Citation: Yan Song, Xiuyuan Li, Chaozheng He. Porous carbon framework nested nickel foam as freestanding host for high energy lithium sulfur batteries[J]. Chinese Chemical Letters, ;2021, 32(3): 1106-1110. doi: 10.1016/j.cclet.2020.08.024 shu

Porous carbon framework nested nickel foam as freestanding host for high energy lithium sulfur batteries

Yan Song ^{a, b} ,
Xiuyuan Li ^{a, b} ,
Chaozheng He ^{a, b, *,}

a.
Shaanxi Key Laboratory of Optoelectronic Functional Materials and Devices, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
b.
Institute of Environmental and Energy Catalysis, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China

hecz2019@xatu.edu.cn

Received Date: 21 July 2020
Revised Date: 26 July 2020
Accepted Date: 17 August 2020
Available Online: 19 August 2020

Figures(4)

Constructing 3D multifunctional conductive framework as stable sulfur cathode contributes to develop advanced lithium-sulfur (Li-S) batteries. Herein, a freestanding electrode with nickel foam framework and nitrogen doped porous carbon (PC) network is presented to encapsulate active sulfur for Li-S batteries. In such a mutually embedded architecture with high stability, the interconnected carbon network and nickel foam matrix can expedite ionic/electronic transport and sustain volume variations of sulfur. Furthermore, rationally designed porous structures provide sufficient internal space and large surface area for high active sulfur loading and polar polysulfides anchoring. Benefiting from the synergistic superiority, the Ni/PC-S cathode exhibits a high initial capacity of around 1200 mAh/g at 0.2 C, excellent rate performance, and high cycling stability with a low decay rate of 0.059% per cycle after 500 cycles. This work provides a useful strategy to exploit freestanding porous framework for diverse applications.
- Porous carbon,
- Nitrogen doping,
- Polysulfides anchoring,
- Freestanding electrode,
- Lithium-sulfur batteries
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