Citation: Tianlu Zhang, Zhiguo Lu, Luyao Zhang, Yan Li, Jun Yang, Jie Shen, Jianze Wang, Yunwei Niu, Zuobing Xiao, Lei Chen, Xin Zhang. Preparation of hollow mesoporous silica nanorods for encapsulating and slowly releasing eugenol[J]. Chinese Chemical Letters, ;2020, 31(12): 3135-3138. doi: 10.1016/j.cclet.2020.07.010 shu

Preparation of hollow mesoporous silica nanorods for encapsulating and slowly releasing eugenol

Tianlu Zhang ^{a, c, 1} ,
Zhiguo Lu ^{a, c, 1} ,
Luyao Zhang ^{a, c} ,
Yan Li ^{a, c} ,
Jun Yang ^{a, c} ,
Jie Shen ^{a, c} ,
Jianze Wang ^a ,
Yunwei Niu ^{d, e} ,
Zuobing Xiao ^{d, e} ,
Lei Chen ^{b, *,} ,
Xin Zhang ^{a, *,}

a.
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
b.
Department of Obstetrics and Gynecology, Navy General Hospital of People Liberation Army, Beijing 100048, China
c.
School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
d.
Shanghai Research Institute of Fragrance and Flavor Industry, Shanghai 200232, China
e.
School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 200233, China

chenleis@mail.tsinghua.edu.cn

xzhang@ipe.ac.cn

Received Date: 6 May 2020
Revised Date: 2 July 2020
Accepted Date: 6 July 2020
Available Online: 7 July 2020

Figures(4)

Fragrances are widely used in many aspects of our lives. They cannot only make people happy, but also treat many diseases. However, excessively fast evaporation rate is one of the main obstacles to the use of spices. In this study, mesoporous silica nanorods (MSNRs) and hollow mesoporous silica nanorods (HMSNRs) were prepared to encapsulate eugenol. These two nano-fragrances were named eugenol@MSNRs and eugenol@HMSNRs, respectively. The morphologies, size, interior structures and pore performances of MSNRs and HMSNRs. Besides, the performances of encapsulation and fragrance release of eugenol@MSNRs and eugenol@HMSNRs were compared and analyzed. The results showed that eugenol@HMSNRs encapsulated more fragrance and were faster to encapsulate compared with eugenol@MSNRs. Both the release rates of eugenol from eugenol@MSNRs and eugenol@HMSNRs were slow. But the eugenol was released from eugenol@MSNRs more slowly.
- Eugenol,
- Hollow mesoporous silica nanorods,
- Mesoporous silica nanorods,
- Nano-fragrance,
- Slow release of fragrance
1. [1]
  S. Burt, Int. J. Food Microbiol. 94(2004) 223-253. doi: 10.1016/j.ijfoodmicro.2004.03.022
2. [2]
  M.B. Pashazanousi, M. Raeesi, S. Shirali, Asian J. Chem. 24(2012) 4331-4334.
3. [3]
  M.G. Miguel, Flavour. Frag. J. 25(2010) 291-312. doi: 10.1002/ffj.1961
4. [4]
  B. Cooke, E. Ernst, Br. J. Gen. Pract. 50(2000) 493-496.
5. [5]
  B. Ali, N.A. Al-Wabel, S. Shams, et al., Asian Pac. J. Trop. Bio. 5(2015) 601-611. doi: 10.1016/j.apjtb.2015.05.007
6. [6]
  A.M. Borda, D.G. Clark, D.J. Huber, B.A. Welt, T.A. Nell, Postharvest. Biol. Tec. 59(2011) 245-252. doi: 10.1016/j.postharvbio.2010.09.008
7. [7]
  D.L. Berthier, I. Schmidt, W. Fieber, et al., Langmuir 26(2010) 7953-7961. doi: 10.1021/la904832d
8. [8]
  Z. Guo, S. Li, Z. Liu, W. Xue, ACS Biomater. Sci. Eng. 4(2018) 988-996. doi: 10.1021/acsbiomaterials.7b00971
9. [9]
  J. Zhang, J. Cui, Y. Deng, Z. Jiang, W.M. Saltzman, ACS Biomater. Sci. Eng. 2(2016) 2080-2089. doi: 10.1021/acsbiomaterials.6b00502
10. [10]
  Y. Yuan, F. Gong, Y. Cao, et al., J. Biomed. Nanotechnol. 11(2015) 668-679. doi: 10.1166/jbn.2015.1966
11. [11]
  A. Gupta, S. Asthana, R. Konwar, M.K. Chourasia, J. Biomed. Nanotechnol. 9(2013) 915-925. doi: 10.1166/jbn.2013.1591
12. [12]
  L. Song, A. Zeng, M. Hu, et al., J. Biomed. Nanotechnol. 14(2018) 267-280. doi: 10.1166/jbn.2018.2486
13. [13]
  X. Jia, M. Pei, X. Zhao, et al., ACS Biomater. Sci. Eng. 2(2016) 1641-1648. doi: 10.1021/acsbiomaterials.6b00443
14. [14]
  D. Li, Y. Song, J. He, M. Zhang, P. Ni, ACS Biomater. Sci. Eng. 5(2019) 2307-2315. doi: 10.1021/acsbiomaterials.9b00301
15. [15]
  D.J. Suchyta, M.H. Schoenfisch, ACS Biomater. Sci. Eng. 3(2017) 2136-2143. doi: 10.1021/acsbiomaterials.7b00255
16. [16]
  A. Wadi, M. Abdel-Hafez, G.A. Husseini, J. Biomed. Nanotechnol.15(2019) 162-169. doi: 10.1166/jbn.2019.2672
17. [17]
  D.J. Fu, Y. Jin, M.Q. Xie, et al., Chin. Chem. Lett. 25(2014) 1435-1440. doi: 10.1016/j.cclet.2014.06.027
18. [18]
  Y.H. Niu, T. Yang, R.Y. Ke, C. Wang, Mater. Express 9(2019) 563-569. doi: 10.1166/mex.2019.1537
19. [19]
  M.C.F. Goncalves, O. Mertins, A.R. Pohlmann, N.P. Silveira, S.S. Guterres, J. Biomed. Nanotechnol. 8(2012) 240-250. doi: 10.1166/jbn.2012.1375
20. [20]
  J.F. Shi, M.G. Sun, X.Y. Li, et al., J. Biomed. Nanotechnol. 11(2015) 1568-1582. doi: 10.1166/jbn.2015.2075
21. [21]
  J. Wang, Z. Teng, Y. Tian, et al., J. Biomed. Nanotechnol. 9(2013) 1882-1890. doi: 10.1166/jbn.2013.1691
22. [22]
  Y.J. Cheng, S.Y. Qin, Y. Ma, et al., ACS Biomater. Sci. Eng. 5(2019) 1878-1886. doi: 10.1021/acsbiomaterials.9b00099
23. [23]
  K.M. Rao, S. Parambadath, A. Kumar, C.S. Ha, S.S. Han, ACS Biomater. Sci. Eng. 4(2018) 175-183. doi: 10.1021/acsbiomaterials.7b00558
24. [24]
  W.X. Gao, Y.L. Hu, L. Xu, et al., Chin. Chem. Lett. 29(2018) 1795-1798. doi: 10.1016/j.cclet.2018.05.022
25. [25]
  Y. Wang, Y. Yan, J. Cui, et al., Adv. Mater. 22(2010) 4293-4297. doi: 10.1002/adma.201001497
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