Citation: Shaoxin Deng, Cheng-Xing Cui, Lu Liu, Lingyao Duan, Jichao Wang, Yuping Zhang, Lingbo Qu. A facile and controllable one-pot synthesis approach to amino-functionalized hollow silica nanoparticles with accessible ordered mesoporous shells[J]. Chinese Chemical Letters, ;2021, 32(3): 1177-1180. doi: 10.1016/j.cclet.2020.09.002 shu

A facile and controllable one-pot synthesis approach to amino-functionalized hollow silica nanoparticles with accessible ordered mesoporous shells

Shaoxin Deng ^{a, b} ,
Cheng-Xing Cui ^{b, c} ,
Lu Liu ^b ,
Lingyao Duan ^b ,
Jichao Wang ^b ,
Yuping Zhang ^{b, *,} ,
Lingbo Qu ^{a, c, **,}

a.
Postdoctoral Station of Food Science and Engineering, College of Food Science and Engineering, Henan University of Technology, Zhengzhou 450001, China
b.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China
c.
College of Chemistry, and Institute of Green Catalysis, Zhengzhou University, Zhengzhou 450001, China

^**

zhangyuping@hist.edu.cn

qulingbo@zzu.edu.cn

Received Date: 13 July 2020
Revised Date: 13 August 2020
Accepted Date: 3 September 2020
Available Online: 5 September 2020

Figures(4)

The development of a practical synthetic method to functionalize hollow mesoporous silica with organic groups is of current interest for selective adsorption and energy storage applications. Herein, a facile and controllable one-pot approach for the synthesis of monodisperse amino-functionalized hollow mesoporous silica nanoparticles is presented. A novel solid-to-hollow structural transformation procedure of the silica nanoparticles is presented. The structural transformation is easily designed, as observed through transmission electron microscopy, by tailoring the HCl and N-lauroylsarcosine sodium molar ratio and the water content in the sol-gel. Ordered and radially oriented in situ amino-functionalized mesochannels were successfully introduced into the shells of the hollow silica nanoparticles. A formation mechanism for the hollow mesoporous silica materials is discussed.
- Hollow silica,
- One-pot approach,
- Solid-to-hollow transformation,
- Ordered mesoporous shell,
- Amino functionalization
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