Citation: Lantao Liu, Huihui Liu, Zhenzhen Zuo, An-An Zhang, Zhongyi Li, Tuanjie Meng, Wei Wu, Yuanzhao Hua, Guoliang Mao. Synthesis of planar chiral isoquinolinone-fused ferrocenes through palladium-catalyzed C-H functionalization reaction[J]. Chinese Chemical Letters, ;2021, 32(1): 239-242. doi: 10.1016/j.cclet.2020.10.034 shu

Synthesis of planar chiral isoquinolinone-fused ferrocenes through palladium-catalyzed C-H functionalization reaction

Lantao Liu ^{a, c, d, *,} ,
Huihui Liu ^b ,
Zhenzhen Zuo ^d ,
An-An Zhang ^a ,
Zhongyi Li ^a ,
Tuanjie Meng ^a ,
Wei Wu ^b ,
Yuanzhao Hua ^d ,
Guoliang Mao ^{b, *,}

a.
Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China
b.
College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
c.
Beijing National Laboratory for Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China
d.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

liult05@iccas.ac.cn

maoguoliang@nepu.edu.cn

Received Date: 10 September 2020
Revised Date: 20 October 2020
Accepted Date: 21 October 2020
Available Online: 25 October 2020

Figures(4)

(S, S)-Me-BI-DIME/Pd(0)-catalyzed ennantioselective C–H functionalization of N-ferrocenyl o-bromo-benzanilides has been realized, affording isoquinolinone-fused ferrocenes with up to 97% ee. The products can be transformed into planar chiral ferrocenyl monophosphines, which demonstrate their preliminary application.
- (S, S)-Me-BI-DIME,
- Palladium,
- Asymmetric catalysis,
- C-H functionalization,
- Planar chiral ferrocenes
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