Citation: Peng Zhang, Bin Cao, Razium A. Soomro, Ning Sun, Bin Xu. Se-decorated SnO₂/rGO composite spheres and their sodium storage performances[J]. Chinese Chemical Letters, ;2021, 32(1): 282-285. doi: 10.1016/j.cclet.2020.10.006 shu

Se-decorated SnO₂/rGO composite spheres and their sodium storage performances

Peng Zhang ^a ,
Bin Cao ^a ,
Razium A. Soomro ^{a, b} ,
Ning Sun ^{a, b} ,
Bin Xu ^{a, *,}

a.
State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China
b.
Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

xubin@mail.buct.edu.cn

Received Date: 25 August 2020
Revised Date: 19 September 2020
Accepted Date: 21 September 2020
Available Online: 12 October 2020

Figures(3)

SnO₂ is considered a promising anode material for sodium-ion batteries due to its high theoretical capacity and low cost. However, the poor electrical conductivity and dramatic volume variation during charge/discharge cycling is a major limitation in its practical applicability. Here we propose a simple one-pot spray pyrolysis process to construct unique pomegranate-like SnO₂/rGO/Se spheres. The ideal structural configuration of these architectures was effective in alleviating the large volume variation of SnO₂, besides facilitating rapid electron transfer, allowing the devised anode to exhibit superior sodium storage performances in terms of capacity (506.7 mAh/g at 30 mA/g), cycle performance (397 mAh/g after 100 cycles at 50 mA/g) and rate capability (188.9 mAh/g at an ultrahigh current density of 10 A/g). The experimental evidence confirms the practical workability of p-SnO₂/rGO/Se spheres in SIBs.
- Sodium-ion batteries,
- Spray pyrolysis,
- SnO₂,
- Pomegranate-like structure,
- rGO nanosheets
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Se-decorated SnO2/rGO composite spheres and their sodium storage performances

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通讯作者: 陈斌, bchen63@163.com

Se-decorated SnO₂/rGO composite spheres and their sodium storage performances