Citation: Qingkai Qi, Shan Jiang, Qinglong Qiao, Jinbei Wei, Bin Xu, Xiaocun Lu, Zhaochao Xu, Wenjing Tian. Direct observation of intramolecular coplanarity regulated polymorph emission of a tetraphenylethene derivative[J]. Chinese Chemical Letters, ;2020, 31(11): 2985-2987. doi: 10.1016/j.cclet.2020.05.044 shu

Direct observation of intramolecular coplanarity regulated polymorph emission of a tetraphenylethene derivative

Qingkai Qi ^{a, b, c, **,} ,
Shan Jiang ^a ,
Qinglong Qiao ^b ,
Jinbei Wei ^a ,
Bin Xu ^a ,
Xiaocun Lu ^{c, *,} ,
Zhaochao Xu ^{b, *,} ,
Wenjing Tian ^{a, *,}

a.
State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China
b.
CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
c.
Department of Chemistry & Biomolecular Science, Clarkson University, Potsdam, NY 13699, United States

^**

Received Date: 6 May 2020
Revised Date: 26 May 2020
Accepted Date: 30 May 2020
Available Online: 1 June 2020

Figures(4)

Polymorphism makes it possible to clarify the relationship between emission property and crystal structure. However, based on the exact molecular conformation in tetraphenylethene polymorphisms, it is still challenging to evaluate the difference of intramolecular coplanarity without the support of calculation because of the complex combination of four different torsion angles between four peripheral benzenes and the central ethylene plane. Here, by using a di-formyl-functionalized tetraphenylethene derivative, two ideal polymorphisms with a consistent trend of the corresponding torsion angles have been obtained. For the first time, we explicitly demonstrated that intramolecular coplanarity is the underlying cause of the polymorphism-dependent emission of tetraphenylethene derivatives.
- Tetraphenylethene,
- Polymorphism,
- Intramolecular coplanarity,
- Intermolecular stacking,
- Photophysical property
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