Citation: Weimin Zhao, Fucheng Ren, Qizhang Yan, Haodong Liu, Yong Yang. A facile synthesis of non-aqueous LiPO₂F₂ solution as the electrolyte additive for high performance lithium ion batteries[J]. Chinese Chemical Letters, ;2020, 31(12): 3209-3212. doi: 10.1016/j.cclet.2020.05.006 shu

A facile synthesis of non-aqueous LiPO₂F₂ solution as the electrolyte additive for high performance lithium ion batteries

Weimin Zhao ^{a, b} ,
Fucheng Ren ^b ,
Qizhang Yan ^c ,
Haodong Liu ^{c, *,} ,
Yong Yang ^{b, *,}

a.
College of Chemical Engineering and Safety, Binzhou University, Binzhou 256503, China
b.
State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
c.
Department of Nanoengineering, University of California San Diego, La Jolla 92093, United States

haodong.liu.xmu@gmail.com

yyang@xmu.edu.cn

Received Date: 5 April 2020
Revised Date: 30 April 2020
Accepted Date: 30 April 2020
Available Online: 15 December 2020

Figures(3)

Constructing a reliable and favorable electrode-electrolyte interface is crucial to utilize the exceptional energy storage capability in commercial lithium-ion batteries. Here, we report a facile synthesis approach for the lithium difluorophosphate (LiPO₂F₂) solution as an effective film-forming additive via direct adding the Li₂CO₃ into LiPF₆ solution at 45 ℃. Benefiting from the significantly reduced interface resistance (R_SEI) and charge transfer impedance (R_ct) of both the cathode and anode by adding the prepared LiPO₂F₂ solution into a baseline electrolyte, the cycling performance of the graphite‖LiNi_0.5Mn_0.3Co_0.2O₂ pouch cell is remarkably improved under all-climate condition.
- Lithium difluorophosphate (LiPO₂F₂),
- solution,
- Electrolyte additives,
- Electrode-electrolyte interface,
- Synthesis,
- Li-ion batteries
1. [1]
  M. Li, J. Lu, Z.W. Chen, et al., Adv. Mater. 30(2018) 1800561. doi: 10.1002/adma.201800561
2. [2]
  Y.Y. Liu, Y.Y. Zhu, Y. Cui, Nat. Energy 4(2019) 540-550. doi: 10.1038/s41560-019-0405-3
3. [3]
  Y. Yu, P. Karayaylali, Y. Katayama, et al., J. Phys. Chem. C 122(2018) 27368-27382. doi: 10.1021/acs.jpcc.8b07848
4. [4]
  K. Xu, Chem. Rev. 114(2014) 11503-11618. doi: 10.1021/cr500003w
5. [5]
  W. Zhao, Y. Ji, Z. Zhang, et al., Curr. Opin. Electrochem. 6(2017) 84-91. doi: 10.1016/j.coelec.2017.10.012
6. [6]
  J. Xia, L. Madec, L. Ma, J. Power Sources 295(2015) 203-211. doi: 10.1016/j.jpowsour.2015.06.151
7. [7]
  W.M. Zhao, B.Z. Zheng, H.D. Liu, et al., Nano Energy 63(2019) 103815. doi: 10.1016/j.nanoen.2019.06.011
8. [8]
  M.Q. Xu, L. Zhou, Y.N. Dong, et al., Energy Environ. Sci. 9(2016) 1308-1319. doi: 10.1039/C5EE03360H
9. [9]
  Y.C. Li, S. Wan, G.M. Veith, et al., Adv. Energy Mater. 7(2017) 1601397. doi: 10.1002/aenm.201601397
10. [10]
  J. Cha, J.G. Han, J. Hwang, et al., J. Power Sources 357(2017) 97-106. doi: 10.1016/j.jpowsour.2017.04.094
11. [11]
  X.Q. Zhang, T. Li, B.Q. Li, et al., Angew. Chem. Int. Ed. 59(2020) 3252-3257. doi: 10.1002/anie.201911724
12. [12]
  J.W. Chen, L.D. Xing, X.R. Yang, et al., Electrochim. Acta 290(2018) 568-576. doi: 10.1016/j.electacta.2018.09.077
13. [13]
  Y. Chen, W.M. Zhao, Q.H. Zhang, et al., Adv. Funct. Mater. (2020) 2000396.
14. [14]
  M.F. He, R. Gao, M. Hobold, et al., Proc. Natl. Acad. Sci. U. S. A.117(2020) 73-79. doi: 10.1073/pnas.1911017116
15. [15]
  Y.K. Li, B. Cheng, F.P. Jiao, et al., ACS Appl. Mater. Interfaces 12(2020) 16298-16307. doi: 10.1021/acsami.9b22360
16. [16]
