016/j.cclet.2020.11.014 shu

Noncentrosymmetric K₂Mn₃(SO₄)₃F₂·4H₂O and Rb₂Mn₃(SO₄)₃F₂·2H₂O with pseudo-KTP structures

Yang Zhou ^a ,
Yanqiang Li ^b ,
Qingran Ding ^b ,
Youchao Liu ^b ,
Yangxin Chen ^b ,
Xitao Liu ^{b, c} ,
Xiaoying Huang ^b ,
Lina Li ^{b, c} ,
Sangen Zhao ^{b, c, *,} ,
Junhua Luo ^{b, c, *,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

zhaosangen@fjirsm.ac.cn

jhluo@fjirsm.ac.cn

Received Date: 28 September 2020
Revised Date: 21 October 2020
Accepted Date: 5 November 2020
Available Online: 6 November 2020

Figures(4)

Two fluoride sulfates, K₂Mn₃(SO₄)₃F₂·4H₂O (I) and Rb₂Mn₃(SO₄)₃F₂·2H₂O (Π) are obtained by water solution method. Single-crystal X-ray diffraction analysis indicated that they crystallize in space groups of Cmc2₁. Their structures feature a pseudo-KTP structure consisting of interconnecting [Mn₃(SO₄)₃F₂(H₂O₎₂]_∞ layers, which are further packing along the a axis with alkali metal cations balancing the charges. The structure relationships between the two compounds are discussed. Second-harmonic generation measurements manifest that I and Π have similar second-harmonic generation responses of about 0.2 and 0.25 times that of KH₂PO₄.
- Sulfate,
- Second harmonic generation,
- Crystal structure,
- X-ray diffraction,
- Thermogravimetric analysis
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沈阳化工大学材料科学与工程学院沈阳 110142

Noncentrosymmetric K2Mn3(SO4)3F2·4H2O and Rb2Mn3(SO4)3F2·2H2O with pseudo-KTP structures

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通讯作者: 陈斌, bchen63@163.com

Noncentrosymmetric K₂Mn₃(SO₄)₃F₂·4H₂O and Rb₂Mn₃(SO₄)₃F₂·2H₂O with pseudo-KTP structures