Citation: Ming Xu, Yuheng Liu, Qiang Yu, Shihao Feng, Liang Zhou, Liqiang Mai. Phenylenediamine-formaldehyde chemistry derived N-doped hollow carbon spheres for high-energy-density supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(1): 184-189. doi: 10.1016/j.cclet.2020.11.004 shu

Phenylenediamine-formaldehyde chemistry derived N-doped hollow carbon spheres for high-energy-density supercapacitors

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

liangzhou@whut.edu.cn

mlq518@whut.edu.cn

Received Date: 22 June 2020
Revised Date: 5 August 2020
Accepted Date: 2 November 2020
Available Online: 5 November 2020

Figures(5)

Porous carbon spheres represent an ideal family of electrode materials for supercapacitors because of the high surface area, ideal conductivity, negligible aggregation, and ability to achieve space efficient packing. However, the development of new synthetic methods towards porous carbon spheres still remains a great challenge. Herein, N-doped hollow carbon spheres with an ultrahigh surface area of 2044 m²/g have been designed based on the phenylenediamine-formaldehyde chemistry. When applied in symmetric supercapacitors with ionic electrolyte (EMIBF₄), the obtained N-doped hollow carbon spheres demonstrate a high capacitance of 234 F/g, affording an ultrahigh energy density of 114.8 Wh/kg. Excellent cycling stability has also been achieved. The impressive capacitive performances make the phenylenediamine-formaldehyde resin derived N-doped carbon a promising candidate electrode material for supercapacitors.
- Porous carbon spheres,
- Hollow structure,
- Supercapacitors,
- Ionic electrolyte,
- Energy density
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