  W.M. Zhao, G.R. Zheng, M. Lin, J. Power Sources 380(2018) 149-157. doi: 10.1016/j.jpowsour.2018.01.041
17. [17]
  J.G. Han, K. Kim, Y. Lee, et al., Adv. Mater. 31(2019) 1804822. doi: 10.1002/adma.201804822
18. [18]
  E. Markevich, R. Sharabi, H. Gottlieb, et al., Electrochem. Commun. 15(2012) 22-25. doi: 10.1016/j.elecom.2011.11.014
19. [19]
  K. Leung, C.M. Tenney, J. Phys. Chem. C 117(2013) 24224-24235. doi: 10.1021/jp408974k
20. [20]
  X. Yu, A. Manthiram, Energy Environ. Sci. 11(2018) 527-543. doi: 10.1039/C7EE02555F
21. [21]
  B. Liao, H. Li, M. Xu, et al., Adv. Energy Mater. 8(2018) 1800802. doi: 10.1002/aenm.201800802
22. [22]
  E.R. Logan, E.M. Tonita, K.L. Gering, et al., J. Electrochem. Soc. 165(2018) A21-A30. doi: 10.1149/2.0271802jes
23. [23]
  J.M. Zheng, M.H. Engelhard, D. Mei, et al., Nat. Energy 2(2017) 17012. doi: 10.1038/nenergy.2017.12
24. [24]
  A.M. Haregewoin, A.S. Wotango, B.J. Hwang, Energy Environ. Sci. 9(2016) 1955-1988. doi: 10.1039/C6EE00123H
25. [25]
  J.M. Tarascon, M. Armand, Nature 414(2001) 359-367. doi: 10.1038/35104644
26. [26]
  J. Kim, J. Lee, H. Ma, et al., Adv. Mater. (2017) 1704309.
27. [27]
  Y.P. Stenzel, J. Henschel, M. Winter, et al., RSC Adv. 20(2019) 11413-11419.
28. [28]
  W. Weber, R. Wagner, B. Streipert, J. Power Sources 306(2016) 193-199. doi: 10.1016/j.jpowsour.2015.12.025
1. [1]
  Sun Jinfeng , Guo Lingzhi , Gao Miaomiao , Sun Xuan , Zhang Jinyang , Liang Longwei , Liu Yang , Hou Linrui , Yuan Changzhou . Solid-state template-free fabrication of uniform Mo₂C microflowers with lithium storage towards Li-ion batteries. Chinese Chemical Letters, 2020, 31(6): 1670-1673. doi: 10.1016/j.cclet.2019.09.049
2. [2]
  Li Wei , Siqin Gao-Wa , Zhu Zhi , Qi Lu , Tian Wen-Huai . Electrochemical properties of niobium and phosphate doped spherical Li-rich spinel LiMn₂O₄ synthesized by ion implantation method. Chinese Chemical Letters, 2017, 28(7): 1438-1446. doi: 10.1016/j.cclet.2017.03.035
3. [3]
  Rui Sun , Jing Song , Si Jie Liu , Hui Zhao , Chun Li Yan , Ai Jun Zhang , Diwa Koirala , Da Wei Li , Chun Hu . Design, synthesis and biological evaluation of 1,4-dihydrothieno[3',2':5,6]thiopyrano[4,3-c]pyrazole-3-carboxylic amide derivatives as potential estrogen receptor antagonists. Chinese Chemical Letters, 2011, 22(3): 256-259. doi: 10.1016/j.cclet.2010.10.029
4. [4]
  Xi Wang , Yi-Jun Yang , Ying Ma , Jian-Nian Yao . Controlled synthesis of multi-shelled transition metal oxide hollow structure through one-pot solution route. Chinese Chemical Letters, 2013, 24(01): 1-6.
5. [5]
  Peng Cho Tang , Zhi Gang Lin , Yang Wang , Fang Long Yang , Qian Wang , Jian Hong Fu , Lei Zhang , Ai Shen Gong , Jing Jing Luo , Jun Dai , Gao Hong She , Dan Dan Si , Jun Feng . Design and synthesis of DPP-4 inhibitor for the treatment of type 2 diabetes. Chinese Chemical Letters, 2010, 21(3): 253-256. doi: 10.1016/j.cclet.2009.11.014
6. [6]
  Li Qiang Fu , Xin Sheng Guo , Xin Liu , Hui Li He , Yu Lin Wang , Yu She Yang . Synthesis and antibacterial activity of C-2 (S)-substituted pleuromutilin derivatives. Chinese Chemical Letters, 2010, 21(5): 507-510. doi: 10.1016/j.cclet.2010.01.001
7. [7]
  Xiao Ming Ji , Ye Lu , Ming Qin Zhao , Xiao Yun Zhang , Yun Liu , Le Liu . Synthesis of new 2,5-dimethyl pyrrole derivatives from acetonylacetone. Chinese Chemical Letters, 2010, 21(8): 919-921. doi: 10.1016/j.cclet.2010.03.004
8. [8]
  Chun Hua ZHANG , Nian Fa YANG , Li Wen YANG . Synthesis of New Chiral C₂-Symmetrical Bis(oxazoline) Compounds. Chinese Chemical Letters, 2003, 14(2): 125-126.
9. [9]
  Qiang Feng , Chao Zhang , Qiang Tang , Mei Ming Luo . Synthesis of 1,1'-binaphthyl-2,2'-diamine from 2-naphthol under atmospheric pressure. Chinese Chemical Letters, 2009, 20(10): 1150-1152. doi: 10.1016/j.cclet.2009.05.033
10. [10]
  Shao Zao Tan , Liu Cai Ding , Ying Liang Liu , You Sheng Ouyang , Yi Ben Chen . Synthesis and antibacterial activity of new layered perovskite compounds, Ag_xNa_2-xLa₂Ti₃O₁₀. Chinese Chemical Letters, 2007, 18(1): 85-88. doi: 10.1016/j.cclet.2006.11.025
11. [11]
  Xiang Ping HU , Hui Lin CHEN , Hui Cong DAI , Xin Quan HU , Zhuo ZHENG . Synthesis and Potential Application of Novel C₂-Symmetrical Bis(ferrocenyl) P₂N Ligand. Chinese Chemical Letters, 2003, 14(11): 1113-1115.
12. [12]
  Lei Li , Yu Chi , Xiao-Yu Zhang , Guang-Quan Zhang , Yong Zhang , Ting-Xing Zhao , Ming Huang , Hong-Bo Li . Synthesis, crystal structure and thermal analysis of tetraiodo-4, 4'-bi-1, 2, 4-triazole. Chinese Chemical Letters, 2013, 24(9): 786-788.
13. [13]
  Shuang Zhi , Shuai Mu , Ying Liu , Min Gong , Ping-Bao Wang , Deng-Ke Liu . Synthesis and biological evaluation of novel phenothiazine derivatives as non-peptide arginine vasopressin V2 receptor antagonists. Chinese Chemical Letters, 2015, 26(5): 627-630. doi: 10.1016/j.cclet.2015.01.022
14. [14]
  Yan-Chun Guo , Jing Li , Jiao-Li Ma , Zhi-Ran Yu , Hai-Wei Wang , Wen-Juan Zhu , Xin-Cheng Liao , Yu-Fen Zhao . Synthesis and antitumor activity of α-aminophosphonate derivatives containing thieno[2,3-d]pyrimidines. Chinese Chemical Letters, 2015, 26(6): 755-758. doi: 10.1016/j.cclet.2015.03.026
15. [15]
  Shuo Zhang , Yu-Li Wang , Qun-Chao Wei , Wei-Ren Xu , Li-Da Tang , Gui-Long Zhao , Jian-Wu Wang . Design, synthesis and biological activity of cyclohexane-bearing C-glucoside derivatives as SGLT2 inhibitors. Chinese Chemical Letters, 2013, 24(05): 429-432.
16. [16]
  Xue-Ping Chu , Qing-Fa Zhou , Shen Zhao , Fei-Fei Ge , Mian Fu , Jia-Peng Chen , Tao Lu . Synthesis and biological evaluation of 3-amino-2-pyrones as selective cyclooxygenase-1 (COX-1) inhibitors. Chinese Chemical Letters, 2013, 24(2): 120-122.
17. [17]
  Wen-Jing Liu , De-Sheng Mei , Wen-Hu Duan . Synthesis of 1,7-dimethoxy-2-hydroxyxanthone, a natural product with potential activity on erectile dysfunction. Chinese Chemical Letters, 2013, 24(6): 515-517.
18. [18]
  You-An Xiao , Zhi-Qiang Wang , Xue-Min Wang , Yi Hui , Yong Ling , Xin-Yang Wang , Li-Qin He . Synthesis and in vitro biological evaluation of novel 2-aminoimidazolone derivatives as anti-tumor agents. Chinese Chemical Letters, 2013, 24(8): 727-730.
19. [19]
  Xiao-Hui Zhao , Zhi-Wen Ye . A facile synthesis of a novel energetic surfactant 1-amino-3-dodecyl-1, 2, 3-triazolium nitrate. Chinese Chemical Letters, 2014, 25(2): 209-211.
20. [20]
  Ke-Hui Hou , Cong-Ming Ma , Zu-Liang Liu . Synthesis, characterization and theoretical study of 2-azido-4-nitroimidazole-based energetic salts. Chinese Chemical Letters, 2014, 25(3): 438-440. doi: 10.1016/j.cclet.2013.12.007

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(100)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A facile synthesis of non-aqueous LiPO2F2 solution as the electrolyte additive for high performance lithium ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

A facile synthesis of non-aqueous LiPO₂F₂ solution as the electrolyte additive for high performance lithium ion batteries